File name: Pandora119s1_Athens-NOA_20190904_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20251201T001817.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190904_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190904 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190904T040240.0Z 7186.168519 390 1 32.03 2 89.71 80.95 148.60 43.24 0.00 1 0.00 1 0 15 5.846e-02 5.715e-02 5.329e-02 5.268e-02 4.550233e+03 3.691504e+03 1.403824e+02 -6.000000e+00 3.463005e+03 289.88 -2.00 20.00 -2.00 505.39 0.00e+00 2.131386e-03 1.516261e-03 8.213130e-05 -6.000000e+00 1.696233e-03 289.88 -2.00 20.00 -2.00 500.41 0.00e+00 3.943528e+00 1.066692e+00 6.488120e-02 -6.000000e+00 1.177237e+00 230.11 -2.00 3.45 -2.00 502.03 0.00e+00 19.889 0.134 489.00 513.00 1 9.1484e+00 8.2192e-02 3.4360e-02 -6.0000e+00 9.0737e-02 3.7844e-02 2.0502e-02 2.1774e-03 -6.0000e+00 2.3152e-02 9.0955e-06 -6.5343e-03 5.8475e-03 3.2132e-05 -6.0000e+00 6.7216e-03 6.8301e-02 -4.3931e-04 12 8 8 10 0 0 9.13 21.43 5.26 0.06830 0.02298 8 2 1 4 0 4000.000 26.51 20.00 21.43 -2136 1135 -5719 1790 145 -1375 -3163 -490 225 942 4084 -4556 7301 -9509 -1600 -7701 -3927 2916 7660 -2365 -410 3213 4952 -1236 -2444 13043 332 -1772 9777 4233 13993 -2547 6403 3424 -10979 3408 -3631 -3500 -10327 14417 -5233 3163 -398 -2302 7544 -7958 4097 -5653 2773 -704 -6977 -2331 -697 4393 -7644 1891 3259 3762 15160 -2908 9748 -5508 1962 -2081 6093 -1490 1140 11914 1210 15433 -2109 2826 -11489 -3075 -668 -5581 6628 -248 2656 -2569 1355 528 887 10330 -6250 -235 -3507 1495 5000 10955 -7153 -5908 4416 -509 -665 14086 -11579 -160 -2881 3248 4616 13607 1352 5980 2641 -10138 8174 -5929 3859 -5918 1815 2425 5468 4878 -2385 5828 -6695 -1188 4845 3695 1387 -5688 728 -5521 -5925 1635 286 4705 -9217 -1309 -7691 3080 -1807 -1003 307 4397 5038 -2700 -1740 -1578 -1394 3454 10290 756 -7046 5842 -3942 5817 -2780 -645 -1985 1023 -5647 1692 143 -1421 -3398 -520 238 985 4093 -4914 6902 -10513 -1623 -8315 -4129 2919 7480 -2598 -446 3387 5145 -1337 -2688 12648 356 -1921 9277 4145 12506 -2605 6068 3431 -13048 3563 -4080 -3900 -12205 13203 -5824 3252 -428 -2552 7657 -9478 4316 -6501 2884 -741 -7627 -2376 -689 4134 -8048 1905 3313 3858 13944 -3125 9469 -6091 2017 -2227 5967 -1556 1142 10545 1175 12845 -2073 2640 -12452 -3091 -659 -5768 5987 -236 2426 -2457 1245 491 827 8837 -6363 -227 -3507 1422 4587 9485 -7284 -6002 4188 -496 -644 11850 -12011 -144 -2612 2791 3801 10622 1194 5209 2437 -10733 7183 -5949 3493 -5930 1704 2299 5100 4630 -2456 5568 -7299 -1229 4703 3590 1362 -5929 708 -5598 -6066 1559 277 4478 -9842 -1291 -8034 2858 -1741 -953 289 4020 4668 -2757 -1790 -1642 -1463 3481 9749 792 -7974 5772 -4234 5569 -2863 -650 SO 20190904T040700.0Z 7186.171528 394 1 32.01 2 88.87 