File name: Pandora119s1_Athens-NOA_20210226_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20250409T110652.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20210226_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20210226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210226T054058.2Z 7727.236785 260 1 48.37 2 83.12 106.61 100.21 301.79 0.00 1 0.00 1 0 17 5.330e-01 2.988e-02 4.852e-01 2.727e-02 9.828948e-01 1.530258e-02 1.024586e-02 -6.000000e+00 2.957190e-01 225.57 -2.00 3.45 -2.00 322.33 0.00e+00 -5.640619e-04 6.224109e-03 1.158017e-03 -6.000000e+00 1.208059e-02 277.62 -2.00 20.00 -2.00 321.95 0.00e+00 7.646 0.008 302.00 328.00 3 1.3747e+00 4.9883e-02 9.0428e-02 -6.0000e+00 7.3688e-01 1.4228e+00 6.1798e-02 4.9841e-02 -6.0000e+00 8.0621e-01 -1.8346e+00 5.2960e-02 2.7119e-02 -6.0000e+00 4.7530e-01 7.3098e-01 2.8305e-02 9.2110e-03 -6.0000e+00 1.9957e-01 2.4640e-05 -1.6187e-03 7.1056e-04 1.2865e-04 -6.0000e+00 1.3664e-02 2.0387e-02 -1.6609e-04 12 8 8 10 0 0 59.42 19.83 0.55 0.02039 0.00822 30 7 1 5 0 1611.959 25.28 20.00 19.83 16.38 32.9 935.68 -66893 900000 -52825 32771 91276 -26861 -90825 -8059 105052 -84404 -28025 -125182 122659 -3119 52342 217062 98962 187313 41415 155528 -7088 -17617 93286 46554 211194 2767 -24611 -49376 -40231 -38437 78708 83962 56652 27080 -35522 13790 36133 -25104 81915 11756 42782 1280 121070 -40818 25685 132868 91385 64845 28953 113406 -21532 56771 18980 95680 54974 42194 49202 -1712 54011 42496 43741 -7002 -13338 43198 15637 36251 9870 3811 30522 17302 27602 16414 21343 -6740 11136 -21142 -3379 1065 -12927 17120 -7503 4713 4893 8543 4648 5357 4426 -3319 1295 -6300 5012 4477 -3982 -4657 460 704 -6310 -309 -4080 -3644 1400 -5074 5777 -7817 -5030 -7053 -2368 -3307 2027 -1320 499 283 -2275 -735 -300 -429 2667 -3770 2829 -465 1807 -1657 2860 3955 4003 5883 -86 1116 546 782 -559 575 -1238 269 869 -276 668 603 -548 -84 -273 -966 -1660 -4205 900000 -3065 871 2427 -714 -4391 -214 2794 -4081 -745 -9079 3262 -98 1392 5772 2632 4981 1302 4136 -326 -809 2481 1238 5616 107 -1190 -2745 -1848 -1766 2093 2233 1808 1224 -2490 587 1249 -1639 2396 813 2389 102 3220 -4835 1639 3533 2916 2759 1848 3317 -2447 3623 1918 4834 4386 3927 4318 -219 4022 3277 3257 -846 -1967 4595 2155 4435 1432 617 4627 3137 4938 3373 4025 -1532 1858 -4242 -584 184 -2719 3270 -2195 1424 1644 2933 1753 2111 1830 -1508 554 -2772 1830 1558 -1502 -1914 211 388 -4439 -241 -3669 -3294 1120 -3803 3435 -5272 -3551 -5371 -1826 -2814 1862 -1475 633 395 -3365 -1063 -418 -581 3566 -5660 4199 -727 2651 -2360 3727 4963 4877 6826 -103 1452 851 1429 -1169 1296 -3050 704 2438 -816 1979 1798 -1626 -232 -690 -2247 -3740 SS 20210226T055053.3Z 7727.243672 263 1 48.55 2 81.26 108.22 101.81 303.42 0.00 1 0.00 1 0 17 5.441e-01 1.849e-02 3.550e-01 9.155e-03 8.668747e-01 5.040106e-03 9.010932e-03 -6.000000e+00 3.019486e-01 225.57 -2.00 3.45 -2.00 322.01 0.00e+00 7.254829e-03 2.176557e-03 1.073531e-03 -6.000000e+00 1.234060e-02 277.63 -2.00 20.00 -2.00 321.64 0.00e+00 6.217 0.004 302.00 328.00 3 1.3751e+00 1.6087e-02 7.5701e-02 -6.0000e+00 7.5251e-01 6.2232e-01 2.3406e-02 4.4940e-02 -6.0000e+00 8.2353e-01 -8.5442e-01 2.6603e-02 2.5056e-02 -6.0000e+00 