File name: Pandora119s1_Athens-NOA_20190905_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20251201T001810.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190905_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190905 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190905T040331.0Z 7187.169109 390 1 32.01 2 89.71 81.42 157.52 23.89 0.00 1 0.00 1 0 22 7.729e-02 7.393e-02 7.405e-02 7.300e-02 -1.007528e+03 4.406690e+03 4.062881e+02 -6.000000e+00 4.578578e+03 289.81 -2.00 20.00 -2.00 505.30 0.00e+00 2.719955e-03 2.073899e-03 8.352415e-05 -6.000000e+00 2.243186e-03 289.81 -2.00 20.00 -2.00 500.35 0.00e+00 3.226910e+00 1.452443e+00 4.627158e-02 -6.000000e+00 1.557747e+00 230.04 -2.00 3.45 -2.00 501.97 0.00e+00 19.889 0.134 489.00 513.00 1 9.5396e+00 1.1204e-01 3.4150e-02 -6.0000e+00 1.2005e-01 7.1663e-02 2.8073e-02 1.9013e-03 -6.0000e+00 3.0651e-02 6.4821e-06 9.9913e-03 8.1660e-03 7.8065e-05 -6.0000e+00 8.8837e-03 -1.8249e-02 2.6757e-05 12 8 8 10 0 0 14.01 21.36 7.15 -0.01825 0.05106 8 2 1 4 0 4000.000 26.51 20.00 21.36 -2637 2017 4801 3718 -5475 786 -12612 -10282 -4353 -8950 -7003 -9087 7930 951 8129 5311 -1513 -7190 -3133 15116 2400 15430 -6235 10478 4524 -7964 7684 3662 1297 -5415 433 2097 5969 -8328 11686 9024 -11782 5972 7561 2654 1239 -476 5995 -8330 6954 549 -792 7308 1725 9830 32 8377 -10321 10719 -7379 9758 4911 3567 2062 -6441 4047 -807 4082 -166 -11185 11990 -6388 -5210 1106 1074 1122 -521 4147 2736 11579 -529 12145 -3456 -3925 -7279 -1665 14965 -4996 10329 -8033 -3962 -6326 844 10203 2409 364 -11676 18058 -5734 13560 3405 -5047 -2252 -3859 -7634 -4181 13040 -2104 6559 -1968 -2134 214 -7908 -4666 13744 3169 3335 -5101 2959 -347 15842 -5542 -1216 9229 -4591 3309 -1016 17763 -13000 18921 8789 8302 15237 -6267 26164 1690 -4128 -6537 951 -3424 -1130 -10294 285 -9552 -13031 -69 -3313 6897 877 -4242 -458 -1767 2954 -602 -1247 -2544 1891 4511 3644 -5884 810 -15098 -12095 -4809 -10242 -7751 -10125 7557 938 7452 5048 -1567 -8053 -3432 13942 2525 14289 -7193 10276 4726 -9414 7709 3764 1333 -5819 435 2092 5865 -9703 11350 9036 -14066 6070 7500 2757 1277 -504 6014 -9746 7027 591 -857 7184 1755 8996 31 7466 -11073 9455 -7997 9127 4899 3631 2133 -7253 4112 -863 4155 -175 -13046 10929 -6889 -5475 1077 1036 1078 -511 3917 2639 10214 -521 10379 -3325 -3768 -7224 -1569 12323 -4932 8810 -8288 -3939 -6447 801 8849 2274 355 -13007 15079 -6080 11760 3221 -5090 -2158 -3685 -7494 -3985 10656 -2050 5970 -1960 -2114 205 -8145 -4664 11575 3021 3153 -5331 2885 -352 13735 -5946 -1241 8388 -4733 3123 -997 14502 -14514 15415 7942 7545 12918 -6582 19764 1612 -4119 -6614 891 -3381 -1110 -11296 286 -10444 -14868 -69 -3470 6714 886 -4479 -459 -1757 2756 -580 -1217 SO 20190905T040748.0Z 7187.172083 