File name: Pandora119s1_Athens-NOA_20220901_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20250409T110740.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20220901_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20220901 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220901T044706.8Z 8279.199384 67 1 49.51 2 80.58 86.81 136.12 67.11 0.00 1 0.00 1 0 25 4.497e-01 2.314e-02 3.516e-01 1.690e-02 7.088166e-01 9.422516e-03 7.527521e-03 -6.000000e+00 2.555138e-01 230.33 -2.00 3.45 -2.00 321.85 0.00e+00 4.554058e-03 3.847887e-03 7.626438e-04 -6.000000e+00 1.123526e-02 290.08 -2.00 20.00 -2.00 321.47 0.00e+00 5.810 0.003 302.00 328.00 3 3.0498e+00 2.9823e-02 6.8367e-02 -6.0000e+00 6.4356e-01 4.0676e-01 3.9561e-02 3.7603e-02 -6.0000e+00 7.0117e-01 -7.1872e-01 4.1499e-02 2.0382e-02 -6.0000e+00 4.1092e-01 3.1003e-01 2.0761e-02 6.7185e-03 -6.0000e+00 1.7121e-01 4.0983e-05 -1.1888e-03 5.0773e-04 8.5219e-05 -6.0000e+00 1.1797e-02 -1.1476e-03 -1.0721e-04 12 9 8 11 8 0 78.14 21.44 0.67 -0.00115 -0.01008 25 6 1 5 0 1980.136 26.51 20.01 21.44 29.74 33.8 988.76 129358 -92926 -109842 900000 -150394 900000 -53013 -166626 -147608 -152810 900000 -88782 900000 -114006 900000 -121080 -50301 96422 -24962 37050 -14997 16120 -1156 -15785 -21582 -76567 207422 -49304 18963 -47847 -9316 20851 19980 20294 25927 4727 435 14076 -14182 -33292 2233 28023 20040 9225 34600 23409 54495 -18480 12307 8378 30827 67184 16369 49911 8822 17966 9242 18982 17542 4649 18490 -975 35772 21542 20613 12585 11437 23596 8930 25280 8477 16343 4760 2621 6730 -6182 -4249 -7987 -4130 -10170 -5977 4497 -4879 1772 -2700 482 -958 3592 2993 -2322 999 -5617 2820 -7279 -5896 -2478 -3536 154 -760 -525 -3638 -1071 -747 1216 -1332 -418 -1463 -317 -371 -1768 384 -1452 -1318 1679 1720 308 241 -159 -2139 1338 -2114 -1619 1986 2291 3128 1735 2723 1560 786 1161 326 824 1106 -562 -25 31 80 18 310 -570 -56 -1268 -1095 2130 -1530 -2302 900000 -4052 900000 -873 -4988 -3977 -4574 900000 -1462 900000 -3754 900000 -6524 -1506 1587 -672 610 -420 318 -27 -442 -675 -3896 3415 -2029 375 -1891 -291 584 658 735 854 179 18 579 -934 -2890 154 1753 1419 744 2165 1657 2871 -1881 1054 786 2538 4314 1739 4519 1162 2232 1286 2386 2153 626 2186 -152 4829 3482 3640 2373 2122 3955 1884 5259 2334 4378 1425 757 1702 -1582 -979 -1913 -1057 -3318 -2218 1737 -2300 830 -1410 261 -557 2064 1738 -1380 537 -3010 1330 -3889 -3494 -1665 -2810 137 -758 -532 -3588 -925 -579 919 -1118 -370 -1382 -318 -410 -2247 538 -2226 -2045 2463 2395 417 329 -229 -3349 2119 -3440 -2515 2866 3199 4176 2273 3403 2057 1194 2008 629 1695 2392 -1318 -62 83 215 51 846 -1503 -138 -2939 -2441 SS 20220901T045558.4Z 8279.205538 72 1 48.89 2 78.84 88.16 134.59 69.09 0.00 1 0.00 1 0 25 4.267e-01 1.343e-02 2.652e-01 7.765e-03 6.375265e-01 4.100561e-03 6.849475e-03 -6.000000e+00 2.415842e-01 230.33 -2.00 3.45 -2.00 321.39 0.00e+00 9.836762e-03 1.598310e-03 5.839936e-04 -6.000000e+00 9.638342e-03 290.08 -2.00 20.00 -2.00 321.05 0.00e+00 4.981 0.002 302.00 328.00 3 2.7281e+00 1.2445e-02 5.9365e-02 -6.0000e+00 6.0875e-01 1.6114e-01 1.7008e-02 3.3629e-02 -6.0000e+00 6.6327e-01 -3.2467e-01 1.9288e-02 1.8186e-02 -6.0000e+00 3.8901e-01 1.4216e-01 