File name: Pandora119s1_Athens-NOA_20220720_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20250409T110739.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20220720_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20220720 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220720T040308.3Z 8236.168846 214 1 48.41 2 82.72 69.42 31.94 181.65 0.00 1 0.00 1 0 41 4.949e-01 2.823e-02 4.090e-01 2.173e-02 8.600267e-01 1.257912e-02 8.903606e-03 -6.000000e+00 2.852317e-01 232.41 -2.00 3.45 -2.00 322.23 0.00e+00 1.059366e-02 5.298904e-03 1.039430e-03 -6.000000e+00 1.182553e-02 290.61 -2.00 20.00 -2.00 321.85 0.00e+00 7.269 0.006 302.00 328.00 3 1.3895e+00 4.1207e-02 8.5200e-02 -6.0000e+00 7.2282e-01 1.0756e+00 5.1061e-02 4.5260e-02 -6.0000e+00 7.8745e-01 -1.5322e+00 4.6755e-02 2.4001e-02 -6.0000e+00 4.6226e-01 6.3627e-01 2.4260e-02 7.9448e-03 -6.0000e+00 1.9075e-01 4.0722e-05 -1.5244e-03 6.3736e-04 1.0872e-04 -6.0000e+00 1.3188e-02 -6.9833e-04 -1.6121e-04 12 8 8 10 0 0 99.98 21.53 0.52 -0.00070 -0.01215 56 13 1 5 0 864.399 26.62 20.00 21.53 28.81 33.7 997.63 -86459 -29895 59558 900000 900000 -117393 144380 -72335 -29653 -92239 -46926 92820 -48041 900000 -95730 900000 -34993 900000 150458 33288 112061 158882 900000 -44577 900000 -20084 9820 66036 -36095 -16906 -35952 115723 -18269 38499 -3409 38378 67646 55401 92687 9008 55805 340 3040 89547 34892 82833 -727 265856 6239 48538 11364 33585 69555 10251 94372 20860 30411 51511 -6345 33607 -3970 76348 -1165 41343 25701 27725 36188 -8956 33252 -3430 17858 12443 25373 23715 9791 7113 -16079 1978 -5622 5115 -4146 5515 8039 426 4874 -3928 8882 278 -1912 -2575 -1047 5780 -10649 6240 -9036 1476 -2778 -1374 -4381 -4332 -667 -3119 1484 -7138 306 -1977 632 570 -2937 -1357 -3035 -2568 -1425 143 -247 450 77 -1954 2722 -2009 1756 3942 1211 1906 506 1566 454 3251 1726 -671 2732 1542 1566 -215 -683 -1000 -636 1003 524 1085 -1530 -168 -2906 -4422 -1002 1260 900000 900000 -6211 3056 -2366 -628 -3549 -1083 1964 -1386 900000 -6753 900000 -1952 900000 3184 1025 2372 3362 900000 -2401 900000 -811 283 1398 -1458 -585 -1798 2449 -1090 1407 -177 1181 1562 1599 2140 555 2362 26 234 2929 1947 2869 -59 5626 504 2708 1006 2649 4148 1183 4902 2288 3042 4063 -842 2845 -489 4554 -173 4613 3659 3841 4526 -1809 4798 -825 3848 2945 5174 4563 1940 1273 -3341 350 -1222 1220 -1300 1825 2651 161 1865 -1746 3650 128 -904 -1185 -443 2335 -4507 2545 -4526 796 -1862 -1069 -3948 -3995 -560 -2393 965 -4973 213 -1499 493 483 -2880 -1515 -3950 -3637 -2053 200 -334 584 101 -2781 3937 -3168 2617 5458 1651 2511 654 1949 555 4094 2578 -1196 5291 3279 3549 -532 -1829 -2829 -1824 2866 1495 2928 -3918 -392 -6647 SS 20220720T041402.8Z 8236.176422 217 1 48.84 2 80.69 