File name: Pandora119s1_Athens-NOA_20190913_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20251201T001830.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190913_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190913 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190913T041016.0Z 7195.173796 253 1 32.01 2 89.71 85.25 102.90 264.15 0.00 1 0.00 1 0 60 2.072e-01 1.780e-01 2.062e-01 1.912e-01 3.319465e+04 1.690428e+04 2.044860e+03 -6.000000e+00 1.224554e+04 289.27 -2.00 20.00 -2.00 505.41 0.00e+00 1.244039e-02 5.525397e-03 6.781320e-04 -6.000000e+00 6.008824e-03 289.27 -2.00 20.00 -2.00 500.62 0.00e+00 -1.467779e+00 3.911174e+00 2.308959e-01 -6.000000e+00 4.194275e+00 229.45 -2.00 3.45 -2.00 502.14 0.00e+00 19.908 0.135 489.00 513.00 1 1.0676e+01 3.0109e-01 4.2193e-02 -6.0000e+00 3.2274e-01 1.0599e-01 7.3404e-02 5.4698e-03 -6.0000e+00 8.3168e-02 2.3253e-06 1.3158e-02 1.7715e-02 2.7919e-04 -6.0000e+00 2.3887e-02 1.9209e-02 -4.0659e-04 12 8 8 10 0 0 64.98 21.27 14.71 0.01921 0.11048 8 2 1 4 0 4000.000 26.41 19.98 21.27 900000 20193 45963 28599 -8107 -15843 -28400 8743 2261 16445 39137 14606 -20682 25362 17024 3860 30789 -27476 -24485 25049 1163 -1115 21606 -730 -11059 10776 -24454 -5960 60935 1801 67506 29925 1938 -22562 21925 -5086 14402 597 36240 -4548 -18104 7879 34272 14866 21661 15690 740 5796 -12724 9566 -12214 -20002 32699 5947 11378 -21049 291 20943 5990 19777 1649 -6110 77325 596 13520 -2548 -1440 6402 -17528 -22609 -12941 8076 17121 -1083 26588 -2046 -1964 -5449 1260 6996 -10564 10092 3879 12499 665 16657 -12858 43755 -1122 9626 40890 2479 12499 -15305 -16885 7297 8122 24563 -3293 -12299 1086 -15202 17262 9806 1267 16786 41238 -12346 19693 -39319 14117 2166 1654 16992 9869 9954 -3994 37444 -21333 54468 2131 -3507 8439 24493 7590 -22387 -7899 15762 26949 -19222 12100 21644 -256 14725 843 -16070 -28150 17212 5840 5663 1448 -6844 21806 1177 34067 -9126 -7612 7133 6542 -8172 900000 15995 29027 22194 -9070 -19537 -40195 8552 2341 14547 27858 12692 -25182 19818 13996 3636 23069 -35472 -31114 20072 1186 -1166 18100 -771 -12710 10261 -32065 -6397 34569 1752 34684 21955 1926 -28671 18710 -5562 13264 610 26588 -4905 -22639 7739 27106 14150 19520 15093 824 6074 -15782 9298 -14470 -25316 24501 5931 11060 -28327 331 19615 6550 18924 1853 -7470 43454 681 13826 -2939 -1618 6565 -22552 -30314 -15693 7962 15529 -1186 22615 -2228 -2101 -5936 1267 6587 -11822 9204 3787 11276 679 14451 -14831 29019 -1123 8636 27740 2420 10967 -17277 -18562 6007 6366 15862 -2759 -11216 878 -14987 12934 8315 1212 13985 27037 -13521 16212 -57789 12341 2154 1661 14690 9243 9466 -4451 28610 -27773 34368 2159 -3689 7823 19411 7182 -28097 -8840 13930 21228 -23224 10810 17361 -255 12660 842 -18814 -37703 