File name: Pandora119s1_Athens-NOA_20190825_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20251201T001809.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190825_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190825 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190825T035411.0Z 7176.162627 223 1 32.01 2 89.72 76.39 27.50 122.60 0.00 1 0.00 1 0 36 9.678e-02 9.561e-02 8.738e-02 8.562e-02 8.149814e+03 6.296442e+03 1.361450e+02 -6.000000e+00 5.749569e+03 290.56 -2.00 20.00 -2.00 505.36 0.00e+00 -5.474457e-04 2.431420e-03 6.393398e-05 -6.000000e+00 2.815589e-03 290.56 -2.00 20.00 -2.00 500.43 0.00e+00 2.736638e+00 1.728500e+00 1.186255e-01 -6.000000e+00 1.960648e+00 230.85 -2.00 3.45 -2.00 502.03 0.00e+00 19.870 0.134 489.00 513.00 1 9.7662e+00 1.3239e-01 3.5101e-02 -6.0000e+00 1.5094e-01 5.4101e-02 3.3586e-02 2.7128e-03 -6.0000e+00 3.8865e-02 5.5084e-06 -1.4149e-02 9.2200e-03 4.5883e-05 -6.0000e+00 1.1160e-02 -6.0663e-02 1.1181e-04 12 8 8 10 0 0 -2740.75 22.07 14.52 -0.06066 -0.15881 8 2 1 4 0 4000.000 27.05 19.99 22.07 900000 -5996 -21273 1489 -3095 -969 6858 -9553 15527 9918 7603 15409 -1352 -9241 -4088 18059 -19165 18114 -2530 -4288 12196 -5576 13087 -11791 1642 776 3985 4421 1065 -3078 10771 5968 -6917 -5154 874 738 7561 -574 22410 -2788 4053 6446 9507 224 -3020 1977 -22294 -11 -4525 12217 -130 2210 7497 1829 2002 -1183 10484 -1543 -1552 6004 3608 4483 -13025 3420 1788 -5619 4336 5719 -5423 -8538 1391 -14652 7074 4777 12989 6809 4746 690 -9634 12617 -6288 1873 -2743 -3856 19439 3135 17603 296 9960 719 4284 2847 -15115 9996 -15159 26618 -10311 11213 -1636 509 -7682 804 9414 1291 13837 3107 -8622 -4251 -9229 369 -14130 5261 -7006 18971 6467 631 16951 -13643 13120 6932 21552 -6361 10039 12059 -17918 -1199 -1684 -5943 -7302 9533 1052 3322 -642 3413 6760 -857 3355 10620 -16703 3317 1247 12663 -1149 24947 614 432 -4945 -19230 11957 -6830 900000 -5844 -24304 1387 -3116 -984 6607 -11066 14185 9623 7514 13937 -1428 -10432 -4337 15269 -22970 15562 -2658 -4694 11832 -6351 12421 -14391 1757 841 4186 4606 1135 -3356 9985 5704 -7512 -5585 917 795 7711 -634 19538 -3095 4169 6459 9275 242 -3399 2134 -29966 -12 -5012 11541 -136 2195 6900 1760 1881 -1170 9719 -1606 -1635 5888 3624 4464 -15491 3457 1834 -6163 4252 5448 -5691 -9126 1332 -16354 6359 4428 11202 6282 4450 665 -10131 10501 -6288 1728 -2667 -3822 15426 2960 14500 291 8889 686 3952 2680 -17178 8887 -17260 20150 -10745 9170 -1482 441 -7152 689 7560 1164 11432 2938 -9275 -4368 -9889 358 -15880 4920 -7492 15792 6142 639 14680 -15769 11939 6686 17761 -6662 9030 10570 -20710 -1177 -1668 -6152 -7663 8444 1012 3099 -616 3114 5946 -819 3123 9385 -19784 3270 1273 11657 -1225 20618 649 457 -5472 -23618 10836 -7391 SO 20190825T035829.0Z 