4.8495e-01 3.5610e-01 1.2812e-02 8.5605e-03 -6.0000e+00 2.0230e-01 1.1640e-04 -1.1632e-03 2.4490e-04 1.0899e-04 -6.0000e+00 1.3938e-02 1.9230e-02 -1.3880e-04 12 8 8 10 0 0 76.51 19.87 0.42 0.01923 0.01049 79 18 1 5 0 614.394 25.39 20.00 19.87 16.99 32.9 939.52 -161966 -169740 -136484 -189739 -119233 -255046 -121464 14181 -152672 -174471 -186304 -49757 -68833 21999 -80919 41681 -41093 16869 -49014 -63252 900000 -93745 81823 51122 45884 79981 -85946 -62687 -89802 676 -46791 85668 -7037 13857 37244 30917 -9945 -28936 40307 19237 20744 39615 -3265 70864 411 44351 8074 44163 26764 27189 40118 16902 30552 32062 29361 14503 19496 20824 969 27968 1870 23731 18448 21802 17656 15663 10760 4387 16803 11613 10928 5348 -815 6335 862 9339 -694 4220 -1852 4092 3281 -865 1585 -3031 -2219 -1626 -541 2088 -563 2032 1140 2995 -5039 -1063 -2191 -3224 -1376 -1524 -661 -1677 206 -2087 -1933 -962 -3085 -1804 -2608 857 -1068 -644 -521 -1412 105 -1177 288 -699 484 -345 -468 532 428 3147 604 1134 1791 1953 1153 1482 546 -61 1125 117 846 168 -213 71 76 318 -293 16 -281 -916 -1467 -2235 -3030 -1883 -4311 -1161 -8693 -1084 127 -2106 -3115 -3780 -444 -614 196 -1445 372 -700 196 -1074 -1643 900000 -3119 730 456 451 714 -2929 -1628 -2988 11 -1367 918 -206 396 798 662 -337 -1245 1151 734 875 1627 -196 2277 24 1900 465 2050 1434 1567 2279 1372 2380 2680 2669 1577 2057 2129 115 2429 214 2407 2291 3043 2794 2517 1816 826 3109 2629 2749 1476 -233 1563 201 1766 -136 822 -445 1136 1097 -350 695 -1473 -1136 -877 -303 1166 -321 1082 570 1385 -2478 -535 -1296 -2302 -1143 -1358 -647 -1668 187 -1865 -1537 -755 -2664 -1624 -2504 862 -1129 -785 -722 -2135 159 -1773 409 -969 673 -510 -732 845 657 4441 839 1518 2305 2427 1408 1948 850 -110 2253 256 1949 418 -572 197 215 903 -826 41 -688 -2081 -3244 SS 20210226T060323.6Z 7727.252356 268 1 49.14 2 78.93 110.28 103.79 305.53 0.00 1 0.00 1 0 17 5.045e-01 8.389e-03 1.745e-01 3.074e-03 7.303199e-01 1.622049e-03 7.723881e-03 -6.000000e+00 2.800112e-01 225.57 -2.00 3.45 -2.00 321.48 0.00e+00 3.547306e-03 6.549242e-04 7.558781e-04 -6.000000e+00 1.143399e-02 277.63 -2.00 20.00 -2.00 321.15 0.00e+00 5.024 0.002 302.00 328.00 3 1.0759e+00 4.9549e-03 6.1915e-02 -6.0000e+00 6.9775e-01 1.4572e-01 7.3382e-03 3.8004e-02 -6.0000e+00 7.6327e-01 -1.7476e-01 8.9457e-03 2.1409e-02 -6.0000e+00 4.4998e-01 6.7181e-02 4.3792e-03 7.2159e-03 -6.0000e+00 1.8904e-01 5.8389e-04 -5.1820e-04 8.3505e-05 8.5165e-05 -6.0000e+00 1.2931e-02 1.8076e-02 -1.1517e-04 11 8 0 10 0 0 89.40 19.93 0.24 0.01808 0.01418 214 49 1 5 0 227.478 25.39 20.00 19.93 17.72 33.0 943.94 -226074 900000 -225361 -85779 -185116 -114131 -158983 -187909 -5253 -215227 -109291 -158456 -42452 -112757 -83589 -10269 -66383 -20135 -53329 15864 -27118 -38971 -22689 -33153 28563 -47267 20374 -44954 -26146 -506 -28737 8613 -19412 10370 -28289 -346 -13107 -4268 -1203 1953 10990 -10187 8563 -2050 1200 10934 4341 9250 -3311 7243 1564 9651 6547 4144 8933 1736 7091 1604 4236 -1127 2363 4598 3200 7902 958 4065 1136 2546 2053 864 3464 -95 1198 -112 934 690 -1852 1439 -1666 1958 -2447 -143 -2024 -1595 -1150 -1390 584 -697 681 -227 794 928 -710 -75 -1175 615 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