File name: Pandora119s1_Athens-NOA_20210623_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20250409T110738.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20210623_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20210623 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210623T041028.2Z 7844.173937 190 1 48.92 2 78.93 68.83 119.52 263.70 0.00 1 0.00 1 0 17 4.483e-01 1.154e-02 2.599e-01 7.650e-03 6.434218e-01 4.136511e-03 6.846428e-03 -6.000000e+00 2.557952e-01 232.71 -2.00 3.45 -2.00 321.38 0.00e+00 3.116309e-03 1.578475e-03 5.985183e-04 -6.000000e+00 1.062374e-02 288.45 -2.00 20.00 -2.00 321.01 0.00e+00 5.020 0.002 302.00 328.00 3 2.7751e+00 1.2541e-02 6.0167e-02 -6.0000e+00 6.4843e-01 1.1760e-01 1.6925e-02 3.4313e-02 -6.0000e+00 7.0513e-01 -1.8692e-01 1.9263e-02 1.8432e-02 -6.0000e+00 4.1295e-01 7.9268e-02 9.6066e-03 5.9391e-03 -6.0000e+00 1.7034e-01 1.1840e-04 -4.0204e-04 2.2424e-04 6.8815e-05 -6.0000e+00 1.1596e-02 7.1644e-03 -4.4716e-05 12 8 8 10 0 0 6.33 21.97 0.40 0.00716 0.00414 37 9 1 5 0 1321.885 27.05 20.00 21.97 31.33 33.2 1022.06 -240845 -44329 -118604 -102089 -162701 -140349 -59381 -199175 -148456 -129528 900000 -102000 -123062 -41834 -64359 -59280 -45692 -24037 -48426 -30138 68859 -44228 -24583 -16405 -30954 -43479 -19171 -46881 29929 -9457 -35732 4892 -14547 6573 -10154 13104 -13615 1238 7002 9012 4746 17198 5513 7237 3155 17337 -703 4354 11471 5830 9837 9567 4904 4008 8404 4363 -659 6130 5881 7039 2047 9184 6114 9972 -930 5005 1130 -1947 4508 2597 62 584 3262 1258 883 -2988 -2711 -3091 -1163 -2255 -570 -1029 -1103 -1359 -172 -1368 -942 -1684 1933 1696 -325 -73 -173 -324 -1451 -534 805 -615 80 -423 154 -181 -864 -985 -1556 -2497 -1315 -414 -88 876 -156 177 -646 -100 363 218 398 100 -287 -841 158 869 10 1010 629 633 875 2136 365 62 422 -340 318 306 164 -374 -112 282 -397 133 -290 47 -802 -5716 -331 -1126 -831 -2207 -1428 -443 -4322 -2215 -1757 900000 -1176 -2170 -468 -1047 -1126 -868 -408 -1149 -634 616 -1110 -517 -345 -819 -1386 -494 -1558 491 -240 -1260 139 -592 241 -427 418 -609 56 370 568 357 1236 471 628 289 1411 -70 425 1089 621 1114 1226 725 652 1396 787 -130 1131 1057 1222 382 1744 1364 2435 -271 1344 307 -556 1321 903 25 244 1323 494 319 -1003 -836 -956 -391 -914 -267 -557 -659 -791 -106 -912 -661 -1231 1366 1162 -231 -48 -109 -208 -1054 -410 706 -628 89 -476 162 -171 -748 -860 -1483 -2546 -1394 -465 -108 1192 -238 285 -1049 -155 529 305 559 149 -455 -1399 258 1355 16 1465 879 852 1130 2843 560 108 799 -688 670 687 394 -953 -290 739 -1046 335 -688 105 -1742 SS 20210623T041635.4Z 7844.178188 193 1 49.08 2 77.80 69.69 120.67 264.52 0.00 1 0.00 1 0 25 3.349e-01 9.484e-03 2.150e-01 4.989e-03 5.985260e-01 2.638870e-03 6.495316e-03 -6.000000e+00 1.910498e-01 232.71 -2.00 3.45 -2.00 321.08 0.00e+00 2.658161e-03 9.497499e-04 4.859736e-04 -6.000000e+00 7.540459e-03 288.45 -2.00 20.00 -2.00 320.72 0.00e+00 4.591 0.002 302.00 328.00 3 2.5572e+00 7.8260e-03 5.5318e-02 -6.0000e+00 4.8417e-01 6.5901e-02 1.0261e-02 3.1798e-02 -6.0000e+00 5.2644e-01 -9.4644e-02 1.1483e-02 1.6808e-02 -6.0000e+00 3.0842e-01 3.6751e-02 5.8153e-03 5.2856e-03 -6.0000e+00 1.2703e-01 2.3006e-04 -4.8256e-04 1.4437e-04 6.0599e-05 -6.0000e+00 8.5856e-03 6.4824e-03 -5.9542e-05 12 8 8 10 0 0 23.08 21.99 0.29 0.00648 0.00286 57 13 1 5 0 861.006 27.05 20.00 21.99 31.49 33.1 1022.96 -76738 75477 -149136 -73561 -126533 -162973 -109842 -97056 22944 -125862 48668 -92076 -41897 -37358 -35906 -5383 -75723 42952 -32053 553 -34144 -24236 -7614 -10685 22242 -51745 7743 -24761 10012 15093 -15369 29968 -1659 11466 -10197 14732 -1799 -18556 11953 -1404 7236 -2474 8231 -5982 2816 -2690 3171 3408 -2897 13016 -3196 4450 3012 1958 7125 1550 5721 -2628 7361 -2087 3585 2668 1255 5497 1955 1362 -2867 2339 643 3692 2226 -354 1626 -1513 561 -1711 2220 -1076 -1816 -422 -1712 2116 -2114 -1517 -660 -1818 44 -713 1957 -256 1094 -558 -532 -19 85 536 -906 1504 -645 417 -776 -464 -119 -140 443 -2337 -660 -1149 -604 -50 15 87 266 438 18 372 504 -304 -134 -882 -201 -843 1028 504 969 1331 9 1440 -73 918 -42 411 -92 -276 437 -577 15 -193 266 -476 39 191 -554 -467 367 -2344 -597 -1590 -2775 -1158 -1023 112 -2245 237 -1307 -442 -485 -582 -79 -2352 488 -845 11 -1024 -658 -179 -282 460 -2208 204 -883 244 361 -579 863 -77 516 -511 597 -93 -1229 720 -118 636 -259 819 -710 310 -320 363 399 -375 1515 -482 700 528 377 1389 333 1223 -614 1515 -462 768 629 340 1617 635 433 -918 720 219 1422 972 -167 752 -687 230 -641 734 -365 -681 -185 -890 1211 -1389 -1048 -483 -1343 33 -570 1526 -198 835 -402 -363 -13 64 435 -860 1597 -766 492 -868 -465 -109 -139 440 -2530 -739 -1377 -782 -72 23 145 441 696 28 528 719 -458 -215 -1497 -338 -1374 1586 754 1384 1822 12 1960 -113 1587 -80 822 -193 -616 1037 -1357 36 -469 644 -1117 93 422 -1202 SS 20210623T042158.3Z 7844.181924 196 1 48.91 2 76.80 70.43 121.68 265.25 0.00 1 0.00 1 0 25 3.178e-01 1.032e-02 1.901e-01 5.391e-03 5.639553e-01 2.833372e-03 6.162544e-03 -6.000000e+00 1.813343e-01 232.71 -2.00 3.45 -2.00 320.89 0.00e+00 3.489655e-03 9.739237e-04 4.138545e-04 -6.000000e+00 7.236400e-03 288.45 -2.00 20.00 -2.00 320.54 0.00e+00 4.269 0.001 302.00 328.00 3 3.0268e+00 8.3207e-03 5.1589e-02 -6.0000e+00 4.5956e-01 8.5997e-02 1.0529e-02 2.9718e-02 -6.0000e+00 4.9965e-01 -1.2053e-01 1.1219e-02 1.5518e-02 -6.0000e+00 2.9294e-01 5.0757e-02 5.7627e-03 4.8175e-03 -6.0000e+00 1.2128e-01 1.9958e-04 -4.8070e-04 1.5632e-04 5.4334e-05 -6.0000e+00 8.1498e-03 6.1318e-03 -3.7291e-05 12 8 8 10 0 0 99.50 22.01 0.26 0.00613 0.00252 45 10 1 5 0 1086.695 27.15 20.00 22.01 31.70 33.2 1024.64 133205 -140143 900000 -127658 -72261 -92349 -110319 55815 -111769 56808 -102981 -44400 -48953 -48361 -592 -53951 25400 -36633 42415 -24059 11128 -1396 -33679 36504 -13607 68489 -29813 9227 -24458 -4737 -8903 -28117 32457 -13742 28708 -5338 10417 -2406 -3430 12482 -9258 13058 -1516 11429 940 2118 6820 -3390 11152 -1231 8070 -107 9246 3744 -1353 6248 1968 5638 -2638 3694 -23 2208 4496 -1135 4482 -2725 4650 -453 3759 569 -850 2967 -222 1147 -151 82 -1516 -2043 1331 -3801 418 -2598 -117 -2494 -712 -276 -1647 1283 -958 740 -397 64 11 -261 757 -958 1585 30 409 -413 -151 338 -743 449 -1654 -204 -879 -458 -489 -114 476 -886 770 -19 545 187 -9 226 -1139 83 -1094 642 82 -181 858 914 1074 1222 1014 192 516 140 -475 324 -277 231 -619 321 61 -208 -81 -309 -348 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