File name: Pandora119s1_Athens-NOA_20191015_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20251201T003713.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20191015_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20191015 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191015T043848.0Z 7227.193611 241 1 32.01 2 89.72 100.91 78.46 272.17 0.00 1 0.00 1 0 15 5.761e-02 5.692e-02 5.155e-02 5.101e-02 3.577040e+03 3.432967e+03 3.925587e+02 -6.000000e+00 3.358762e+03 285.75 -2.00 20.00 -2.00 505.35 0.00e+00 3.935969e-03 1.443830e-03 1.567406e-04 -6.000000e+00 1.654551e-03 285.75 -2.00 20.00 -2.00 500.33 0.00e+00 1.876183e+00 1.036510e+00 2.315044e-02 -6.000000e+00 1.154741e+00 226.37 -2.00 3.45 -2.00 501.96 0.00e+00 20.012 0.137 489.00 513.00 1 9.2491e+00 7.9707e-02 3.4519e-02 -6.0000e+00 8.8936e-02 1.0424e-01 2.0108e-02 1.8902e-03 -6.0000e+00 2.2624e-02 9.2131e-06 -6.5019e-03 5.6769e-03 7.2199e-05 -6.0000e+00 6.6188e-03 -3.4669e-03 2.0279e-04 12 8 8 10 0 0 94.49 20.26 6.06 -0.00347 -0.04857 8 2 1 4 0 4000.000 25.58 20.01 20.26 -2865 10587 -7392 -1962 1266 -1586 2732 -7017 6743 -11772 1911 902 -3684 1669 -2143 11580 -2562 -824 -6223 -3610 656 1179 2521 700 3995 -7128 2645 6329 1177 424 -7337 3440 -9414 8144 3274 -1267 4932 -4132 617 -2741 4965 3032 11539 7300 -7500 3677 5442 1105 -10014 3807 5305 -776 -1182 -9472 -1616 -4329 7130 -2986 494 -971 795 6138 -324 5937 2110 17007 4661 -1591 -7821 1904 5529 239 10457 601 1933 -11907 -4472 3114 -8035 6491 -5269 9738 2678 1398 1991 3162 13000 -722 9086 -5487 10973 2312 -4290 6214 517 7725 -3894 6551 1328 -972 1913 -7900 12472 -1662 7579 6201 -4362 2784 -9505 2272 -7674 2692 910 -1095 8519 -8648 627 -829 5414 -7971 -1041 5634 -789 -6347 -5290 -2819 -3015 2624 -6558 -216 -7181 -2664 223 -826 -2581 601 3679 3456 -5179 7115 -8828 10922 -8306 8810 1883 2112 3283 -3288 4234 -1309 -2773 9009 -7709 -2000 1287 -1700 2857 -8177 6856 -14290 1995 937 -3948 1674 -2218 10463 -2696 -868 -6883 -3946 692 1240 2623 745 4132 -8258 2770 6318 1213 430 -7879 3311 -10459 7796 3373 -1383 5057 -4601 649 -2965 4975 3120 11031 7372 -8871 3906 5663 1188 -11536 3829 5126 -779 -1180 -10072 -1622 -4582 7053 -3227 518 -1033 832 6112 -344 5927 2172 14896 4548 -1628 -8404 1834 5098 232 9237 591 1884 -13255 -4559 2899 -8272 5750 -5253 8395 2493 1327 1893 2987 11142 -709 8083 -5525 9679 2195 -4398 5749 503 6864 -3802 5622 1174 -865 1649 -7607 10049 -1586 6717 5594 -4345 2559 -9849 2108 -7980 2566 896 -1113 7934 -9625 639 -857 5220 -8470 -1043 5226 -778 -6480 -5370 -2801 -3007 2473 -6766 -208 -7366 -2578 207 -769 -2454 560 3389 3245 -5374 6595 -9664 9865 -9133 8177 1866 2066 3117 -3271 3859 -1261 SO 20191015T044307.0Z 7227.196609 245 1 32.00 2 88.88 101.58 79.28 272.81 0.00 