File name: Pandora119s1_Athens-NOA_20220905_L2Fit_fout2c3d20201216p1-8.txt File generation date: 20250409T110705.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_OF_v1d20201007.txt Instrument calibration file used: Pandora119s1_CF_v3d20201216.txt Level 1 file used: Pandora119s1_Athens-NOA_20220905_L1_smca1c3d20201216p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20220905 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 366 Nominal wavelengths inside fitting window [nm]: 305.0034 305.1447 305.2860 305.4272 305.5685 305.7097 305.8509 305.9921 306.1334 306.2745 306.4157 306.5569 306.6980 306.8392 306.9803 307.1215 307.2626 307.4037 307.5448 307.6858 307.8269 307.9680 308.1090 308.2501 308.3911 308.5321 308.6731 308.8141 308.9551 309.0960 309.2370 309.3779 309.5189 309.6598 309.8007 309.9416 310.0825 310.2234 310.3643 310.5051 310.6460 310.7868 310.9276 311.0685 311.2093 311.3501 311.4908 311.6316 311.7724 311.9131 312.0538 312.1946 312.3353 312.4760 312.6167 312.7574 312.8980 313.0387 313.1793 313.3200 313.4606 313.6012 313.7418 313.8824 314.0230 314.1635 314.3041 314.4446 314.5852 314.7257 314.8662 315.0067 315.1472 315.2877 315.4281 315.5686 315.7090 315.8495 315.9899 316.1303 316.2707 316.4111 316.5515 316.6918 316.8322 316.9725 317.1129 317.2532 317.3935 317.5338 317.6741 317.8144 317.9546 318.0949 318.2351 318.3753 318.5156 318.6558 318.7960 318.9361 319.0763 319.2165 319.3566 319.4968 319.6369 319.7770 319.9171 320.0572 320.1973 320.3374 320.4774 320.6175 320.7575 320.8975 321.0376 321.1776 321.3176 321.4575 321.5975 321.7375 321.8774 322.0173 322.1573 322.2972 322.4371 322.5770 322.7169 322.8567 322.9966 323.1364 323.2763 323.4161 323.5559 323.6957 323.8355 323.9752 324.1150 324.2548 324.3945 324.5342 324.6739 324.8136 324.9533 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220905T053221.3Z 8283.230802 87 1 48.61 2 72.31 95.23 169.27 354.42 0.00 1 0.00 1 0 25 1.078e-01 6.564e-03 6.823e-02 3.547e-03 4.218763e-01 1.790954e-03 4.765055e-03 -6.000000e+00 6.093415e-02 230.03 -2.00 3.45 -2.00 319.93 0.00e+00 1.540696e-03 4.778000e-04 2.067766e-04 -6.000000e+00 2.427599e-03 289.81 -2.00 20.00 -2.00 319.59 0.00e+00 3.245 0.001 302.00 328.00 3 3.6441e+00 5.0062e-03 3.8668e-02 -6.0000e+00 1.5343e-01 -6.6309e-04 5.8589e-03 2.1652e-02 -6.0000e+00 1.6712e-01 -1.0269e-02 5.2267e-03 1.1016e-02 -6.0000e+00 9.8117e-02 1.4850e-03 2.7967e-03 3.3060e-03 -6.0000e+00 4.0678e-02 3.4317e-04 -1.0039e-05 1.0271e-04 3.4595e-05 -6.0000e+00 2.7613e-03 7.7497e-04 -4.6416e-05 11 9 0 11 8 0 99.98 21.15 0.26 0.00077 0.00070 48 11 1 5 0 1012.524 26.32 19.98 21.15 23.32 33.9 949.00 64494 -40112 -11627 -19685 -21482 18714 -46085 45064 -42256 4161 -26328 -16686 10822 -9206 632 -16609 10174 -4364 5661 -4317 -3518 12515 -12036 11899 -9001 5769 -9910 -3785 155 -8930 4955 433 7575 -7090 -2614 -2376 -6852 3976 -1258 3682 -5137 2492 1209 225 1018 -1560 2412 -1886 1080 -835 3124 1615 -317 3083 -590 2635 -962 1065 135 270 1017 -315 2973 851 1104 -364 262 -201 1246 573 -392 1397 -213 973 -183 -326 1360 -1804 482 -1358 206 -1990 -1120 -1252 -1703 -236 -1025 435 -150 946 46 579 441 -13 996 -616 1004 747 15 122 -871 231 -728 315 -767 -318 -975 -745 9 -271 709 31 522 -136 -121 697 248 -60 -515 141 -773 74 114 -155 952 13 697 398 717 208 89 -84 -187 389 -394 452 -361 144 -283 -252 -5 -241 131 502 -1001 -237 -433 -444 246 -1146 534 -1309 91 -778 -460 269 -334 25 -901 476 -247 311 -276 -232 703 -874 728 -733 429 -886 -308 11 -718 381 40 734 -867 -294 -253 -815 495 -197 661 -1140 547 281 54 245 -391 583 -475 266 -214 828 479 -103 1044 -218 973 -379 414 52 102 388 -132 1338 422 570 -181 124 -94 616 321 -247 912 -142 615 -108 -178 662 -871 241 -801 138 -1498 -909 -1069 -1527 -224 -1040 451 -158 949 44 509 360 -10 857 -608 1080 910 20 158 -1093 260 -783 341 -895 -392 -1267 -997 13 -420 1153 53 863 -218 -180 968 347 -88 -810 234 -1281 121 181 -237 1407 18 940 549 1082 339 152 -150 -345 748 -798 955 -787 313 -619 -546 -11 -482 254 SS 20220905T053856.6Z 8283.235377 91 1 3.37 2 71.02 96.29 169.31 1.85 0.00 1 0.00 1 0 25 1.379e-01 1.265e-02 1.287e-01 1.114e-02 4.002696e-01 5.554038e-03 4.601615e-03 -6.000000e+00 7.795917e-02 230.03 -2.00 3.45 -2.00 318.84 0.00e+00 1.076848e-03 1.119012e-03 1.420659e-04 -6.000000e+00 3.106438e-03 289.81 -2.00 20.00 -2.00 318.52 0.00e+00 3.038 0.000 302.00 328.00 3 3.7614e+00 1.5091e-02 3.6317e-02 -6.0000e+00 1.9629e-01 1.2133e-02 1.7116e-02 2.0411e-02 -6.0000e+00 2.1384e-01 -4.2081e-03 1.2884e-02 1.0171e-02 -6.0000e+00 1.2555e-01 1.7696e-03 6.9362e-03 2.9436e-03 -6.0000e+00 5.2029e-02 3.7688e-04 -2.2720e-04 3.0894e-04 2.9300e-05 -6.0000e+00 3.5340e-03 1.6299e-03 -1.2140e-04 12 9 9 12 1 1 999.00 21.09 0.39 0.00163 -0.00008 1 7 1 5 0 1600.861 26.32 19.98 21.09 23.53 33.9 951.48 -33298 48735 -22928 -6718 77649 -16412 -28402 19685 81994 2675 48804 -17274 -28429 16232 -24243 28396 -7316 4356 14184 -1614 21478 -8146 3237 -18185 4806 -6623 -1361 -2641 -8624 20251 -12564 14830 397 1478 219 -4926 -362 -5963 2346 -4347 1326 -3389 239 5994 2180 2215 -3420 439 -2491 -1659 188 2968 3456 1040 4869 -3028 3204 2524 859 2090 -820 2664 145 2160 -1672 2902 -2623 -224 -1020 -618 607 -3244 302 611 -176 240 662 4082 -1191 2114 -1947 -1930 -348 -744 -1072 -2088 -357 -1486 115 1672 -329 575 -802 835 