File name: Pandora119s1_Athens-NOA_20190901_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20251201T001749.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190901_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190901 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190901T040008.0Z 7183.166759 383 1 32.01 2 89.71 79.55 112.57 67.10 0.00 1 0.00 1 0 15 7.206e-02 6.941e-02 5.783e-02 5.705e-02 3.426424e+03 3.862257e+03 1.969544e+02 -6.000000e+00 4.272399e+03 290.08 -2.00 20.00 -2.00 505.36 0.00e+00 1.318558e-03 1.641677e-03 9.770461e-05 -6.000000e+00 2.092535e-03 290.08 -2.00 20.00 -2.00 500.41 0.00e+00 3.407566e+00 1.158434e+00 3.520237e-02 -6.000000e+00 1.453181e+00 230.33 -2.00 3.45 -2.00 502.04 0.00e+00 19.882 0.134 489.00 513.00 1 9.2834e+00 8.9683e-02 3.4109e-02 -6.0000e+00 1.1199e-01 4.8717e-02 2.2215e-02 1.9742e-03 -6.0000e+00 2.8618e-02 8.3743e-06 4.1303e-03 6.3671e-03 4.1248e-05 -6.0000e+00 8.2849e-03 5.4919e-02 -4.6170e-04 12 8 8 10 0 0 -201.65 21.41 1.13 0.05492 0.08357 8 2 1 4 0 4000.000 26.51 19.99 21.41 7271 17119 -11146 6139 -6567 11729 -5385 -8976 982 3198 18491 -9035 2020 -1156 -1053 567 -9987 9498 -6793 9517 2665 -2427 19 -9096 -1031 -10598 2793 -5190 -81 6120 -2238 9060 -7310 7469 -6731 7111 -7447 5315 12016 -1702 12811 -5252 12822 2238 1244 -4205 2787 522 5007 5327 -6015 4945 -8073 -4660 1750 -1242 6929 6125 11217 -3291 8758 7716 -6157 14887 1189 6077 1625 2348 1628 -8958 -1735 -17440 -1537 -7026 752 4855 2632 -3667 -10173 11587 -6061 -656 -2089 5844 -7507 3148 -759 985 10399 -230 5301 274 170 3861 -6773 8803 -2257 6662 -3010 -8416 1911 4816 17431 -5385 8326 -4868 3544 3890 1336 8939 -3770 6681 -3504 5484 -5375 -5367 -1444 -5144 16716 -3402 3429 -9211 -5690 7464 -7615 -2980 -9881 20833 4039 765 -8077 938 955 5060 16165 -1661 2726 -2308 6216 -5118 -2647 1496 -4675 4598 -3512 3323 -5937 -9208 6817 7776 6283 13578 -11739 5617 -7023 10697 -5933 -10352 1026 3241 15885 -10088 1994 -1166 -1058 564 -11209 8970 -7714 9310 2811 -2702 20 -10625 -1145 -12623 2970 -5751 -86 5942 -2271 8463 -7995 7248 -7698 7145 -8625 5371 11247 -1818 11844 -5856 12056 2365 1337 -4779 2936 555 4995 5169 -6371 4600 -8493 -4783 1723 -1293 6773 6092 10627 -3604 8511 7598 -6798 13613 1205 5932 1591 2251 1552 -9389 -1683 -19838 -1503 -7324 728 4471 2442 -3572 -10478 9570 -5988 -618 -2012 5243 -7763 2943 -739 943 9068 -224 4926 271 169 3701 -6963 7787 -2180 5745 -2801 -8174 1679 4193 13787 -5374 7367 -4925 3271 3548 1248 7800 -3788 6139 -3611 5219 -5746 -5773 -1501 -5541 14358 -3530 3282 -9921 -5911 6828 -8140 -3051 -10600 16844 3860 753 -8407 903 910 4615 13290 -1620 2598 -2356 5915 -5517 -2808 1533 -5127 4608 -3805 3326 -6408 -10098 6315 7161 SO 20190901T040424.0Z 7183.169722 387 1 32.01 