File name: Pandora119s1_Athens-NOA_20191107_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20251201T003802.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20191107_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20191107 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191107T050229.0Z 7250.210058 408 1 32.01 2 89.73 110.95 146.36 318.48 0.00 1 0.00 1 0 29 9.377e-02 8.696e-02 9.440e-02 9.223e-02 1.037651e+04 6.927314e+03 3.884708e+02 -6.000000e+00 5.407976e+03 283.04 -2.00 20.00 -2.00 505.36 0.00e+00 -1.944474e-03 2.591093e-03 6.288164e-05 -6.000000e+00 2.679558e-03 283.04 -2.00 20.00 -2.00 500.29 0.00e+00 2.273455e+00 1.883266e+00 8.675165e-02 -6.000000e+00 1.895551e+00 224.47 -2.00 3.45 -2.00 501.93 0.00e+00 20.109 0.139 489.00 513.00 1 9.9036e+00 1.4358e-01 3.5244e-02 -6.0000e+00 1.4556e-01 7.5747e-02 3.6846e-02 2.5384e-03 -6.0000e+00 3.7599e-02 4.8953e-06 -2.1881e-02 9.5357e-03 1.8383e-05 -6.0000e+00 1.0804e-02 1.3323e-01 -4.7590e-04 12 8 8 10 0 0 -71.20 20.49 12.62 0.13323 -0.01855 8 2 1 4 0 4000.000 25.79 19.99 20.49 15883 7957 -4305 -5853 -2732 -9637 -9665 4097 -3575 -4622 10148 6767 -1328 -13147 16277 -303 5587 -756 -1974 8511 4046 19068 -1147 1015 -7654 -5435 847 -6170 12570 3389 -2970 -10728 -5591 3104 11905 7752 -11499 16140 -2359 -3012 8743 595 4003 -761 -12124 -7722 1097 10811 4143 -6720 -1219 7195 -1443 -1788 -5136 39125 -1946 3696 12733 -8770 -3831 -685 13063 3669 6087 -11283 9080 -16412 -10844 1738 -650 -1946 -8808 26203 5997 3469 8334 16548 25576 -10710 -712 17097 -797 -1697 670 6979 2705 14185 -238 10646 -8497 4743 -8917 -2634 13851 -11549 4539 1549 -471 13248 -2209 10967 -4054 2093 4008 1690 -3256 375 -16960 -7601 2167 8134 -3451 660 -10142 -964 14339 11818 -7128 6310 -1255 3314 9427 -7597 15257 -10435 -13679 9099 17135 6267 -12638 2326 -4433 -5806 -1047 4423 -1937 -13026 -13 -7739 15754 9710 4987 948 -849 -5195 -5277 12873 3355 900000 12722 6860 -4258 -6046 -2822 -10967 -11258 4232 -4025 -5260 9888 6743 -1417 -15193 14270 -313 5485 -784 -2122 8419 4243 17788 -1279 1110 -9154 -6371 930 -7219 12015 3473 -3171 -12244 -6102 3174 11465 7944 -14382 15235 -2653 -3373 8648 638 4169 -838 -14691 -8999 1200 10643 4295 -7411 -1273 6724 -1441 -1781 -5211 26793 -2007 3665 11623 -9936 -4127 -716 11925 3680 5937 -12966 8394 -19278 -11884 1659 -630 -1902 -9264 19609 5544 3296 7473 13457 18725 -11166 -669 13507 -759 -1648 643 6355 2588 12127 -229 9422 -8906 4382 -9507 -2636 11906 -12184 3958 1350 -409 10098 -1906 8398 -3718 1882 3676 1626 -3317 366 -19577 -7967 2071 7386 -3547 655 -11249 -980 12599 10731 -7650 6029 -1275 3166 8368 -7768 12752 -11038 -14982 8139 14127 5607 -13591 2133 -4299 -5668 -976 3948 -1878 -14410 -13 -8408 13714 9073 4924 980 -895 -5690 -5722 