File name: Pandora119s1_Athens-NOA_20190827_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20251201T001802.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190827_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190827 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190827T035552.0Z 7178.163796 275 1 32.01 2 89.72 77.27 47.41 94.18 0.00 1 0.00 1 0 15 6.331e-02 6.203e-02 6.169e-02 6.101e-02 1.070769e+04 4.536536e+03 6.663769e+02 -6.000000e+00 3.759726e+03 290.42 -2.00 20.00 -2.00 505.34 0.00e+00 -3.068903e-03 1.736999e-03 1.364857e-04 -6.000000e+00 1.840615e-03 290.42 -2.00 20.00 -2.00 500.38 0.00e+00 5.374668e-01 1.228569e+00 8.193514e-02 -6.000000e+00 1.277358e+00 230.70 -2.00 3.45 -2.00 502.01 0.00e+00 19.879 0.134 489.00 513.00 1 9.6139e+00 9.4166e-02 3.4726e-02 -6.0000e+00 9.8448e-02 9.8095e-02 2.3747e-02 2.5828e-03 -6.0000e+00 2.5150e-02 7.8386e-06 -5.5860e-03 6.2766e-03 6.2216e-05 -6.0000e+00 7.2727e-03 -7.8537e-02 3.4098e-04 12 8 8 10 0 0 -1320.36 22.11 7.23 -0.07854 -0.11728 8 2 1 4 0 4000.000 27.05 19.99 22.11 2534 -12029 3054 9110 -5944 1356 -1206 587 -108 4046 -8036 -2037 -4306 -8662 -2223 -724 -846 -9289 7279 -4474 751 5163 4816 2195 -10018 15854 -1982 3630 -192 -7182 1520 4526 6 724 -22 -5002 2131 9781 3408 23626 5373 -7369 6936 1803 -900 9318 2848 -1998 899 6719 -1219 4270 -13019 6129 -3767 6845 -10412 -577 8708 -10393 3091 -10507 15702 7011 5478 2773 -6274 -3652 3104 -1764 -7473 -2271 1582 10172 -4471 -2014 4333 10585 6015 -148 1103 -3844 12058 1003 6197 4317 -3956 6907 973 -411 -6087 -1488 -2971 3720 9359 -3489 6983 -895 -7513 7926 -9661 3656 1593 2561 4886 2880 207 -8809 -6024 -3820 8655 4134 2947 4068 -3023 3611 -3799 -2876 3349 5546 -8606 824 -5404 4205 -1964 -3353 3128 -7176 3398 7309 4997 2247 10255 -5239 -4616 8623 1835 -5758 -1058 -7905 3388 -4580 10221 -6789 10502 -7423 -3560 9701 -4067 -5034 2321 -12375 2822 8154 -6208 1353 -1262 613 -115 4111 -9139 -2157 -4606 -9565 -2283 -733 -865 -10536 7168 -5060 816 5401 5068 2376 -11961 15013 -2235 3837 -208 -7925 1545 4428 7 742 -23 -5681 2263 9565 3515 20218 5345 -8324 6825 1881 -972 9126 2969 -2165 931 6426 -1230 3972 -14148 5486 -3776 6326 -11714 -598 8275 -11963 3108 -11823 13982 6812 5382 2771 -6600 -3689 2969 -1708 -7605 -2192 1480 8832 -4537 -1996 3989 9017 5294 -138 1012 -3728 10073 947 5631 4044 -4056 6368 952 -408 -6431 -1512 -3081 3596 8419 -3478 6084 -820 -7185 6408 -9312 3141 1448 2407 4545 2792 207 -9581 -6323 -3915 7873 3966 2879 3944 -3156 3543 -4044 -3052 3340 5360 -9436 808 -5579 3930 -1956 -3392 2968 -7543 3205 6606 4589 2097 8731 -5178 -4441 7543 1752 -5909 -1054 -8562 3317 -4902 9499 -7508 9760 -8198 -3734 8767 -4162 -5180 SO 20190827T040009.0Z 7178.166771 279 1 32.01 2 88.90 77.93 