81.62 148.05 44.84 0.00 1 0.00 1 0 15 2.954e-02 2.964e-02 2.859e-02 2.844e-02 8.627052e+03 2.088276e+03 4.575673e+02 -6.000000e+00 1.749901e+03 289.88 -2.00 20.00 -2.00 505.37 0.00e+00 2.463572e-03 8.153854e-04 1.431192e-04 -6.000000e+00 8.572154e-04 289.88 -2.00 20.00 -2.00 500.51 0.00e+00 1.581834e+00 5.730200e-01 8.298622e-02 -6.000000e+00 5.950964e-01 230.11 -2.00 3.45 -2.00 502.11 0.00e+00 18.203 0.103 489.00 513.00 1 8.9085e+00 4.4191e-02 3.0498e-02 -6.0000e+00 4.5865e-02 5.8233e-02 1.0913e-02 2.3090e-03 -6.0000e+00 1.1707e-02 1.7317e-05 4.5483e-03 3.0926e-03 5.3446e-05 -6.0000e+00 3.3952e-03 1.1529e-02 -1.3139e-04 12 8 8 10 0 0 68.98 21.45 3.42 0.01153 0.04308 8 2 1 4 0 4000.000 26.73 20.00 21.45 -3112 3298 -6795 5328 -1115 -570 -52 -5151 1887 -4053 4128 -491 3849 1518 -3931 -3073 -4181 608 491 2729 -1623 -62 1663 -3958 327 -4377 3244 -2410 -1254 -992 -554 1975 -3612 2082 1137 2476 -1866 2601 1452 1053 3446 2638 9126 5370 4362 577 -4546 2296 -4303 1924 -761 3852 1733 -2738 -312 -2313 -1164 851 1729 5116 -1311 2535 -1800 2345 -2652 594 4245 1969 249 -1912 2807 -3620 6309 474 -1897 1047 -3186 -1566 -4008 482 -1831 365 -1083 3503 -3843 -6036 1904 -1181 4177 562 2637 -1960 -5678 1146 -1494 4099 -1814 2728 883 -863 -1611 470 -851 4156 4784 -1820 661 -728 3720 2506 -997 4038 470 -2251 1403 -1687 1421 2979 1040 887 2069 -1329 -1053 -7837 -1673 642 2537 1894 459 2877 -771 -4000 1870 -2943 2976 433 -493 2653 5361 -4002 -2973 -3252 -4061 2518 1108 -979 857 -129 1470 -4314 -2887 2910 -6820 4891 -1124 -584 -54 -5671 1935 -4369 4046 -497 3682 1472 -4010 -3127 -4367 618 510 2809 -1756 -67 1751 -4317 343 -4817 3290 -2551 -1284 -990 -543 1899 -3749 2100 1183 2563 -2009 2656 1486 1078 3454 2689 8817 5450 4509 620 -5117 2383 -4682 1921 -761 3611 1651 -2760 -315 -2441 -1238 895 1765 5178 -1384 2584 -1919 2392 -2819 603 4093 1916 244 -1892 2638 -3641 5796 466 -1913 1016 -3181 -1516 -3941 452 -1761 346 -1049 3271 -3896 -6288 1833 -1171 3923 549 2545 -1953 -5898 1105 -1452 3763 -1679 2410 780 -750 -1420 415 -790 3794 4430 -1809 638 -708 3460 2380 -994 3878 472 -2344 1419 -1772 1458 3012 1065 897 2038 -1340 -1056 -8246 -1663 626 2429 1825 448 2727 -750 -3971 1735 -2863 2752 418 -489 2596 5179 -4294 -3185 -3514 -4444 2581 1146 -1021 863 -129 1438 -4494 SO 20190904T041110.1Z 7186.174422 398 1 32.20 2 88.06 82.25 147.50 46.33 0.00 1 0.00 1 0 22 1.020e-02 1.008e-02 8.149e-03 8.121e-03 1.276925e+04 6.157868e+02 7.911136e+02 -6.000000e+00 6.040645e+02 289.88 -2.00 20.00 -2.00 505.40 0.00e+00 2.744416e-03 2.326314e-04 1.501222e-04 -6.000000e+00 2.959910e-04 289.88 -2.00 20.00 -2.00 500.65 0.00e+00 1.379812e+00 1.621258e-01 8.840160e-02 -6.000000e+00 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