File name: Pandora119s1_Athens-NOA_20210802_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20250409T110725.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20210802_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20210802 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210802T043225.4Z 7884.189183 236 1 49.21 2 78.98 76.05 22.69 145.81 0.00 1 0.00 1 0 25 5.571e-01 1.763e-02 3.674e-01 1.285e-02 5.963259e-01 6.914680e-03 6.452282e-03 -6.000000e+00 3.193374e-01 231.98 -2.00 3.45 -2.00 321.32 0.00e+00 4.315153e-03 2.594304e-03 5.186564e-04 -6.000000e+00 1.371822e-02 290.89 -2.00 20.00 -2.00 320.97 0.00e+00 5.042 0.002 302.00 328.00 3 3.3736e+00 2.0958e-02 5.8850e-02 -6.0000e+00 8.0988e-01 1.2980e-01 2.7245e-02 3.1536e-02 -6.0000e+00 8.8202e-01 -2.5580e-01 2.9623e-02 1.6539e-02 -6.0000e+00 5.1592e-01 1.1149e-01 1.4905e-02 5.2336e-03 -6.0000e+00 2.1248e-01 6.8388e-05 -8.0057e-04 3.8714e-04 6.2351e-05 -6.0000e+00 1.4398e-02 -2.7246e-04 -6.8845e-05 12 8 8 10 0 0 99.08 23.07 0.32 -0.00027 -0.00629 36 8 1 5 0 1366.566 27.99 20.00 23.07 35.96 33.3 1031.83 -23501 -177756 -46480 -181473 2918 -201003 -61870 -16675 -132439 900000 -117273 900000 -44370 900000 59635 21520 900000 32049 244134 -57133 31806 -25938 362603 9219 56013 110195 -33053 141417 -54386 99783 -43233 44833 20058 -33581 38407 -27613 23853 -13069 22488 10586 -886 18636 10630 24474 17458 27837 3390 19656 16066 7335 30971 -7523 -3480 13593 9833 16012 8013 15490 -3660 6974 -5316 6812 1716 914 3013 1855 6917 5805 1897 4636 3485 847 -914 -4130 -3202 6453 7170 -2943 1213 2066 -2491 902 -334 -6794 -1296 -4102 126 1101 -1774 1117 -1482 1463 -2972 -2996 -1267 1778 1287 -1166 1302 -1960 320 960 101 971 -837 -274 -2923 -252 199 -18 -80 -573 1058 -617 763 -1105 838 74 -482 -656 -519 744 -345 1096 -350 2313 697 1289 1055 310 1132 -95 1328 -1399 59 -120 -844 876 -190 287 139 -355 -1220 -294 -4822 -582 -5681 37 -6352 -775 -209 -2819 900000 -2386 900000 -570 900000 747 283 900000 473 3057 -2251 562 -788 4540 216 904 1380 -1302 1771 -2491 1249 -2099 1137 741 -2243 1307 -1636 918 -826 1216 779 -81 1554 989 2100 1587 2389 370 1863 1633 853 3187 -1216 -592 2164 1687 2676 1498 2697 -751 1259 -1107 1367 411 250 863 524 1789 1531 563 1554 1294 341 -375 -1669 -1209 1980 2000 -896 388 775 -1149 451 -186 -4282 -826 -2889 90 809 -1350 802 -1020 907 -1820 -1848 -850 1339 1126 -1202 1443 -2217 340 916 88 846 -806 -280 -3217 -288 246 -24 -120 -914 1662 -949 1112 -1564 1167 109 -745 -1070 -845 1184 -536 1623 -504 3131 919 1745 1612 536 2078 -188 2694 -3090 137 -297 -2145 2230 -490 708 324 -784 -2631 SS 20210802T043825.0Z 7884.193345 239 1 48.73 2 77.84 76.92 22.05 149.07 0.00 1 0.00 1 0 25 2.283e-01 6.246e-03 1.773e-01 3.820e-03 5.469343e-01 2.014387e-03 5.925645e-03 -6.000000e+00 1.300781e-01 231.98 -2.00 3.45 -2.00 320.98 0.00e+00 2.902023e-03 7.173721e-04 4.236609e-04 -6.000000e+00 5.157234e-03 290.89 -2.00 20.00 -2.00 320.63 0.00e+00 4.603 0.002 302.00 328.00 3 2.0826e+00 5.9382e-03 5.3670e-02 -6.0000e+00 3.2909e-01 -2.4456e-02 7.7432e-03 2.8878e-02 -6.0000e+00 3.5807e-01 -1.8601e-02 8.6506e-03 1.5366e-02 -6.0000e+00 2.0974e-01 8.1547e-03 4.4025e-03 4.8909e-03 -6.0000e+00 8.7247e-02 