7176.165613 227 1 32.01 2 88.89 77.05 26.81 124.12 0.00 1 0.00 1 0 15 4.887e-02 4.880e-02 4.495e-02 4.458e-02 9.570469e+03 3.280393e+03 7.494821e+02 -6.000000e+00 2.903281e+03 290.56 -2.00 20.00 -2.00 505.37 0.00e+00 6.862275e-04 1.268277e-03 7.898647e-05 -6.000000e+00 1.420862e-03 290.56 -2.00 20.00 -2.00 500.56 0.00e+00 1.314435e+00 8.944836e-01 4.318135e-02 -6.000000e+00 9.856629e-01 230.84 -2.00 3.45 -2.00 502.14 0.00e+00 18.238 0.104 489.00 513.00 1 9.4093e+00 6.8644e-02 2.9960e-02 -6.0000e+00 7.5975e-02 5.3060e-02 1.7263e-02 2.0593e-03 -6.0000e+00 1.9403e-02 1.0882e-05 -3.4753e-03 4.7715e-03 8.3451e-05 -6.0000e+00 5.6182e-03 8.9918e-03 -1.5438e-04 12 8 8 10 0 0 84.75 22.06 3.07 0.00899 -0.01511 8 2 1 4 0 4000.000 27.05 19.99 22.06 564 -2657 3971 4386 -898 -2507 10480 4221 3538 7644 -2535 4666 7712 -6834 -3313 -5723 3893 -1046 1261 -2491 1912 5578 -10456 60 -8165 2408 2112 2269 4160 2353 12009 -6853 1781 2830 -1962 -2878 -5338 -2597 -2928 6407 781 2308 5778 768 1727 412 1849 6854 -1664 -11887 4754 -5746 -2759 248 -6196 2922 -1851 -509 5125 151 -8541 -3561 -1830 3318 514 2740 -739 992 -7906 3403 2716 -343 -3027 3023 812 -3766 -10338 -128 9565 3330 2293 2273 10913 -1652 1109 2446 -7857 9408 1435 -2885 173 3183 179 3223 2898 -10464 9646 -2014 2123 -330 -2834 -792 -3936 -2340 5770 -7843 -2024 -3825 7305 -5828 6589 -4010 4429 -1992 2427 6194 -3700 2561 -3766 -1343 1280 7706 1843 1015 -3789 -2298 8637 2893 -1985 -4002 3584 2400 2088 -2395 -1208 -4709 4773 -3956 2338 3415 -7478 -5749 1058 -4473 1960 7820 -4844 4608 4803 12512 504 -2462 3520 3993 -888 -2588 9698 4216 3575 7380 -2680 4532 7172 -7266 -3377 -5987 3741 -1050 1266 -2642 1960 5535 -12214 63 -9392 2497 2191 2328 4114 2314 10517 -7222 1745 2818 -2105 -3165 -6026 -2833 -3174 6279 808 2363 5766 814 1832 445 1964 6855 -1739 -13460 4557 -5829 -2681 235 -6366 2814 -1914 -527 5043 156 -9653 -3841 -1947 3351 531 2737 -754 980 -8434 3207 2560 -334 -3044 2892 799 -3874 -11222 -123 8283 3051 2123 2117 9403 -1591 1050 2306 -8245 8517 1371 -2883 168 3038 177 3090 2748 -11069 8118 -1854 1834 -288 -2539 -707 -3753 -2284 5354 -8464 -2062 -3940 6701 -6116 6170 -4225 4331 -2042 2454 6071 -3941 2575 -4027 -1387 1268 7061 1777 987 -3881 -2328 7860 2789 -2006 -4116 3391 2271 1961 -2341 -1172 -4799 4512 -4159 2347 3437 -8485 -6313 1118 -4893 2054 7669 -5192 4524 4651 11203 SO 20190825T040237.0Z 7176.168484 231 1 32.01 2 88.10 77.68 26.15 125.65 0.00 1 0.00 1 0 22 2.777e-02 2.770e-02 2.280e-02 2.269e-02 1.219263e+04 1.727309e+03 8.407236e+02 -6.000000e+00 1.649303e+03 290.56 -2.00 20.00 -2.00 505.41 0.00e+00 1.431353e-03 6.529200e-04 5.071190e-05 -6.000000e+00 8.075432e-04 290.56 -2.00 20.00 -2.00 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