11461 3238 900000 SO 20191107T050645.0Z 7250.213021 412 1 32.01 2 88.94 111.61 146.87 320.05 0.00 1 0.00 1 0 15 5.508e-02 5.382e-02 5.588e-02 5.533e-02 6.920577e+03 3.846076e+03 6.503845e+02 -6.000000e+00 3.177165e+03 283.04 -2.00 20.00 -2.00 505.32 0.00e+00 1.081483e-03 1.548054e-03 1.209331e-04 -6.000000e+00 1.572889e-03 283.04 -2.00 20.00 -2.00 500.34 0.00e+00 2.281419e+00 1.111901e+00 2.807220e-02 -6.000000e+00 1.108264e+00 224.47 -2.00 3.45 -2.00 501.95 0.00e+00 18.536 0.109 489.00 513.00 1 9.5597e+00 8.5154e-02 3.0583e-02 -6.0000e+00 8.5214e-02 6.4510e-02 2.1574e-02 1.8652e-03 -6.0000e+00 2.1816e-02 8.3540e-06 -1.7614e-03 5.9696e-03 9.6829e-05 -6.0000e+00 6.3240e-03 3.6428e-03 -2.2203e-04 12 8 8 10 0 0 54.20 20.50 5.33 0.00364 -0.00858 8 2 1 4 0 4000.000 25.79 20.00 20.50 3511 8683 1947 942 -1894 4104 4000 2587 -2323 3270 -3364 -968 1998 -4445 5192 -3579 -1406 -5381 3071 3319 3584 -245 11 6077 -1207 298 1694 1024 -2980 -233 -727 -4825 3890 -7533 -5619 2175 3776 4398 5324 3146 -1720 -4134 1268 235 7986 -3180 -440 482 -6440 3586 -10765 3153 457 5313 -16853 3669 1399 -3851 4135 -1247 4615 66 2811 1011 -6215 11071 -4861 5013 -6665 -1447 -11710 -5327 9832 -2936 13945 -1473 8232 -5904 -4957 19353 -1142 7727 -4266 5843 2518 316 1499 -8059 -139 -3010 6290 -10916 9229 3278 13257 6684 -11670 2536 -7496 5765 -8014 -1569 2297 -1820 7742 -4415 -4953 -6373 605 -3733 4229 -8180 -1933 6127 -3096 4810 4424 -7178 1429 3301 6021 693 2907 2442 1774 6205 3048 5178 1463 1489 -3609 4659 -6052 -3316 -1367 -2878 401 47 1933 -3263 1014 -5267 9000 6246 -2037 10914 -1070 3568 -3730 -2895 3121 7544 1800 907 -1934 4051 4035 2683 -2542 3368 -3662 -1015 2006 -4705 4955 -3732 -1450 -5887 3158 3466 3768 -269 12 6294 -1315 321 1792 1080 -3214 -238 -734 -5050 3780 -8418 -6326 2301 3936 4524 5373 3218 -1844 -4557 1336 253 8025 -3590 -482 518 -7295 3594 -12135 3020 444 4919 -19322 3605 1439 -4128 4219 -1310 4689 69 2849 1043 -6847 10142 -5145 4735 -6982 -1421 -12648 -5392 8608 -2948 11906 -1464 7330 -5961 -4897 14897 -1078 6713 -4208 5258 2365 306 1438 -8509 -136 -3023 5788 -11748 8392 3163 11444 6033 -12035 2265 -7056 4797 -7449 -1388 2014 -1723 6848 -4466 -5029 -6513 573 -3707 3920 -8696 -1953 5759 -3213 4642 4316 -7896 1438 3226 5645 676 2756 2328 1710 5743 2918 4854 1421 1443 -3568 4191 -5992 -3175 -1288 -2789 383 46 1886 -3399 1022 -5697 8491 6078 -2151 10044 -1094 3422 -3798 -2918 SO 20191107T051053.0Z 7250.215891 416 1 32.01 2 88.19 112.25 147.35 321.61 0.00 1 0.00 1 0 15 3.633e-02 3.597e-02 2.795e-02 2.777e-02 8.948136e+03 2.000922e+03 5.194191e+02 -6.000000e+00 2.094989e+03 283.04 -2.00 20.00 -2.00 505.36 0.00e+00 1.762981e-03 7.820598e-04 9.674288e-05 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