File name: Pandora119s1_Athens-NOA_20211009_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20250409T110701.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20211009_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20211009 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211009T051051.3Z 7952.215871 61 1 48.94 2 82.52 104.13 118.97 91.49 0.00 1 0.00 1 0 17 4.449e-01 2.935e-02 3.559e-01 1.803e-02 7.940319e-01 1.016252e-02 8.289115e-03 -6.000000e+00 2.514250e-01 226.95 -2.00 3.45 -2.00 321.96 0.00e+00 6.289001e-04 4.321290e-03 9.394100e-04 -6.000000e+00 1.066769e-02 286.43 -2.00 20.00 -2.00 321.58 0.00e+00 7.114 0.006 302.00 328.00 3 1.5759e+00 3.2445e-02 8.1158e-02 -6.0000e+00 6.3055e-01 8.1784e-01 4.2775e-02 4.1587e-02 -6.0000e+00 6.9160e-01 -1.1072e+00 4.3657e-02 2.3088e-02 -6.0000e+00 4.0711e-01 4.4094e-01 2.2070e-02 7.8780e-03 -6.0000e+00 1.7250e-01 4.5047e-05 -9.3898e-04 5.2555e-04 9.8281e-05 -6.0000e+00 1.2070e-02 5.3302e-03 -2.0517e-06 12 8 8 10 0 0 10.27 20.62 0.52 0.00533 -0.00173 41 9 1 5 0 1193.315 25.90 20.00 20.62 23.86 32.6 946.72 900000 -84653 900000 900000 -72654 16758 -72045 113872 -152262 -12224 -113769 -90706 105640 -112038 900000 -54698 900000 -8557 75767 900000 -9837 900000 -50580 900000 -35402 60826 28794 -1677 -4229 -47725 60331 -64416 900000 4598 18032 78989 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2198 -3751 2497 -1648 -1995 3168 -3470 3807 -2224 2557 -2168 -151 -468 -1563 2356 -4587 3480 -4815 -195 -724 -2261 -708 -2710 727 -4131 23 -4216 -792 -1202 -3613 1259 -4973 1235 -3902 1358 -680 -2051 444 -2451 3229 -3033 2417 94 2070 3390 1546 6044 -88 4132 2023 2555 1550 81 2599 -1096 5227 -4959 1618 -1029 1555 2826 -4557 2673 -5166 -3208 SS 20211009T052217.4Z 7952.223812 64 1 48.93 2 80.35 105.98 116.84 93.18 0.00 1 0.00 1 0 25 4.938e-01 1.209e-02 2.409e-01 5.104e-03 6.691247e-01 2.741822e-03 7.125524e-03 -6.000000e+00 2.762419e-01 226.95 -2.00 3.45 -2.00 321.60 0.00e+00 4.736284e-03 1.113867e-03 7.059736e-04 -6.000000e+00 1.142331e-02 286.43 -2.00 20.00 -2.00 321.24 0.00e+00 5.686 0.003 302.00 328.00 3 1.3487e+00 8.4612e-03 6.5758e-02 -6.0000e+00 6.9177e-01 1.4029e-01 1.1902e-02 3.5203e-02 -6.0000e+00 7.5567e-01 -2.6213e-01 1.3926e-02 1.9447e-02 -6.0000e+00 4.4365e-01 1.1454e-01 6.8566e-03 6.5084e-03 -6.0000e+00 1.8485e-01 2.6840e-04 -7.6127e-04 1.4895e-04 7.8247e-05 -6.0000e+00 1.2645e-02 5.1092e-03 -4.0689e-05 12 8 8 10 0 0 82.05 20.65 0.34 0.00511 -0.00061 121 28 1 5 0 404.262 26.00 20.01 20.65 24.97 32.5 953.06 -80077 -215618 171232 -205873 -77010 -184843 -181603 -25513 -212111 900000 -178159 -55971 -110327 -43796 56668 -73480 -1319 -62118 -17451 -62660 19828 -9008 -57233 -24813 -47776 6542 -50878 37263 -34771 -28037 32580 -46321 8303 -16066 13620 -14034 1634 7977 886 11965 -4176 24184 -2689 16666 12182 17418 14410 -5254 17911 6204 18501 12801 12196 10530 3609 10966 -1879 10070 3304 7330 4950 3545 8607 3774 7995 2470 5739 2301 2698 3404 1453 3892 -90 3640 -1779 3085 -492 -4459 562 -2194 483 -1786 88 -3333 -2592 239 -2239 1280 -622 1438 -314 1155 -1714 -1439 -314 -2127 613 -225 49 -425 -421 -433 -1525 -121 -1438 -1155 -984 -811 -521 -832 388 -435 767 -45 216 226 -213 220 -689 -3 -255 588 900 358 1010 