File name: Pandora119s1_Athens-NOA_20190818_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20251130T235825.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190818_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190818T034811.0Z 7169.158461 213 1 32.02 2 89.72 73.38 66.00 238.15 0.00 1 0.00 1 0 15 7.337e-02 7.086e-02 7.274e-02 7.162e-02 1.083643e+04 5.461519e+03 8.715356e+02 -6.000000e+00 4.366178e+03 291.03 -2.00 20.00 -2.00 505.37 0.00e+00 -7.523420e-04 2.043484e-03 9.803082e-05 -6.000000e+00 2.136648e-03 291.03 -2.00 20.00 -2.00 500.39 0.00e+00 3.153709e+00 1.449024e+00 3.601677e-02 -6.000000e+00 1.486785e+00 231.36 -2.00 3.45 -2.00 502.00 0.00e+00 19.860 0.134 489.00 513.00 1 9.5496e+00 1.1109e-01 3.4098e-02 -6.0000e+00 1.1447e-01 4.3359e-02 2.7861e-02 2.2254e-03 -6.0000e+00 2.9479e-02 6.6652e-06 3.5657e-03 7.4532e-03 8.6430e-05 -6.0000e+00 8.4596e-03 -1.1156e-02 -1.9472e-04 12 8 8 10 0 0 44.46 21.33 9.52 -0.01116 0.01358 8 2 1 4 0 4000.000 26.41 20.00 21.33 900000 -1238 5952 -6476 781 -189 2730 1146 -6516 9798 -5554 -2813 -4908 -2022 14189 -81 587 -2557 26746 -5027 7418 -4171 7053 -932 -3994 3934 -3859 353 -8942 8741 8628 12015 5679 1384 4258 -8040 7746 9846 -15183 10085 -4797 -1431 -8036 -5680 -7260 -1004 1170 11346 9164 -7860 12731 -3488 -11849 3981 -15490 -159 -7343 11596 3068 9212 1463 1018 -364 7761 -976 1568 3821 -5773 -2742 -6138 -8666 6829 2770 11389 -2671 6403 -8236 -3544 8598 7596 2255 716 4289 564 14817 -129 -4460 9847 7524 -2609 9355 -5841 -8327 262 3885 5585 -3414 271 4839 2927 -11028 743 1710 6991 -5623 -6305 -4363 1449 -5322 -5970 7565 -6342 -3073 -2694 1786 2852 -5525 14678 -5725 3613 -6746 7126 13141 -505 19548 -6502 542 3628 7605 9422 -2494 -13176 -2198 -4963 7919 5640 -4858 -1211 -8745 -474 2347 -5339 -455 15663 1406 -862 2309 3513 -10568 14009 900000 -1167 5350 -6804 786 -192 2747 1187 -7315 9299 -6081 -2961 -5211 -2064 12261 -81 592 -2720 21730 -5708 7506 -4760 7215 -1036 -4595 4184 -4417 384 -10451 8361 8125 10938 5599 1465 4490 -9460 7980 9853 -18821 9888 -5307 -1537 -9297 -6479 -8476 -1104 1252 10839 8788 -8724 11200 -3527 -12875 3710 -17891 -161 -8191 10828 3130 8834 1516 1062 -386 7568 -1031 1594 3739 -6127 -2787 -6382 -9183 6204 2641 10060 -2661 5945 -8509 -3437 7487 6642 2030 658 3837 530 12190 -124 -4499 8602 6718 -2581 8254 -6045 -8866 254 3564 4899 -3180 237 3955 2414 -10504 644 1524 6156 -5790 -6463 -4383 1398 -5337 -6049 6927 -6577 -3108 -2730 1739 2767 -5881 12836 -6123 3481 -7100 6439 11109 -490 15590 -6754 526 3415 6872 8336 -2467 -14341 -2126 -4926 6966 5164 -5047 -1237 -9569 -484 2361 -5852 -478 14394 1452 -903 2310 3421 -11740 12194 SO 20190818T035230.1Z 7169.161459 217 1 32.20 2 88.90 74.05 66.70 239.01 