File name: Pandora119s1_Athens-NOA_20220607_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20250409T110621.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20220607_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20220607 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220607T041230.6Z 8193.175354 102 1 43.79 2 78.33 70.15 130.75 357.14 0.00 1 0.00 1 0 25 4.086e-01 1.039e-02 2.847e-01 6.376e-03 6.156121e-01 3.389965e-03 6.571364e-03 -6.000000e+00 2.329048e-01 232.33 -2.00 3.45 -2.00 321.27 0.00e+00 2.858425e-03 1.278166e-03 5.543072e-04 -6.000000e+00 9.202233e-03 286.95 -2.00 20.00 -2.00 320.91 0.00e+00 4.783 0.002 302.00 328.00 3 2.4809e+00 1.0230e-02 5.7327e-02 -6.0000e+00 5.8971e-01 5.2827e-02 1.3784e-02 3.2748e-02 -6.0000e+00 6.4122e-01 -1.2583e-01 1.5687e-02 1.7634e-02 -6.0000e+00 3.7578e-01 5.4482e-02 7.8509e-03 5.6821e-03 -6.0000e+00 1.5504e-01 2.0840e-04 -3.9286e-04 1.8499e-04 6.4369e-05 -6.0000e+00 1.0473e-02 1.1641e-04 -1.0603e-04 12 9 9 12 1 1 99.99 21.29 0.26 0.00012 -0.00284 79 20 1 5 0 545.273 26.41 20.00 21.29 27.53 33.4 1004.19 -213405 -113645 -174784 -46543 -93088 -102588 32131 -194177 139463 -121435 -68919 -50672 -20522 1947 -25582 100938 -61815 91924 -35346 20121 -1600 19689 -977 -47790 12213 -33381 8427 -17186 -30232 -11081 -38116 8909 -28402 24186 -22661 3632 13737 -10343 28311 -9086 13371 -2870 3075 -1721 9580 10046 -5035 14981 1061 8736 2886 8107 6304 4473 8683 -2398 6424 2534 4574 -466 2754 4726 -588 7819 -24 3841 2259 1366 4312 168 5223 423 2443 -482 610 -1835 -1401 -1194 -1868 2184 -1930 983 -2979 -2462 -1767 -1086 204 -1735 1045 -685 1877 599 -1520 1411 -1980 -93 -1114 1175 -771 638 -238 -464 -192 -1077 68 -1245 62 -680 165 -138 -484 442 -68 224 -53 65 556 -188 -67 -594 409 -678 1321 244 500 745 14 1373 -221 572 -302 161 23 101 400 -503 334 200 -238 -419 -70 -122 -268 -4128 -1033 -3139 -289 -741 -842 200 -4382 867 -1742 -634 -416 -153 15 -331 628 -1552 595 -828 300 -30 308 -18 -1566 239 -1102 189 -489 -947 -297 -1501 275 -1439 839 -1179 144 529 -574 1317 -749 1010 -266 285 -173 872 967 -556 1442 118 949 367 1102 960 757 1504 -484 1233 509 877 -92 537 985 -142 1970 -7 1054 631 378 1305 59 1973 177 1002 -194 224 -639 -446 -376 -651 839 -908 515 -1793 -1562 -1190 -780 153 -1375 809 -523 1302 391 -961 877 -1414 -75 -1056 1209 -890 732 -258 -470 -177 -1004 68 -1339 70 -789 207 -193 -755 724 -113 354 -79 92 788 -282 -107 -999 679 -1096 2020 365 715 1024 20 1929 -344 994 -579 326 48 219 929 -1243 835 511 -609 -1033 -162 -274 -586 SS 20220607T041728.6Z 8193.178803 105 1 1.83 2 77.41 70.84 130.80 358.68 0.00 1 0.00 1 0 17 4.757e-01 2.211e-02 3.657e-01 1.972e-02 5.624108e-01 1.029794e-02 6.224040e-03 -6.000000e+00 2.713083e-01 232.33 -2.00 3.45 -2.00 320.47 0.00e+00 1.959180e-03 3.236741e-03 3.527339e-04 -6.000000e+00 1.107848e-02 286.95 -2.00 20.00 -2.00 320.13 0.00e+00 4.458 0.001 302.00 328.00 3 2.5724e+00 2.9480e-02 5.2944e-02 -6.0000e+00 6.8695e-01 5.2828e-02 3.5986e-02 2.9447e-02 -6.0000e+00 7.4773e-01 -1.5639e-01 3.5698e-02 1.5179e-02 -6.0000e+00 4.3809e-01 6.9445e-02 1.8637e-02 4.6239e-03 -6.0000e+00 1.8334e-01 2.7608e-04 -1.0634e-03 5.5494e-04 4.8133e-05 -6.0000e+00 1.2321e-02 