46.60 94.87 0.00 1 0.00 1 0 15 4.489e-02 4.323e-02 3.532e-02 3.501e-02 8.893987e+03 2.587191e+03 7.482816e+02 -6.000000e+00 2.665221e+03 290.42 -2.00 20.00 -2.00 505.34 0.00e+00 8.697109e-04 9.983153e-04 1.017734e-04 -6.000000e+00 1.304498e-03 290.42 -2.00 20.00 -2.00 500.41 0.00e+00 1.425364e+00 7.103018e-01 2.940312e-02 -6.000000e+00 9.046165e-01 230.70 -2.00 3.45 -2.00 502.02 0.00e+00 18.250 0.104 489.00 513.00 1 9.1487e+00 5.4687e-02 2.9897e-02 -6.0000e+00 6.9735e-02 7.0070e-02 1.3633e-02 1.9022e-03 -6.0000e+00 1.7793e-02 1.3969e-05 4.4409e-03 3.7711e-03 9.3074e-05 -6.0000e+00 5.1604e-03 8.4752e-04 -4.6826e-05 12 8 8 10 0 0 25.41 22.10 1.54 0.00085 0.03165 8 2 1 4 0 4000.000 27.05 19.99 22.10 2857 3691 -7669 7340 1916 7968 -4150 2762 4286 407 -2646 1146 2793 -1744 13506 -1017 -3229 2251 -1347 -857 -6125 1777 -3307 6393 -4318 -4690 1328 -2022 11451 -4356 -2305 -5556 -1476 1345 1423 -565 4454 4751 2100 -817 -2155 -2176 3870 -1628 3131 -269 1178 -5392 1198 -2345 -8397 5853 -2582 9478 -4266 -3683 3199 -1291 -1868 -2488 -211 1187 991 -1748 -2650 758 1548 -665 -1715 -612 753 -3779 -3191 5591 7939 -149 6088 -1399 457 -6389 293 10232 1893 1226 -5135 1484 1890 -5885 1503 -6838 5196 -3787 13863 -1671 1238 -4050 -2724 6345 1742 6350 -10979 4900 1992 3583 -3076 -34 6142 -3986 3007 -6486 10355 -708 1722 -6403 -3261 -556 -4879 -338 1353 2544 929 -4287 1079 -5824 3639 -71 -5397 8403 -3718 4473 587 4755 -917 5835 -145 -1419 4079 1270 2987 -6015 7696 -2157 1700 248 -2811 1104 1672 2094 -5576 5427 2572 3339 -7990 6792 1925 7712 -4493 2815 4302 421 -2786 1146 2713 -1755 11631 -1019 -3360 2267 -1436 -922 -6983 1878 -3686 6490 -4896 -5335 1414 -2195 10627 -4625 -2369 -5928 -1544 1407 1519 -604 4631 4882 2139 -853 -2283 -2321 3926 -1763 3258 -290 1243 -5994 1222 -2419 -8973 5321 -2540 8356 -4420 -3892 3216 -1369 -1998 -2678 -222 1238 1037 -1874 -2841 775 1546 -671 -1726 -603 730 -3844 -3177 5275 7333 -144 5461 -1333 424 -6325 272 8664 1759 1158 -5220 1420 1805 -6066 1439 -7141 4848 -3900 12006 -1676 1183 -3976 -2566 5325 1502 5191 -10767 4206 1827 3349 -3065 -33 5720 -3982 2797 -6686 9127 -705 1688 -6851 -3401 -569 -5244 -347 1359 2490 910 -4374 1040 -6032 3442 -70 -5607 7598 -3787 4176 564 4327 -875 5205 -139 -1398 3879 1264 2896 -6455 7263 -2261 1722 255 -2964 1107 1638 2012 -5743 5031 SO 20190827T040417.0Z 7178.169641 283 1 32.01 2 88.10 78.56 45.81 95.55 0.00 1 0.00 1 0 15 1.687e-02 1.688e-02 1.712e-02 1.704e-02 1.206153e+04 1.294467e+03 7.441249e+02 -6.000000e+00 1.001742e+03 290.42 -2.00 20.00 -2.00 505.38 0.00e+00 8.980700e-04 4.887306e-04 6.585246e-05 -6.000000e+00 4.902770e-04 290.42 -2.00 20.00 -2.00 500.57 0.00e+00 1.191416e+00 3.419384e-01 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