4.0330e-04 -3.5640e-04 1.1278e-04 5.2005e-05 -6.0000e+00 5.9067e-03 -1.4177e-03 -2.6883e-05 10 0 0 10 0 0 95.45 23.08 0.26 -0.00142 -0.00410 118 27 1 5 0 412.612 27.99 20.01 23.08 36.29 33.3 1034.09 900000 -101990 -30938 -16168 107477 -64828 -131886 -56735 -87317 -7721 -47773 7829 -15580 -60235 8607 -54946 -14746 -35906 5953 -28485 -14907 -18119 -3219 -721 -18558 1000 -26544 -7807 -7232 -20648 -531 -4874 5114 -18926 -71 -4093 10271 -1166 -8146 2408 -3850 5065 3772 122 3523 -776 7494 111 5739 -1253 2761 1739 3330 2451 644 5120 -349 2449 157 587 803 2077 3417 1028 1425 -1280 1184 -1237 1125 869 -1054 1485 131 707 -762 749 -1286 -1065 1019 -2587 245 -405 -1431 -2235 -1186 -284 -910 736 581 1237 901 932 409 76 591 -203 633 601 386 -447 -435 3 -904 -223 -584 -934 -581 -519 -123 -98 224 99 401 -330 313 89 256 -28 -593 -318 -889 188 203 198 622 226 697 457 278 75 159 284 34 400 -336 278 -444 466 -162 -247 247 -456 -195 900000 -1070 -178 -82 400 -461 -1920 -442 -1064 -52 -453 50 -137 -1060 96 -1414 -290 -960 115 -829 -399 -503 -78 -19 -622 29 -1069 -256 -228 -762 -18 -210 232 -1218 -4 -212 494 -74 -624 203 -396 516 412 14 407 -96 870 14 714 -175 405 289 598 483 138 1090 -82 561 36 132 184 511 939 326 480 -430 372 -400 384 346 -480 697 63 322 -326 284 -454 -368 374 -1159 125 -237 -931 -1552 -872 -222 -761 629 501 1028 701 672 278 52 441 -175 623 678 441 -520 -515 4 -889 -219 -627 -1070 -696 -661 -156 -137 344 161 645 -512 451 122 351 -40 -920 -520 -1465 298 310 292 949 333 979 661 415 126 289 544 68 842 -764 661 -1090 1157 -406 -598 563 -991 -410 SS 20210802T044345.8Z 7884.197058 242 1 48.88 2 76.81 77.69 21.53 152.12 0.00 1 0.00 1 0 25 1.923e-01 5.032e-03 6.112e-02 2.401e-03 5.119810e-01 1.246196e-03 5.654834e-03 -6.000000e+00 1.095446e-01 231.98 -2.00 3.45 -2.00 320.68 0.00e+00 2.687459e-03 4.074732e-04 3.556089e-04 -6.000000e+00 4.331750e-03 290.89 -2.00 20.00 -2.00 320.33 0.00e+00 4.270 0.001 302.00 328.00 3 1.7512e+00 3.6155e-03 4.9966e-02 -6.0000e+00 2.7713e-01 -2.9333e-03 4.4938e-03 2.6990e-02 -6.0000e+00 3.0134e-01 -3.2578e-02 4.6905e-03 1.4020e-02 -6.0000e+00 1.7666e-01 1.1792e-02 2.4326e-03 4.3278e-03 -6.0000e+00 7.2990e-02 7.8981e-04 -3.7096e-04 7.0553e-05 4.8396e-05 -6.0000e+00 4.9288e-03 -2.0403e-03 6.0303e-07 10 0 0 10 0 0 61.17 23.12 0.23 -0.00204 -0.00483 163 37 1 5 0 299.828 27.99 20.00 23.12 36.65 33.3 1036.46 -67469 -54456 -78170 -60018 -69038 -64872 -64864 -65404 -67176 -54328 -43050 -49226 -38663 -29216 -18149 -11172 -8684 -7977 -4755 -12327 -842 -548 -4497 -4107 -6903 -12931 -7510 -10075 -726 -9453 -4731 -4419 1236 -7706 -2924 -3355 -2845 -2638 -511 3709 -1504 576 433 2451 588 498 3614 1324 2025 306 1973 975 1916 3655 1908 1410 85 690 -649 498 1060 1091 1844 1379 1599 831 1430 -679 381 611 211 1165 -49 130 -282 -50 -620 -1691 220 -896 -164 -1191 -1599 -1641 -1218 -389 283 394 744 625 426 224 104 111 449 -343 16 603 101 -467 -320 -143 -493 -290 -876 -976 -703 -338 -148 219 412 266 223 179 252 82 158 -9 -370 -341 -439 -103 -72 76 530 255 658 903 445 129 -14 30 -15 220 -173 86 -181 177 -129 -125 132 -254 -198 -695 -599 -1208 -787 -905 -759 -790 -903 -1085 -852 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