70.99 32.05 186.68 0.00 1 0.00 1 0 25 5.846e-01 1.148e-02 2.593e-01 6.459e-03 7.477774e-01 3.535898e-03 7.788539e-03 -6.000000e+00 3.334140e-01 232.41 -2.00 3.45 -2.00 321.79 0.00e+00 5.138248e-03 1.489395e-03 8.483666e-04 -6.000000e+00 1.316731e-02 290.61 -2.00 20.00 -2.00 321.42 0.00e+00 5.874 0.003 302.00 328.00 3 1.2227e+00 1.1240e-02 7.0456e-02 -6.0000e+00 8.4438e-01 2.3765e-01 1.6553e-02 4.0590e-02 -6.0000e+00 9.1798e-01 -3.7888e-01 1.9571e-02 2.2752e-02 -6.0000e+00 5.3795e-01 1.6063e-01 9.4615e-03 7.6535e-03 -6.0000e+00 2.2197e-01 2.2455e-04 -8.4145e-04 1.8560e-04 8.8104e-05 -6.0000e+00 1.4985e-02 -1.1903e-03 -7.9495e-05 12 9 8 11 8 0 99.97 21.56 0.34 -0.00119 -0.00751 136 31 1 5 0 359.049 26.62 20.00 21.56 29.21 33.5 999.76 -171103 -140532 -188945 -196636 -105120 -175918 -201952 -214253 -210404 -66964 -190493 -174387 -163224 -97272 -103095 -80423 -60903 -75038 21652 -55930 4463 -2526 -56218 -42325 -44633 -66464 -74840 -44270 -70254 -28712 -10204 -35213 8700 3302 5903 -26393 -10948 -27700 11858 -6091 -2486 12513 16159 12251 5604 10243 8529 10788 12840 1840 15049 11770 22112 8216 12640 12970 10403 2839 7084 13193 6701 4009 7962 3897 6807 7119 3707 4198 6741 4224 5342 5062 4036 4470 1576 3077 -2042 -2064 -1097 -1962 -1531 108 -316 -2120 48 -407 -80 -539 -417 618 -683 1667 -641 -1032 -782 -1819 -239 -988 -230 -987 -270 -707 -804 -24 -1390 -942 -1192 -1064 -134 -565 -303 -466 44 -355 349 -279 187 150 139 -366 -283 352 1256 943 728 1209 509 1336 547 226 538 -12 286 82 -126 80 -157 86 88 156 -293 -523 -832 -1293 -974 -2164 -2477 -662 -1662 -2544 -3374 -3578 -422 -3000 -2526 -2673 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4.8637e-03 6.0481e-02 -6.0000e+00 6.0769e-01 6.3974e-02 6.7824e-03 3.5146e-02 -6.0000e+00 6.6058e-01 -1.1760e-01 7.9998e-03 1.9240e-02 -6.0000e+00 3.8712e-01 4.8407e-02 3.9769e-03 6.2928e-03 -6.0000e+00 1.5979e-01 6.6252e-04 -3.6776e-04 8.6125e-05 7.2727e-05 -6.0000e+00 1.0781e-02 -1.9763e-03 -2.4733e-05 11 8 0 10 0 0 99.98 21.58 0.26 -0.00198 -0.00474 230 53 1 5 0 211.876 26.62 20.01 21.58 29.47 33.7 1001.55 -156454 -181066 -56908 -159063 -28726 -178586 -104582 -151483 -123423 -96626 -124907 -7597 -107799 -91258 -96898 -39633 -40466 -37987 -22794 -44645 -9211 -40849 -40181 -33058 -31447 -16138 -47567 -11095 -40378 -13585 -20861 -14666 -194 -9649 -486 -16618 -1311 -2719 -2767 -1698 -1724 7477 1631 8137 -2937 3013 778 -1217 4553 923 7761 4052 9343 1222 3980 5327 2852 4084 -615 2133 -292 2657 2875 2985 4007 1559 3305 267 3070 1473 1585 1191 439 1397 -375 -320 -2867 -947 248 577 67 -1118 -977 -2234 -577 -1376 -495 -121 50 1265 22 1071 -464 91 42 -417 -27 238 208 -505 -120 -355 -570 -39 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