9.6074e-03 5.9095e-03 -6.0000e+00 1.6236e-01 1.3068e-04 -1.2251e-03 2.2339e-04 6.4025e-05 -6.0000e+00 1.1035e-02 -1.4743e-03 -9.5657e-05 12 8 8 10 0 0 14.18 21.45 0.46 -0.00147 -0.01068 52 12 1 5 0 940.014 26.51 20.00 21.45 30.25 33.9 992.28 900000 -143364 112022 -193045 63157 -162412 -107978 -160542 -131718 -24947 -192004 -30164 -105729 -35810 -74999 -35335 16021 1948 76140 -45792 50375 -23646 -33171 12302 -8483 -2208 -64435 71205 -65589 16300 -13280 -13777 36111 -91 29969 -19709 6436 13385 3990 -4023 7446 17816 6204 13239 1715 8072 16055 7830 26233 -3655 18790 3755 9884 6461 5162 4221 9412 10941 7727 6706 2294 3064 1886 5876 7347 2523 6731 2369 5404 2360 1933 2970 2479 4456 -5334 3942 377 -4498 -1696 -5664 -1713 -2435 -165 -1820 -1086 -1557 -309 -171 643 1574 -1232 1440 -123 -1120 -163 -1951 1440 -1092 -328 -1302 -22 -571 1627 145 -1715 -866 -1903 -820 -1504 188 -294 272 540 -8 442 -912 -207 433 -87 -435 -182 709 -266 1380 333 859 1238 1275 759 343 328 339 344 544 -230 102 -65 160 -578 -122 -1015 -47 -109 900000 -2269 848 -5713 478 -2906 -1226 -2983 -1994 -189 -5682 -228 -1921 -434 -1600 -696 218 34 692 -1355 648 -627 -954 233 -206 -52 -2617 809 -2618 333 -432 -553 1039 -4 998 -922 268 598 214 -280 523 1214 504 1048 156 711 1348 738 2149 -425 1914 499 1354 992 849 721 1561 1785 1266 1089 399 580 413 1411 1881 667 1649 613 1465 765 705 1130 947 1586 -1924 1159 105 -1313 -531 -2206 -758 -1247 -91 -1084 -684 -1057 -219 -126 473 1114 -838 886 -73 -677 -109 -1543 1283 -1153 -381 -1550 -25 -572 1440 130 -1691 -900 -2102 -957 -1930 267 -428 420 834 -11 679 -1354 -306 669 -132 -696 -290 1177 -429 2123 497 1232 1701 1813 1229 579 609 670 712 1190 -544 255 -165 413 -1506 -304 -2402 -104 -231 SS 20220901T050211.2Z 8279.209852 75 1 49.06 2 77.61 89.11 133.51 70.43 0.00 1 0.00 1 0 25 3.500e-01 7.491e-03 1.819e-01 4.794e-03 5.926609e-01 2.535703e-03 6.453016e-03 -6.000000e+00 1.981114e-01 230.33 -2.00 3.45 -2.00 321.21 0.00e+00 4.736221e-03 9.388974e-04 5.146277e-04 -6.000000e+00 7.882919e-03 290.08 -2.00 20.00 -2.00 320.86 0.00e+00 4.526 0.002 302.00 328.00 3 2.5285e+00 7.5780e-03 5.4420e-02 -6.0000e+00 4.9919e-01 1.1030e-02 1.0078e-02 3.1374e-02 -6.0000e+00 5.4356e-01 -1.0949e-01 1.1486e-02 1.6882e-02 -6.0000e+00 3.1906e-01 4.8909e-02 5.8058e-03 5.4315e-03 -6.0000e+00 1.3224e-01 2.6403e-04 -7.6856e-04 1.4112e-04 6.3409e-05 -6.0000e+00 8.9665e-03 -1.7519e-03 -6.8499e-05 11 8 0 10 0 0 32.37 21.46 0.31 -0.00175 -0.00753 82 19 1 5 0 598.227 26.51 20.00 21.46 30.60 33.8 994.38 -138669 -125476 -141021 -126195 -72159 -91221 -76170 51075 -101055 -121566 -126179 -125270 -40312 -64925 20992 -46504 13605 -43716 -41113 -27855 -30036 -1947 -15029 17591 -4236 3427 -8549 -27476 12150 -28170 868 -13461 -3696 634 -7008 -2638 -9333 7055 -71 6285 2729 443 4595 -204 10302 -1587 8360 -3684 8541 2730 1013 1421 4780 7927 3814 6530 4220 625 2027 -738 2907 1757 1603 3678 1031 1803 -2079 802 1441 405 21 885 -634 837 -460 -794 1154 -1713 -23 -2891 -1015 -1171 -1985 -1697 -691 -209 -553 -245 601 584 1275 47 1439 -34 867 -1343 -280 409 23 -195 -91 95 404 29 -948 -1330 -877 -882 -144 72 571 -147 393 -87 126 560 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