300 1214 599 1235 303 520 121 6 340 -657 270 -314 435 -41 -347 -24 -598 -343 -398 -4194 852 -4098 -422 -2509 -2465 -127 -4894 900000 -3304 -362 -1537 -414 282 -1363 -15 -1321 -287 -1559 247 -148 -1398 -519 -1232 114 -1473 482 -900 -712 535 -1865 252 -632 427 -502 59 285 42 612 -287 1357 -209 1108 860 1198 1050 -483 1369 567 1657 1372 1451 1391 545 1602 -323 1540 525 1091 770 613 1620 854 1874 602 1321 561 716 1045 509 1403 -34 1243 -587 867 -132 -1251 167 -804 204 -889 48 -1815 -1496 144 -1459 833 -414 909 -206 696 -1015 -870 -211 -1558 509 -218 52 -460 -428 -395 -1271 -99 -1299 -1105 -991 -873 -614 -1111 571 -689 1208 -68 312 313 -299 322 -1085 -5 -414 909 1337 518 1397 403 1559 808 1890 532 1002 250 13 781 -1637 701 -839 1172 -111 -900 -58 -1368 -758 SS 20211009T053005.8Z 7952.229234 68 1 48.96 2 78.87 107.26 115.39 94.31 0.00 1 0.00 1 0 25 3.661e-01 8.198e-03 2.007e-01 5.177e-03 6.068643e-01 2.685122e-03 6.589329e-03 -6.000000e+00 2.045852e-01 226.95 -2.00 3.45 -2.00 321.19 0.00e+00 2.419117e-03 1.018089e-03 5.334772e-04 -6.000000e+00 8.245258e-03 286.43 -2.00 20.00 -2.00 320.86 0.00e+00 4.998 0.002 302.00 328.00 3 2.2407e+00 8.0401e-03 5.8194e-02 -6.0000e+00 5.1143e-01 6.2010e-02 1.0929e-02 3.1621e-02 -6.0000e+00 5.5845e-01 -9.9092e-02 1.2601e-02 1.7194e-02 -6.0000e+00 3.2863e-01 3.5362e-02 6.3450e-03 5.6169e-03 -6.0000e+00 1.3705e-01 2.2121e-04 -6.0488e-04 1.4816e-04 6.6359e-05 -6.0000e+00 9.3737e-03 4.2842e-03 -2.9110e-05 11 8 0 10 0 0 99.68 20.68 0.24 0.00428 -0.00026 68 16 1 5 0 719.869 26.00 20.01 20.68 25.76 32.7 958.41 -162622 -182704 -69465 -43599 -96115 -108202 -108635 -147976 -123969 -81396 -72048 -83424 -67018 -102355 -17220 -59881 25230 -42233 -113 -1798 10660 2602 -24095 10697 -40397 8271 -1787 -12521 2135 -32448 -10322 -5316 13337 -7061 21916 -15010 -6146 -6881 -16029 2122 -5394 3183 1450 5770 3867 2711 5731 -2903 4565 2364 1039 6931 2712 6919 486 10303 -371 434 -179 707 2450 2535 4422 932 3989 334 2190 1117 1821 2233 519 2401 488 2704 928 267 -1343 -2733 606 -2622 -595 -224 -1687 -1467 -1456 -418 -1146 111 -193 1600 959 557 913 -1774 74 -845 437 200 93 -508 -566 221 -583 -450 -1197 -1196 -831 -1135 153 231 346 116 407 73 454 -209 -233 471 -600 -368 -542 180 633 117 518 461 274 783 1110 391 -246 366 -202 229 -410 4 -286 607 39 -228 -40 -540 -241 -1941 -3271 -446 -242 -750 -894 -947 -2174 -1650 -785 -661 -919 -769 -2161 -198 -1292 293 -969 -2 -32 176 47 -575 196 -1354 182 -45 -345 49 -1087 -322 -190 465 -337 765 -723 -291 -385 -1214 164 -515 302 148 585 405 294 616 -349 530 296 145 1031 425 1133 91 1816 -75 88 -36 136 473 533 1038 257 1145 97 605 316 557 791 209 1003 208 1072 344 89 -419 -857 202 -1071 -280 -121 -1015 -932 -989 -301 -879 87 -153 1201 676 366 567 -1146 52 -695 410 216 110 -611 -639 222 -538 -417 -1211 -1284 -936 -1367 198 334 554 198 689 120 693 -307 -343 722 -991 -635 -932 296 1001 181 762 653 374 1102 1757 701 -449 703 -407 488 -944 9 -707 1513 97 -550 -90 -1161 -501 SS 20211009T053619.4Z 7952.233558 71 1 33.62 2 77.71 108.30 114.23 95.21 0.00 1 0.00 1 0 17 3.145e-01 1.260e-02 2.142e-01 7.173e-03 5.513804e-01 3.734103e-03 6.054567e-03 -6.000000e+00 1.778057e-01 226.95 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