File name: Pandora119s1_Athens-NOA_20190921_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20251201T001835.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190921_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190921 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190921T041706.0Z 7203.178542 233 1 32.01 2 89.71 89.18 20.80 214.22 0.00 1 0.00 1 0 15 5.477e-02 5.332e-02 5.513e-02 5.452e-02 1.391602e+04 4.224215e+03 8.103531e+02 -6.000000e+00 3.225903e+03 288.47 -2.00 20.00 -2.00 505.32 0.00e+00 2.322963e-03 1.551418e-03 1.025886e-04 -6.000000e+00 1.584501e-03 288.47 -2.00 20.00 -2.00 500.29 0.00e+00 1.556341e+00 1.106067e+00 1.058116e-01 -6.000000e+00 1.104933e+00 228.72 -2.00 3.45 -2.00 501.90 0.00e+00 19.926 0.135 489.00 513.00 1 9.3469e+00 8.5007e-02 3.5194e-02 -6.0000e+00 8.5074e-02 8.5870e-02 2.1183e-02 2.9666e-03 -6.0000e+00 2.1798e-02 8.6937e-06 -6.5606e-05 5.6665e-03 5.1434e-05 -6.0000e+00 6.2899e-03 6.9400e-02 -7.0518e-04 12 8 8 10 0 0 59.33 20.61 3.52 0.06940 0.06894 8 2 1 4 0 4000.000 25.90 20.00 20.61 -9980 2704 -8715 6057 -1751 2444 -2323 -4130 -5438 -1311 3380 4919 8488 -891 7625 -3131 -6296 -2552 1913 364 -2011 1976 -3396 5380 -1221 2751 -2145 2680 6278 11997 -1815 7002 -2670 2766 -3339 3779 -2527 -235 -538 -1119 -691 -17 10206 2029 11106 -6193 -8739 1035 -2096 -1373 -3007 611 3010 3455 1377 -7857 -6169 502 3101 -38 -215 6522 -2625 3932 -5258 16243 2630 5521 -3100 -6088 5095 -317 4363 -4480 3066 -5147 3492 -4585 -5636 10818 2175 973 4269 -506 -2667 791 160 -5284 3152 -4332 6479 7709 -314 -2445 -8223 5170 757 6264 -11590 5150 -2676 -4751 -1434 5435 5856 1539 984 -9294 2882 -8299 -1181 8568 4043 5311 2947 -4758 791 -740 -631 -2637 -5238 4016 11272 2543 -6777 -2512 9802 13616 9590 -4413 1546 -1304 -3443 -10046 3102 1149 198 8784 10373 -9153 -1084 6275 -598 -1390 7237 -2049 -9651 6193 -2994 -8148 -10186 2441 -9017 5577 -1797 2467 -2508 -4598 -6154 -1415 3440 4861 7983 -909 7096 -3249 -6815 -2712 1987 390 -2228 2111 -3838 5589 -1327 2879 -2350 2772 6311 11114 -1845 6664 -2765 2784 -3668 3923 -2797 -253 -574 -1192 -732 -18 9856 2151 10861 -7235 -10450 1111 -2285 -1454 -3155 604 2869 3289 1363 -8760 -6921 534 3233 -40 -227 6602 -2847 3991 -5814 14684 2617 5258 -3175 -6350 4715 -310 4090 -4631 2956 -5369 3297 -4617 -5661 9145 2001 909 3888 -488 -2653 766 156 -5434 2968 -4391 5918 7011 -311 -2462 -8400 4598 681 5179 -10918 4147 -2330 -4197 -1268 4798 5196 1452 936 -9748 2666 -8618 -1154 7680 3824 4989 2849 -5003 795 -760 -648 -2735 -5487 3773 9752 2399 -7047 -2514 8697 11638 8522 -4389 1473 -1232 -3289 -10209 2777 1064 189 7821 9235 -10047 -1110 6018 -618 -1450 6904 -2126 -10655 5742 -3008 -8613 SO 20190921T042130.0Z 7203.181597 237 1 32.01 2 88.84 89.86 21.29 