1 0.00 1 0 22 2.971e-02 2.912e-02 3.042e-02 3.017e-02 1.002217e+04 2.259522e+03 7.461264e+02 -6.000000e+00 1.731922e+03 285.75 -2.00 20.00 -2.00 505.32 0.00e+00 3.603327e-03 8.568029e-04 1.462593e-04 -6.000000e+00 8.536424e-04 285.75 -2.00 20.00 -2.00 500.23 0.00e+00 1.307889e+00 6.172494e-01 5.291459e-02 -6.000000e+00 5.971159e-01 226.37 -2.00 3.45 -2.00 501.86 0.00e+00 18.323 0.105 489.00 513.00 1 8.9805e+00 4.7497e-02 3.0406e-02 -6.0000e+00 4.5967e-02 9.9516e-02 1.1765e-02 2.1480e-03 -6.0000e+00 1.1735e-02 1.5875e-05 9.6240e-03 3.2533e-03 7.5002e-05 -6.0000e+00 3.4143e-03 4.1040e-02 -2.8485e-04 12 9 8 11 8 0 72.43 20.25 1.70 0.04104 0.10780 8 2 1 4 0 4000.000 25.58 20.01 20.25 -585 -4410 3396 -873 -1908 -2973 -2739 -3228 -2472 -1074 -5010 2311 4945 -4830 2200 663 -2832 -812 2014 2610 -210 1325 1990 2299 -1373 2374 -1934 -1606 -880 2905 -4370 4217 1113 -2610 5620 976 -727 -830 220 -4202 657 2897 -220 2267 -105 2747 -156 1157 1876 -632 1250 -8203 5455 -886 173 5271 1086 3488 4051 -84 -884 -5607 -867 568 3595 -2937 -1497 931 2496 29 -1246 6542 1146 3886 472 2536 3068 115 -2802 -1755 -466 1033 5324 1110 587 -2953 -749 473 989 -678 -4619 2489 72 1285 3254 60 8839 -2423 1443 -6354 1020 -2113 8453 4761 -2537 1115 -3052 5497 190 1543 2591 -4234 -2125 1893 1333 -971 -3944 -188 488 1042 -4100 719 -3548 -487 4233 -3100 -3677 316 4410 -2884 -804 4260 -2828 2858 -2798 1531 -230 -3649 -2320 -3943 -412 -965 -3117 -1632 2724 3088 -725 2694 1777 -1555 -554 -4423 3246 -898 -2035 -3270 -3046 -3622 -2737 -1159 -5537 2338 4809 -5133 2176 671 -3020 -866 2125 2762 -230 1428 2137 2473 -1499 2555 -2101 -1709 -907 2894 -4531 4158 1131 -2827 5703 1040 -783 -887 231 -4599 689 2999 -238 2418 -115 2931 -170 1225 1931 -650 1234 -8767 5088 -895 177 5263 1149 3624 4192 -90 -941 -6274 -925 594 3608 -3100 -1534 918 2394 28 -1226 5986 1117 3707 464 2417 2862 109 -2713 -1678 -441 969 4822 1057 566 -2955 -731 455 946 -661 -4732 2396 71 1237 3001 55 7285 -2180 1228 -5814 878 -1883 7198 4232 -2464 1046 -2965 4879 178 1446 2435 -4309 -2136 1840 1311 -985 -4147 -190 486 1015 -4141 686 -3529 -471 3927 -3103 -3703 306 4079 -2782 -750 3820 -2640 2525 -2645 1411 -220 -3658 -2323 -4053 -412 -974 -3221 -1657 2625 2922 -700 2479 1644 -1500 SO 20191015T044713.0Z 7227.199456 249 1 32.01 2 88.09 102.21 80.06 273.43 0.00 1 0.00 1 0 15 1.963e-02 1.936e-02 1.924e-02 1.914e-02 3.006839e+03 1.265405e+03 2.036188e+02 -6.000000e+00 1.144352e+03 285.75 -2.00 20.00 -2.00 505.30 0.00e+00 3.631799e-03 5.387512e-04 1.816734e-04 -6.000000e+00 5.641340e-04 285.75 -2.00 20.00 -2.00 500.28 0.00e+00 2.022703e+00 3.890710e-01 3.451157e-02 -6.000000e+00 3.949510e-01 226.37 -2.00 3.45 -2.00 501.90 0.00e+00 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