File name: Pandora119s1_Athens-NOA_20190728_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T165306.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190728_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190728 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190728T033021.0Z 7148.146076 249 1 32.01 2 89.73 65.75 46.83 100.06 0.00 1 0.00 1 0 50 1.054e-01 1.003e-01 9.315e-02 9.093e-02 2.865921e+03 6.217039e+03 5.373082e+02 -6.000000e+00 6.268136e+03 290.78 -2.00 20.00 -2.00 505.36 0.00e+00 4.825188e-03 2.643588e-03 1.474490e-04 -6.000000e+00 3.063832e-03 290.78 -2.00 20.00 -2.00 500.30 0.00e+00 3.265492e+00 1.841230e+00 2.321302e-02 -6.000000e+00 2.123483e+00 232.15 -2.00 3.45 -2.00 501.94 0.00e+00 19.876 0.134 489.00 513.00 1 9.7093e+00 1.4286e-01 3.4155e-02 -6.0000e+00 1.6375e-01 7.0439e-02 3.4879e-02 1.8834e-03 -6.0000e+00 4.1687e-02 5.2182e-06 2.4167e-02 1.0128e-02 8.2460e-05 -6.0000e+00 1.2117e-02 -4.1020e-02 3.5740e-04 12 8 8 10 0 0 89.46 21.71 13.36 -0.04102 0.12661 8 2 1 4 0 4000.000 26.73 20.00 21.71 -2456 -9686 8274 -1804 13347 -5662 4535 -7896 15991 -2890 -3695 17961 -5716 812 -561 -1926 4345 -1437 9933 6982 19259 -2251 -15649 8862 -15615 4599 2291 -8787 -12481 -2965 -7339 9131 9417 -8513 20685 15913 -938 -5719 -2225 -8344 965 10002 -13091 6382 15041 -6425 -26 2531 21024 -11368 -10606 -4573 21450 -1356 6524 14165 8104 7779 -5184 6468 -4044 2695 403 15577 2819 -3843 2316 -3548 13635 5845 -5628 12343 -19838 -2678 -16239 1967 8674 -6818 36512 3462 9579 -8711 7703 -8400 13662 230 -8072 17590 13259 6156 -23074 3040 864 9673 6965 -1032 12528 -4457 -964 -8773 11449 19280 -8406 10841 8 11048 -5115 -4439 21807 6056 -1511 -5274 -2710 234 5756 -9390 4765 12520 -10419 9431 -7406 -14813 -4854 3644 6783 -4744 -9101 1014 8135 -1393 -2460 5559 -16345 -3013 1684 12873 -17758 7621 -857 1235 24293 13725 16334 -11593 17777 -1560 21565 -9223 -3294 -3802 -2407 -10520 7751 -1920 12471 -6490 4717 -9259 14594 -3138 -3986 15397 -6153 817 -577 -2040 4415 -1533 9806 6941 17438 -2470 -19740 8789 -19771 4723 2369 -9910 -14281 -3059 -7984 8628 9119 -10040 18284 14663 -1014 -6436 -2416 -9685 1031 9897 -16089 6674 14424 -7383 -28 2635 17746 -12622 -11509 -4670 17603 -1397 6364 13352 7961 7677 -5827 6487 -4517 2814 428 14057 2847 -4083 2281 -3656 11712 5408 -5863 10828 -24156 -2741 -18809 1869 7609 -6932 24023 3179 8316 -9135 6898 -8663 11611 223 -8289 14346 11359 5724 -28370 2898 839 8489 6159 -965 10246 -4130 -855 -8461 9206 14730 -8650 9272 8 9302 -5035 -4360 16709 5531 -1515 -5568 -2819 238 5577 -10345 4649 11183 -11276 8487 -7661 -16546 -4936 3420 6191 -4866 -9750 981 7283 -1356 -2389 4941 -18080 -2946 1599 11133 -21185 7138 -881 1251 19638 12378 14340 -13352 15028 -1569 16964 -9841 -3343 -3941 SO 20190728T033438.0Z 7148.149051 253 1 32.01 2 88.96 66.41 46.02 100.83 0.00 1 0.00 1 0 22 5.992e-02 5.993e-02 5.312e-02 5.255e-02 9.727201e+03 3.942725e+03 5.221046e+02 -6.000000e+00 3.563641e+03 290.78 -2.00 20.00 -2.00 505.38 0.00e+00 1.289183e-03 1.516252e-03 8.899716e-05 -6.000000e+00 1.742064e-03 290.78 -2.00 20.00 -2.00 500.47 0.00e+00 2.820106e+00 1.062271e+00 7.988847e-02 -6.000000e+00 1.207849e+00 232.15 -2.00 3.45 -2.00 502.08 0.00e+00 18.390 0.106 489.00 513.00 1 9.4266e+00 8.2107e-02 3.0805e-02 -6.0000e+00 9.3132e-02 3.4006e-02 2.0104e-02 2.3494e-03 -6.0000e+00 2.3726e-02 9.2497e-06 4.4116e-03 5.6296e-03 4.3319e-05 -6.0000e+00 6.8905e-03 6.9645e-03 3.0353e-05 12 8 8 10 0 0 5.08 21.71 3.51 0.00696 0.03757 8 2 1 4 0 4000.000 26.73 20.00 21.71 7266 -1945 1432 82 5419 4747 -5088 -6489 -3425 5079 -5345 4302 4768 -3733 4323 -11769 6290 -109 7271 6468 -2306 2014 -14925 12545 -825 4249 298 -7334 268 -7262 10027 3171 -2031 -5573 2560 4299 4182 10457 -1995 -1015 -7838 -5626 4930 -2675 8083 -6183 627 8041 5347 2449 3866 2240 -2140 -18 -3756 15636 -2623 5595 -2181 897 -384 -3824 5932 -3708 5817 378 2994 -7124 -1977 -1883 1784 4705 -8538 6285 4941 280 -2605 -4416 8501 -3867 919 2282 -3972 -8790 -16690 3432 -6552 8592 -3402 16697 -6013 -383 510 2477 5095 -5765 -4868 3034 2353 10302 -8480 2485 -7729 9570 -3324 3066 -363 -5393 13161 1215 12101 504 5783 -1595 -2858 2028 -693 3113 -3013 1638 180 2291 7519 -5430 7466 2127 2554 -2377 -8360 -8398 1389 3425 -6531 5982 -6366 6222 1256 2901 3432 -645 3628 -1540 8773 8297 1774 -1078 -3502 2433 -16090 3499 6258 -1818 1333 80 5147 4644 -5583 -7280 -3722 5024 -5793 4179 4555 -3849 4106 -13235 6009 -113 7182 6520 -2552 2142 -18384 12102 -889 4353 315 -8259 273 -7814 8988 3068 -2118 -6194 2677 4443 4306 10023 -2146 -1078 -8930 -6320 5037 -2981 8141 -7183 676 7929 5309 2441 3705 2144 -2133 -18 -3952 13892 -2775 5635 -2319 925 -401 -4154 5849 -4009 5661 383 2909 -7556 -1968 -1855 1688 4342 -9078 5809 4630 272 -2565 -4365 7321 -3758 854 2106 -3936 -9233 -18674 3234 -6823 7675 -3424 13798 -6132 -382 504 2375 4656 -5575 -4535 2612 2005 8062 -7901 2134 -7639 8232 -3318 2884 -352 -5459 11073 1162 10516 497 5461 -1632 -2982 2033 -719 3111 -3178 1627 179 2207 6864 -5532 6881 2076 2486 -2372 -8845 -8843 1313 3137 -6565 5316 -6477 5690 1231 2849 3404 -674 3669 -1652 8529 8106 1840 -1137 -3722 2404 -19054 3431 SO 20190728T033850.0Z 7148.151968 257 1 32.01 2 88.20 67.05 45.22 101.60 0.00 1 0.00 1 0 29 1.756e-02 1.746e-02 1.441e-02 1.433e-02 1.443490e+04 1.096764e+03 9.272182e+02 -6.000000e+00 1.044599e+03 290.78 -2.00 20.00 -2.00 505.49 0.00e+00 3.222878e-03 4.125147e-04 1.734958e-04 -6.000000e+00 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