216.68 0.00 1 0.00 1 0 15 3.125e-02 3.101e-02 3.108e-02 3.090e-02 6.284955e+03 2.177412e+03 3.271740e+02 -6.000000e+00 1.840472e+03 288.47 -2.00 20.00 -2.00 505.34 0.00e+00 1.318933e-03 8.794309e-04 7.658838e-05 -6.000000e+00 9.037695e-04 288.47 -2.00 20.00 -2.00 500.43 0.00e+00 2.161966e+00 6.230785e-01 6.416468e-02 -6.000000e+00 6.296893e-01 228.72 -2.00 3.45 -2.00 502.04 0.00e+00 18.170 0.102 489.00 513.00 1 8.9878e+00 4.7954e-02 2.9978e-02 -6.0000e+00 4.8496e-02 5.5674e-02 1.1973e-02 2.0519e-03 -6.0000e+00 1.2406e-02 1.5716e-05 2.5018e-03 3.3725e-03 3.0341e-05 -6.0000e+00 3.5918e-03 9.2775e-02 -7.3942e-04 12 8 8 10 0 0 39.54 20.60 2.01 0.09277 0.11013 8 2 1 4 0 4000.000 25.90 20.00 20.60 -267 -6109 184 -5305 -158 6379 -573 253 -7 -304 -6334 2284 2705 2218 7949 -4815 -60 -3759 771 1855 -68 1208 -1389 2514 -750 2481 -3678 5194 -1715 1260 198 -745 626 -2334 753 -1319 -5132 1964 1143 3365 -1300 6477 6034 507 4001 -55 -2073 -3152 -380 778 -2611 2198 -2490 2021 -516 2762 269 -1373 375 -2721 1964 -2215 4006 -2673 -724 -1656 3506 2930 -3614 657 -3263 5523 -3301 5903 1985 -1972 -2472 -4781 2530 114 1270 1010 -3073 4435 -208 -990 -162 -2889 1167 1410 1383 1119 -1740 -7742 6661 -399 3084 -2321 -209 3058 868 -950 -6325 2902 -1940 3611 1291 -4586 883 -6030 215 390 5484 136 327 3602 3418 4594 2695 5755 -1949 -2353 257 -268 -256 -2297 -128 -1145 2380 -98 -6408 3505 -1158 3128 962 4598 -1946 -3125 -3305 -5297 1274 1482 7729 897 -2764 -1031 -3477 770 -1447 1524 -248 -5924 172 -5408 -158 6101 -599 265 -7 -318 -6949 2268 2640 2153 7252 -5014 -60 -4013 803 1941 -73 1286 -1522 2658 -823 2637 -4034 5283 -1831 1274 200 -740 624 -2466 790 -1428 -5758 2035 1182 3385 -1371 6360 6012 539 4147 -60 -2276 -3457 -398 787 -2662 2092 -2462 1925 -515 2740 279 -1464 395 -2952 2035 -2342 4088 -2838 -748 -1705 3377 2798 -3638 627 -3220 5001 -3291 5419 1903 -1955 -2428 -4735 2306 106 1170 938 -2998 4052 -201 -970 -158 -2891 1121 1356 1340 1098 -1770 -8138 6125 -385 2804 -2172 -187 2624 764 -868 -6147 2659 -1908 3382 1231 -4602 837 -6160 209 383 5183 136 331 3547 3393 4514 2684 5490 -1980 -2374 251 -265 -254 -2332 -128 -1151 2306 -97 -6543 3277 -1096 2828 894 4186 -1929 -3193 -3435 -5684 1292 1511 7440 927 -2953 -1072 -3644 760 -1446 1481 SO 20190921T042543.0Z 7203.184526 241 1 32.01 2 88.01 90.51 21.78 218.95 0.00 1 0.00 1 0 15 1.734e-02 1.726e-02 1.665e-02 1.658e-02 7.567053e+03 1.191407e+03 4.858071e+02 -6.000000e+00 1.021387e+03 288.47 -2.00 20.00 -2.00 505.38 0.00e+00 2.026205e-03 4.734468e-04 1.140693e-04 -6.000000e+00 5.014190e-04 288.47 -2.00 20.00 -2.00 500.55 0.00e+00 2.027639e+00 3.327217e-01 5.775759e-02 -6.000000e+00 3.490834e-01 228.72 -2.00 3.45 -2.00 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