0.00 1 0.00 1 0 29 4.722e-02 4.753e-02 3.983e-02 3.946e-02 1.216486e+04 3.087265e+03 5.844770e+02 -6.000000e+00 2.810112e+03 291.03 -2.00 20.00 -2.00 505.37 0.00e+00 2.077000e-03 1.132711e-03 1.375177e-04 -6.000000e+00 1.374453e-03 291.03 -2.00 20.00 -2.00 500.40 0.00e+00 1.711641e+00 8.046631e-01 1.151729e-01 -6.000000e+00 9.530273e-01 231.36 -2.00 3.45 -2.00 502.01 0.00e+00 18.255 0.104 489.00 513.00 1 9.2231e+00 6.1907e-02 3.1251e-02 -6.0000e+00 7.3462e-02 5.9713e-02 1.5310e-02 2.7770e-03 -6.0000e+00 1.8773e-02 1.2388e-05 9.9460e-04 4.1405e-03 5.0060e-05 -6.0000e+00 5.4292e-03 3.6587e-02 -3.5576e-04 12 8 8 10 0 0 22.67 21.34 4.88 0.03659 0.04349 8 2 1 4 0 4000.000 26.51 20.00 21.34 1903 -1561 2372 -3335 -6386 3187 -11752 6172 -3843 1377 -1511 -4024 3288 -9260 6267 -1757 3069 -844 -1431 923 2048 3346 601 8732 -6184 2060 -1112 7816 -2583 -7115 2440 -9178 4394 -95 2273 8994 -5098 2248 -3379 10608 -355 10700 2027 2159 879 -4336 5961 -2705 834 985 -692 1510 -3778 -3493 -6134 3428 -2895 5604 -942 858 2382 -4650 3429 -1222 305 3462 6672 4930 6605 1358 -5411 -413 -1587 120 4715 5352 2320 -6145 1622 -1391 10296 3345 2061 -3113 -2139 1346 -3813 1547 -2312 -871 -1259 -866 4588 -12276 2852 -7402 8699 1372 10778 773 925 -1881 911 8286 173 1532 -8 -894 4988 -740 791 -794 5851 -2327 1 -149 -5690 4468 -3815 3070 -490 421 4525 -4352 -1319 -9225 2448 474 1845 4778 -6072 9311 -7352 3995 -4781 5471 -1711 2501 2483 -1858 5024 -7583 3086 -7023 2210 6926 -11196 2319 1567 1021 1722 -1474 2208 -3393 -6901 3207 -13632 6211 -4172 1409 -1571 -4233 3256 -10017 5772 -1760 2967 -866 -1509 965 2134 3453 639 8597 -7100 2181 -1211 7695 -2766 -7781 2385 -10082 4287 -99 2387 8935 -5823 2367 -3729 10118 -378 10269 2091 2249 937 -4884 6033 -2952 863 995 -693 1448 -3783 -3511 -6469 3373 -3100 5580 -1006 900 2464 -5178 3531 -1316 322 3487 6411 4752 6181 1324 -5613 -408 -1599 120 4521 5070 2234 -6184 1530 -1312 8858 3101 1903 -3057 -2100 1285 -3837 1472 -2281 -847 -1237 -855 4309 -13557 2655 -7421 7203 1189 8325 653 782 -1673 817 7182 167 1481 -7 -880 4615 -712 759 -782 5440 -2363 1 -150 -6113 4360 -4032 2994 -487 409 4190 -4412 -1303 -9902 2344 463 1775 4447 -6244 8109 -7493 3627 -4772 5007 -1716 2447 2469 -1909 4986 -8401 3089 -7787 2226 6589 -12575 2240 1510 992 SO 20190818T035641.0Z 7169.164363 221 1 32.01 2 88.11 74.68 67.39 239.82 0.00 1 0.00 1 0 29 1.108e-02 1.083e-02 8.272e-03 8.209e-03 1.290186e+04 6.205833e+02 7.751482e+02 -6.000000e+00 6.590489e+02 291.03 -2.00 20.00 -2.00 505.54 0.00e+00 2.717292e-03 2.376724e-04 1.494876e-04 -6.000000e+00 3.222025e-04 291.03 -2.00 20.00 -2.00 501.10 0.00e+00 1.264042e+00 1.609906e-01 1.000659e-01 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