1133 -416 -872 2459 569 -514 -185 -33 504 -744 -897 129 -2115 994 472 1775 -234 694 -487 -479 925 -643 621 -946 150 -470 -1286 581 -128 853 -282 395 -908 1046 289 951 414 302 -668 -1745 480 311 267 830 573 233 -123 -868 -907 -1270 1007 -996 -246 1181 -565 -1146 568 1492 112 1345 -899 -1903 861 -2208 1822 -717 404 1275 -178 2007 -998 358 -2607 604 -966 -193 -374 -1218 2169 -1947 2028 69 276 40 -889 -67 -1328 587 -1340 435 -1218 86 2139 795 816 -1334 164 -960 -646 77 1272 1588 514 2430 -1652 1692 1347 455 1097 -444 1503 90 1439 -1179 1884 -1683 -140 -674 -451 478 -2750 248 489 -134 170 430 2501 -798 1522 -1617 -1740 -329 -730 -1110 -2310 -405 -1736 133 1869 -354 581 -771 786 1127 -458 -1038 3092 765 -696 -241 -40 583 -875 -1116 166 -2870 1358 681 2670 -377 1126 -781 -743 1344 -907 876 -1378 229 -743 -2075 911 -199 1280 -413 558 -1253 1437 426 1479 674 503 -1139 -3075 871 580 510 1589 1104 442 -226 -1568 -1599 SS 20220905T054407.8Z 8283.238979 94 1 48.76 2 70.01 97.13 169.23 7.68 0.00 1 0.00 1 0 17 3.270e-02 4.440e-03 2.452e-02 2.053e-03 3.795784e-01 1.036634e-03 4.324635e-03 -6.000000e+00 1.848230e-02 230.03 -2.00 3.45 -2.00 319.60 0.00e+00 7.079918e-04 2.461538e-04 1.613584e-04 -6.000000e+00 7.364315e-04 289.81 -2.00 20.00 -2.00 319.25 0.00e+00 2.893 0.000 302.00 328.00 3 2.8164e+00 2.8691e-03 3.4564e-02 -6.0000e+00 4.6537e-02 -1.3325e-02 3.2977e-03 1.9410e-02 -6.0000e+00 5.0695e-02 1.1801e-02 2.7101e-03 9.7808e-03 -6.0000e+00 2.9763e-02 -9.9605e-03 1.4561e-03 2.9013e-03 -6.0000e+00 1.2336e-02 1.1607e-03 -5.1279e-05 6.0269e-05 3.0974e-05 -6.0000e+00 8.3771e-04 1.9679e-03 -7.0611e-05 11 1 0 11 8 0 99.94 21.06 0.27 0.00197 0.00158 247 57 1 5 0 197.382 26.21 19.99 21.06 24.00 33.8 954.32 -18907 -3976 -9828 -7486 -7730 -18940 -10522 -3185 -5025 -5152 -7159 -7388 -9460 -4109 -1940 1523 2061 2078 -3994 -209 -182 -2970 3076 -1480 -1320 -596 615 -1063 -131 1427 -132 3549 1872 797 -317 -593 -419 -1959 1211 -615 264 -1571 -2018 -438 -1439 249 -1516 -118 -1003 311 1204 767 967 699 693 547 1588 291 28 227 361 1371 839 1951 541 -116 173 -393 669 188 222 -25 -3 154 -22 -131 -98 -392 -724 101 -690 -730 -1754 -1543 -956 -592 -227 90 466 357 634 749 124 821 592 435 502 856 329 -343 -407 -609 -253 118 -344 -848 -952 -628 -140 199 174 263 151 221 112 80 331 -47 -115 -171 -573 -311 99 314 370 364 373 1038 475 111 -138 -190 -106 -37 -118 -124 -3 380 -109 39 -78 -123 -233 -465 -98 -277 -204 -190 -483 -257 -82 -151 -170 -245 -258 -386 -191 -105 93 136 145 -316 -17 -15 -254 251 -135 -130 -62 64 -109 -12 132 -13 393 236 110 -42 -75 -57 -315 230 -143 69 -443 -596 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