394 1 32.01 2 88.88 82.08 157.19 26.27 0.00 1 0.00 1 0 15 3.603e-02 3.555e-02 3.987e-02 3.957e-02 4.963579e+03 2.761080e+03 3.057449e+02 -6.000000e+00 2.134225e+03 289.81 -2.00 20.00 -2.00 505.36 0.00e+00 1.249642e-03 1.127489e-03 3.914829e-05 -6.000000e+00 1.045370e-03 289.81 -2.00 20.00 -2.00 500.38 0.00e+00 2.745982e+00 7.974558e-01 4.085184e-02 -6.000000e+00 7.253122e-01 230.04 -2.00 3.45 -2.00 502.00 0.00e+00 18.223 0.103 489.00 513.00 1 9.1880e+00 6.1379e-02 2.9818e-02 -6.0000e+00 5.5909e-02 5.2460e-02 1.5328e-02 1.8450e-03 -6.0000e+00 1.4255e-02 1.2258e-05 5.1674e-03 4.3667e-03 1.8349e-05 -6.0000e+00 4.1428e-03 2.6625e-02 -1.4796e-04 12 8 8 10 0 0 84.15 21.36 3.82 0.02663 0.06247 8 2 1 4 0 4000.000 26.51 20.00 21.36 -1521 -2805 -324 -5710 489 3234 -2852 260 -5803 2159 2735 696 -66 -1360 4160 -2275 4742 -4392 -340 -6465 -1359 3509 4765 3918 3698 -1131 -175 2268 4791 -1324 -1466 -3123 4991 -1720 1933 -3547 3392 -3144 -2174 -1126 1525 -502 -1740 -987 -2037 2268 4499 -6535 -1056 5779 -1827 1962 2416 1340 2374 7461 -741 -630 -2587 -3504 1806 -1249 4210 7396 3431 -2072 -5001 -1798 -2484 -1511 2343 -1161 -2603 2040 5874 1714 -4438 -5127 9300 156 4633 4024 -2604 3042 -747 -164 8812 -877 -1270 -2037 1180 2892 1576 -54 2980 69 -6341 2792 -2881 3223 9071 2710 1281 -3724 -1464 -368 -2591 -4550 1662 338 -597 -273 -853 4741 5812 2248 2101 3702 -1466 2727 -4893 -403 -2398 -1220 -797 -8899 -3931 275 -3762 -2600 -3074 1738 2593 9092 -4107 1026 -944 -1501 -632 1425 -1782 -5983 1842 -8838 3182 3826 5266 6441 2096 291 -1430 -2713 -315 -6041 500 3290 -3053 279 -6439 2249 2796 698 -66 -1363 3937 -2313 4573 -4746 -360 -7366 -1480 3649 4908 4086 3879 -1243 -189 2358 4749 -1363 -1497 -3267 4922 -1865 2062 -4020 3567 -3497 -2374 -1212 1601 -528 -1874 -1066 -2237 2385 4592 -7342 -1100 5484 -1824 1852 2262 1285 2308 7065 -775 -664 -2781 -3801 1861 -1330 4248 7197 3438 -2163 -5294 -1818 -2497 -1490 2214 -1141 -2619 1975 5477 1649 -4365 -5009 7996 147 4180 3678 -2502 2788 -717 -158 7733 -848 -1233 -2003 1134 2759 1531 -53 2793 65 -6224 2442 -2618 2734 7317 2386 1183 -3719 -1451 -361 -2578 -4582 1574 327 -578 -267 -848 4494 5489 2215 2081 3602 -1489 2621 -5009 -391 -2375 -1199 -784 -9513 -4003 268 -3817 -2595 -3051 1623 2382 7822 -4072 984 -942 -1532 -649 1448 -1842 -6490 1857 -9921 3150 3716 4952 5895 1992 283 SO 20190905T041157.0Z 7187.174965 398 1 32.01 2 88.07 82.72 156.84 28.52 0.00 1 0.00 1 0 22 1.635e-02 1.629e-02 1.509e-02 1.502e-02 1.056432e+04 1.129161e+03 6.821636e+02 -6.000000e+00 9.685384e+02 289.81 -2.00 20.00 -2.00 505.40 0.00e+00 1.863877e-03 4.307725e-04 1.053659e-04 -6.000000e+00 4.745080e-04 289.81 -2.00 20.00 -2.00 500.55 0.00e+00 1.813350e+00 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