2 88.89 80.21 111.84 67.87 0.00 1 0.00 1 0 15 3.185e-02 3.167e-02 3.219e-02 3.202e-02 4.007236e+03 2.180288e+03 4.562084e+02 -6.000000e+00 1.889198e+03 290.08 -2.00 20.00 -2.00 505.37 0.00e+00 2.170460e-03 9.216737e-04 1.172208e-04 -6.000000e+00 9.243674e-04 290.08 -2.00 20.00 -2.00 500.52 0.00e+00 2.682793e+00 6.479984e-01 2.196555e-02 -6.000000e+00 6.394245e-01 230.33 -2.00 3.45 -2.00 502.13 0.00e+00 18.237 0.104 489.00 513.00 1 8.9576e+00 5.0127e-02 2.9828e-02 -6.0000e+00 4.9320e-02 4.4865e-02 1.2441e-02 1.6569e-03 -6.0000e+00 1.2524e-02 1.5313e-05 -2.4088e-03 3.5760e-03 7.5015e-05 -6.0000e+00 3.6600e-03 -1.1460e-02 3.2248e-04 12 8 8 10 0 0 -6.21 21.41 4.70 -0.01146 -0.02817 8 2 1 4 0 4000.000 26.51 20.00 21.41 1805 -4670 -2497 4049 -3386 5114 958 2123 -2507 1346 48 195 2144 3152 -369 2003 4015 -999 317 -789 -2390 14 102 -2213 2795 3531 -4272 167 1642 -2909 3283 -6066 -678 -1519 -1961 -1690 -957 413 -5481 -2305 -3872 7496 -1401 -637 1859 3215 4226 -662 1040 1722 -1585 2260 -1512 14 -331 6228 5417 -3095 -3493 1006 6490 3927 2072 112 -3648 -2601 6855 -623 -1510 -667 -4734 1798 -5712 1179 -797 -5435 2852 -351 -3708 -3348 189 3231 -529 6133 -2392 -3184 1191 2208 -31 -3667 1958 -3583 3596 1102 4118 4435 4103 -2112 -2800 -1710 -2274 419 -1839 367 846 1599 7933 944 3055 1195 1652 3743 -88 -2825 4772 -1117 -3178 1364 -4767 -3559 -1542 582 2616 -5709 30 -2239 -1796 -4830 7084 -1849 2807 -4638 -3377 683 150 406 2006 406 3526 -2597 4266 -5115 4554 629 2593 5408 -899 3113 -5756 1609 1630 -4558 -2388 3845 -3473 4933 980 2168 -2680 1373 49 196 2085 3005 -363 1936 3860 -1032 330 -842 -2608 15 109 -2436 2939 3688 -4798 177 1679 -3040 3183 -6324 -683 -1588 -2106 -1825 -1023 432 -6019 -2441 -4174 7267 -1501 -685 1965 3359 4346 -705 1070 1717 -1593 2144 -1480 13 -331 5989 5354 -3362 -3819 1052 6435 4008 2156 116 -3874 -2697 6527 -615 -1485 -643 -4735 1690 -5836 1134 -784 -5552 2643 -331 -3587 -3218 176 2935 -503 5501 -2356 -3177 1139 2090 -30 -3701 1885 -3688 3470 1088 3895 4100 3718 -1988 -2601 -1555 -2089 382 -1727 347 808 1518 7017 889 2814 1132 1581 3562 -88 -2937 4634 -1158 -3378 1384 -5100 -3714 -1558 571 2513 -5988 30 -2287 -1829 -5070 6594 -1874 2691 -4620 -3290 638 142 390 1932 404 3452 -2733 4224 -5598 4549 655 2633 5276 -918 3003 -6023 1572 SO 20190901T040833.0Z 7183.172604 391 1 32.01 2 88.08 80.84 111.12 68.61 0.00 1 0.00 1 0 22 1.023e-02 1.006e-02 7.961e-03 7.929e-03 1.329387e+04 6.064735e+02 8.575308e+02 -6.000000e+00 6.066623e+02 290.08 -2.00 20.00 -2.00 505.43 0.00e+00 2.077526e-03 2.276467e-04 1.187070e-04 -6.000000e+00 2.970799e-04 290.08 -2.00 20.00 -2.00 500.75 0.00e+00 1.374622e+00 1.578823e-01 8.491277e-02 -6.000000e+00 2.061449e-01 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