4.0382e-04 -1.7041e-04 12 9 9 12 1 1 999.00 21.30 0.43 0.00040 -0.00759 1 13 1 5 0 832.519 26.41 20.00 21.30 27.72 33.5 1005.44 900000 -132458 900000 -117694 -119346 -94409 -10988 226253 -132763 29585 -80597 -85785 -28752 -115285 81355 -53328 95441 -93594 64546 -7063 900000 900000 85433 900000 -44722 93005 -32479 263737 33960 -18809 27345 -2424 120212 -12106 -22718 -25624 -4687 34846 -239 39074 -3504 24842 -16062 3691 -4413 8281 22254 16189 8158 10935 12393 -5160 11928 8800 -7 10013 1639 11061 -293 10545 2461 2999 8264 4970 12862 789 -2949 895 2200 -3330 -86 2182 -454 3228 -5023 -2411 -2371 2463 2110 -2700 2436 -3633 -339 -3115 -2347 2802 -1409 -1159 -368 2291 -1667 -1229 -4879 -1663 -490 -1180 210 852 990 -385 1146 -2049 512 -2601 -3111 -1408 -2846 1199 2478 -1572 1168 -792 708 336 328 273 -1133 389 -439 1445 -320 868 389 -63 3313 -186 2360 1066 -340 46 2690 -1504 -1130 54 -332 979 771 429 -1626 -733 -432 967 -1304 900000 -3499 900000 -2968 -2829 -1814 -211 4347 -4410 568 -1845 -2174 -552 -5814 1563 -2177 1834 -6899 1240 -263 900000 900000 1641 900000 -2936 1787 -2067 5067 1078 -1007 1074 -149 2617 -1027 -2082 -2297 -364 2179 -25 3425 -516 3029 -2983 591 -773 1301 3150 2475 1363 1857 2267 -1234 2633 2175 -2 2652 489 3024 -88 2816 712 936 2763 1897 4830 318 -1206 354 929 -1662 -47 1199 -257 1712 -2672 -1140 -1043 1013 946 -1442 1446 -2525 -246 -2424 -1938 2362 -1270 -1079 -342 2045 -1445 -999 -3875 -1304 -411 -1108 220 984 1215 -483 1351 -2324 525 -2773 -3566 -1660 -3522 1517 3301 -2317 1819 -1289 1147 523 492 396 -1646 584 -689 2347 -523 1376 608 -96 4790 -267 3268 1515 -532 78 4708 -2821 -2169 107 -689 2091 1667 949 -3632 -1583 -901 1928 -2579 SS 20220607T043224.0Z 8193.189167 111 1 48.25 2 74.61 72.91 130.80 3.31 0.00 1 0.00 1 0 17 1.074e-01 4.489e-03 3.608e-02 1.472e-03 4.899723e-01 7.530754e-04 5.370780e-03 -6.000000e+00 6.124558e-02 232.33 -2.00 3.45 -2.00 320.44 0.00e+00 1.052939e-03 2.314284e-04 2.949923e-04 -6.000000e+00 2.419414e-03 286.95 -2.00 20.00 -2.00 320.10 0.00e+00 3.698 0.001 302.00 328.00 3 1.4133e+00 2.1519e-03 4.4513e-02 -6.0000e+00 1.5507e-01 -8.6951e-03 2.6208e-03 2.5394e-02 -6.0000e+00 1.6860e-01 -9.3091e-03 2.6269e-03 1.3151e-02 -6.0000e+00 9.8809e-02 -9.5178e-04 1.3836e-03 4.0417e-03 -6.0000e+00 4.0779e-02 1.9227e-03 -9.9937e-05 4.2521e-05 4.0400e-05 -6.0000e+00 2.7532e-03 -1.0085e-03 -6.5894e-05 10 0 0 10 0 0 99.97 21.36 0.19 -0.00101 -0.00176 363 83 1 5 0 132.903 26.51 20.01 21.36 28.68 33.4 1011.73 -32047 -53310 -18980 -26427 -44591 -19659 -45241 -33089 -32967 -19038 -28638 -37345 -20769 -19218 -8492 -14818 -6479 -11252 1558 -2126 -3092 469 -5861 -2308 -6398 -2311 -1269 -4038 -5135 -7806 -10 -3171 3143 -784 -2879 -3912 -3635 -173 -1883 1358 -205 -850 -246 236 947 -640 229 -139 897 -267 1994 1623 847 2054 751 1543 818 728 361 672 1026 210 1819 1474 1494 -144 373 -284 874 1083 -254 718 -245 324 -549 -217 29 -1124 -204 -1121 -418 -1135 -1606 -1359 -1258 -321 -365 209 421 765 643 717 328 345 542 101 593 648 265 -128 -494 -203 -237 29 -808 -869 -655 -679 -18 -13 387 132 307 149 67 282 100 -35 -346 -350 -539 -286 162 104 572 119 513 905 548 130 -57 -124 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