File name: Pandora119s1_Athens-NOA_20220215_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20250409T110652.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20220215_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20220215 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220215T060619.8Z 8081.254396 278 1 49.42 2 81.32 113.62 102.72 311.11 0.00 1 0.00 1 0 17 4.583e-01 2.300e-02 3.834e-01 1.758e-02 8.490933e-01 9.760888e-03 8.936862e-03 -6.000000e+00 2.569302e-01 225.02 -2.00 3.45 -2.00 321.97 0.00e+00 5.550703e-03 4.158080e-03 1.043685e-03 -6.000000e+00 1.143646e-02 277.01 -2.00 20.00 -2.00 321.59 0.00e+00 6.261 0.004 302.00 328.00 3 2.3919e+00 3.0786e-02 7.5470e-02 -6.0000e+00 6.4128e-01 7.9366e-01 4.2192e-02 4.3978e-02 -6.0000e+00 7.0246e-01 -1.0591e+00 4.4983e-02 2.4401e-02 -6.0000e+00 4.1146e-01 4.2908e-01 2.2332e-02 8.3108e-03 -6.0000e+00 1.7428e-01 4.0054e-05 -1.4884e-03 4.8172e-04 1.1208e-04 -6.0000e+00 1.2507e-02 9.3845e-03 -9.5481e-05 12 8 8 10 0 0 -13.37 18.96 0.72 0.00938 -0.00180 31 7 1 5 0 1594.174 24.56 19.99 18.96 14.56 30.0 914.49 -62584 -94759 900000 900000 900000 -130262 -108718 900000 -202241 900000 -127156 79619 -118249 -79384 -41554 62832 23900 -81171 28157 -77355 129015 -68203 -63610 -32165 35975 -15540 -4045 900000 -73328 900000 -9799 900000 -20429 30924 210124 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-2212 2910 -1133 -916 2176 -372 1881 -2849 15 -2494 -3202 -1713 -3882 -2954 -2645 -1582 583 -1859 -1137 -921 680 -2547 -1509 -1125 55 90 -1390 -1368 -2714 2021 828 -44 -1711 115 -993 -1518 -503 2109 2728 1381 2182 435 1200 3638 2140 2098 999 1925 792 2235 648 -1568 76 -1097 3487 -500 -1831 220 -3851 -2444 SS 20220215T061922.0Z 8081.263449 283 1 48.76 2 78.99 115.81 104.57 313.41 0.00 1 0.00 1 0 17 5.113e-01 1.030e-02 2.279e-01 5.714e-03 7.052352e-01 3.012460e-03 7.517661e-03 -6.000000e+00 2.835380e-01 225.02 -2.00 3.45 -2.00 321.49 0.00e+00 4.128612e-03 1.226796e-03 7.240934e-04 -6.000000e+00 1.151254e-02 277.01 -2.00 20.00 -2.00 321.14 0.00e+00 5.050 0.002 302.00 328.00 3 2.1354e+00 9.2155e-03 6.1268e-02 -6.0000e+00 7.0569e-01 1.5243e-01 1.3120e-02 3.6559e-02 -6.0000e+00 7.7187e-01 -2.3930e-01 1.5502e-02 2.0488e-02 -6.0000e+00 4.5486e-01 9.8808e-02 7.6320e-03 6.9173e-03 -6.0000e+00 1.9029e-01 2.0781e-04 -6.1789e-04 1.5957e-04 8.0342e-05 -6.0000e+00 1.3090e-02 8.6342e-03 -7.7850e-05 12 8 8 10 0 0 33.18 18.98 0.40 0.00863 0.00399 86 20 1 5 0 566.983 24.56 20.00 18.98 15.52 30.1 921.02 -221233 -231754 -173318 -172168 -157327 -158230 -31565 71513 -155700 -101380 -199571 -80896 -159024 -61210 -59375 -84974 -75500 -34711 -38102 -29134 -8674 -29846 3747 148 -23127 495 -22015 -26528 -31371 -27998 -11940 -1723 -6342 -17299 -11925 -23413 -9668 -3144 -2280 6230 3978 6529 6392 120 9634 8059 3618 2039 16877 2232 12567 9861 11925 8648 11224 10830 3843 7923 1997 2726 -345 2979 8761 4084 4952 1675 4216 -875 3606 4252 1544 3879 -180 3085 1622 -2396 -526 -162 2111 -1644 1063 -847 -1824 -1937 -1851 -478 -1420 -45 -517 989 219 758 -902 -898 294 -1755 -634 24 -212 -568 -192 -175 -452 -707 42 -1206 -1229 -843 -185 -572 461 -150 447 174 96 223 378 -225 -509 152 -300 421 199 361 674 592 821 983 971 236 135 191 526 184 -233 -330 -319 237 -83 -196 169 -403 -437 -3026 -4344 -2019 -2006 -1578 -1499 -176 398 -1909 -791 -3943 -586 -2900 -614 -761 -1752 -1641 -561 -701 -519 -131 -549 50 2 -477 9 -491 -606 -734 -671 -293 -47 -216 -733 -465 -978 -377 -135 -109 331 248 430 447 9 683 596 288 171 1291 211 1197 1094 1432 1174 1586 1602 631 1248 323 425 -57 519 1655 929 1206 416 1002 -225 975 1331 554 1427 -68 1069 519 -711 -142 -44 631 -614 457 -428 -1030 -1161 -1181 -321 -1015 -33 -377 686 143 458 -533 -548 200 -1430 -596 24 -231 -626 -197 -174 -408 -639 41 -1254 -1348 -988 -217 -765 682 -239 710 268 140 310 530 -334 -803 247 -482 642 292 513 918 848 1131 1424 1478 412 260 392 1131 423 -576 -856 -844 632 -221 -499 400 -893 -939 SS 20220215T062541.5Z 8081.267842 286 1 48.64 2 77.87 116.90 105.45 314.55 0.00 1 0.00 1 0 17 4.289e-01 8.276e-03 1.615e-01 3.547e-03 6.526429e-01 1.837484e-03 6.971069e-03 -6.000000e+00 2.378238e-01 225.02 -2.00 3.45 -2.00 321.27 0.00e+00 3.668950e-03 7.135341e-04 5.982514e-04 -6.000000e+00 9.792094e-03 277.01 -2.00 20.00 -2.00 320.93 0.00e+00 4.619 0.002 302.00 328.00 3 1.8840e+00 5.4777e-03 5.6068e-02 -6.0000e+00 5.9194e-01 7.1322e-02 7.6749e-03 3.3443e-02 -6.0000e+00 6.4743e-01 -1.2659e-01 9.0613e-03 1.8626e-02 -6.0000e+00 3.8183e-01 4.9900e-02 4.5306e-03 6.2295e-03 -6.0000e+00 1.6034e-01 4.2558e-04 -6.3421e-04 9.9144e-05 6.5643e-05 -6.0000e+00 1.1101e-02 8.3962e-03 -9.4475e-05 11 9 0 11 8 0 17.84 19.01 0.22 0.00840 0.00363 136 31 1 5 0 357.643 24.56 20.00 19.01 16.06 30.1 924.42 -195462 -78077 -192321 900000 -180335 -117076 -154142 -129772 -56328 -152513 21367 -139733 -71191 -85287 -50802 9974 -60935 25333 -21067 50984 -17693 -29236 -28578 -44823 4278 -44865 12198 -48299 -21518 -13936 -14605 1110 -13974 23668 -12469 10804 -8892 5271 -55 -2057 11083 1073 13250 2478 4218 715 2683 6792 1130 10445 4484 9096 637 2096 5765 3212 7027 -419 3514 -1142 3937 3409 2861 6145 1314 3593 845 1070 946 949 967 818 1090 -361 1797 -2436 -730 -341 -784 924 -871 402 -2043 -1348 -1792 -1122 -201 -288 947 -169 1039 285 -638 -215 -618 272 -236 445 218 -495 -438 -303 454 -846 -212 -1645 -395 -845 -447 -135 -18 316 -92 240 113 230 340 -128 105 -601 -81 94 789 101 386 795 311 1173 263 182 -5 32 2 74 75 -60 -158 116 -76 -295 -35 -23 -342 -2581 -393 -3386 900000 -2608 -847 -1696 -1265 -331 -2349 74 -2152 -694 -1260 -687 100 -1303 280 -371 511 -334 -616 -611 -1226 78 -1425 226 -1609 -534 -337 -422 34 -580 752 -553 363 -391 237 -3 -149 808 94 1087 234 398 72 271 681 126 1126 570 1143 96 340 962 573 1250 -81 629 -209 700 668 645 1530 369 966 228 294 285 333 378 337 445 -141 630 -795 -216 -101 -260 360 -406 213 -1222 -847 -1207 -803 -150 -223 722 -125 711 183 -395 -135 -439 223 -226 485 262 -601 -497 -306 413 -783 -211 -1759 -438 -1009 -583 -197 -26 500 -146 366 176 341 508 -201 162 -970 -129 142 1243 155 567 1119 424 1658 427 308 -10 63 4 162 177 -148 -398 296 -193 -719 -80 -50 -714 SS 20220215T063101.4Z 8081.271544 289 1 48.67 2 76.94 117.82 106.17 315.53 0.00 1 0.00 1 0 25 3.280e-01 7.396e-03 1.296e-01 2.658e-03 6.152615e-01 1.368752e-03 6.699749e-03 -6.000000e+00 1.819115e-01 225.02 -2.00 3.45 -2.00 321.06 0.00e+00 2.872270e-03 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