15212 5716 5623 1512 -7788 19062 1224 25853 -10257 -8306 6647 6128 -8955 SO 20190913T041438.0Z 7195.176829 257 1 32.01 2 88.86 85.93 103.73 264.80 0.00 1 0.00 1 0 22 1.168e-01 1.097e-01 1.028e-01 9.979e-02 2.743607e+04 8.565174e+03 1.450170e+03 -6.000000e+00 6.906747e+03 289.27 -2.00 20.00 -2.00 505.48 0.00e+00 3.565357e-03 2.885202e-03 1.909592e-04 -6.000000e+00 3.385543e-03 289.27 -2.00 20.00 -2.00 500.62 0.00e+00 2.228792e+00 1.995204e+00 2.355135e-01 -6.000000e+00 2.350030e+00 229.45 -2.00 3.45 -2.00 502.20 0.00e+00 18.184 0.103 489.00 513.00 1 1.0118e+01 1.5408e-01 3.5374e-02 -6.0000e+00 1.8114e-01 -2.9709e-03 3.6820e-02 5.2160e-03 -6.0000e+00 4.6151e-02 4.6436e-06 1.3705e-02 9.5277e-03 4.8673e-05 -6.0000e+00 1.3431e-02 -2.4795e-02 2.0432e-04 12 8 8 10 0 0 -211.45 21.25 11.99 -0.02480 0.07027 8 2 1 4 0 4000.000 26.41 19.98 21.25 9955 4707 -5897 3954 16087 -8503 -1901 13764 -3085 -5188 1725 6152 -11622 9746 -6299 -10636 16179 -4293 20366 -11238 14404 11871 -4253 -5163 -4998 1126 -1400 20130 1542 23863 -9173 -9538 3948 -18043 13831 2146 4074 1163 5192 6346 1211 -282 -17544 9417 5038 12510 -10591 -6224 5387 -4744 3042 -3705 10671 -5068 5593 8627 -21065 26678 5222 31153 -1284 -3292 11381 -2498 -1099 -11605 20708 84 4693 -5316 -8336 2610 -1172 27979 -1285 14139 -587 3091 -9443 -19134 11833 -8963 -7453 -16766 -658 -5112 5893 27690 -1981 20726 -37 -6430 5369 -581 -2700 -10287 7931 -15526 11299 -9951 6832 7808 15662 13280 -6191 23804 -9228 -5468 11111 -21082 23123 -12362 20738 -7288 9803 2505 -1028 21536 -10756 30680 -8600 20170 -7938 -3210 -1574 -10776 3652 8416 22572 9232 -3862 2458 -5211 -2016 5370 3020 -7060 15664 10725 10603 9163 -19393 385 -3652 7765 14192 -7857 -5225 -6320 4276 8061 4119 -5928 3717 13752 -9249 -2011 12491 -3212 -5453 1712 5768 -12556 8674 -6436 -11491 13993 -4543 17124 -13075 13027 11055 -4678 -5767 -5595 1183 -1495 17025 1534 18665 -9977 -10584 3937 -22460 13016 2271 4202 1225 5229 6329 1251 -300 -22425 9297 5227 12022 -12704 -7036 5305 -5045 2931 -3781 9492 -5390 5495 8415 -28030 22140 5379 24813 -1420 -3728 11127 -2787 -1196 -13481 17580 87 4566 -5679 -8966 2595 -1192 21884 -1307 12442 -574 2871 -9848 -21915 10215 -9369 -7755 -19359 -651 -5284 5419 20800 -1946 16260 -36 -6646 4849 -538 -2445 -9627 5982 -14494 7996 -8779 5248 6234 12214 11098 -6307 18563 -9778 -5582 9906 -25598 18625 -13913 17186 -7838 8982 2512 -1084 18216 -12448 23569 -9367 16281 -8483 -3292 -1599 -12079 3554 7807 18117 8397 -3960 2352 -5403 -2049 5165 3035 -7813 14389 10534 10343 9162 -25942 423 -4155 7817 13245 -9043 -5828 -7162 4419 SO 20190913T041849.0Z 7195.179734 261 1 32.01 2 88.03 86.57 104.51 265.42 0.00 1 0.00 1 0 22 4.449e-02 4.404e-02 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