File name: Pandora38s1_BayonneNJ_20181220_L2Fit_fwvt1c1d20180507p1-8.txt File generation date: 20251206T171550.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 38 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora38_OF_v1d20170308.txt Instrument calibration file used: Pandora38s1_CF_v1d20180507.txt Level 1 file used: Pandora38s1_BayonneNJ_20181220_L1_smca1c1d20180507p1-8.txt Full location name: Bayonne NJDEP (USEPA AQS ID 34-017-0006) Short location name: BayonneNJ Country of location: USA Location latitude [deg]: 40.6703 Location longitude [deg]: -74.1261 Location altitude [m]: 3 Local noon date: 20181220 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1670 1820 Nominal wavelengths inside fitting window [nm]: 492.0004 492.1216 492.2428 492.3639 492.4851 492.6062 492.7273 492.8484 492.9695 493.0905 493.2116 493.3326 493.4536 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7836 494.9044 495.0251 495.1459 495.2667 495.3874 495.5081 495.6288 495.7495 495.8702 495.9908 496.1115 496.2321 496.3527 496.4732 496.5938 496.7144 496.8349 496.9554 497.0759 497.1964 497.3168 497.4373 497.5577 497.6781 497.7985 497.9189 498.0392 498.1596 498.2799 498.4002 498.5205 498.6408 498.7610 498.8813 499.0015 499.1217 499.2419 499.3620 499.4822 499.6023 499.7224 499.8425 499.9626 500.0827 500.2027 500.3228 500.4428 500.5628 500.6828 500.8027 500.9227 501.0426 501.1625 501.2824 501.4023 501.5221 501.6420 501.7618 501.8816 502.0014 502.1212 502.2409 502.3606 502.4804 502.6001 502.7197 502.8394 502.9591 503.0787 503.1983 503.3179 503.4375 503.5570 503.6766 503.7961 503.9156 504.0351 504.1546 504.2740 504.3935 504.5129 504.6323 504.7517 504.8711 504.9904 505.1098 505.2291 505.3484 505.4677 505.5869 505.7062 505.8254 505.9446 506.0638 506.1830 506.3021 506.4213 506.5404 506.6595 506.7786 506.8977 507.0167 507.1358 507.2548 507.3738 507.4928 507.6117 507.7307 507.8496 507.9685 508.0874 508.2063 508.3251 508.4440 508.5628 508.6816 508.8004 508.9192 509.0379 509.1566 509.2754 509.3941 509.5127 509.6314 509.7501 509.8687 509.9873 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181220T122219.0Z 6928.515498 1 1 32.01 2 89.88 121.74 115.06 320.58 0.00 1 0.00 1 0 15 6.933e-02 6.817e-02 6.330e-02 6.251e-02 4.452602e+03 3.831770e+03 3.022641e+02 -6.000000e+00 3.621543e+03 277.12 -2.00 20.00 -2.00 505.36 0.00e+00 1.774231e-03 1.689922e-03 4.830763e-05 -6.000000e+00 1.889795e-03 277.12 -2.00 20.00 -2.00 500.44 0.00e+00 1.213128e+00 1.224743e+00 3.858242e-02 -6.000000e+00 1.340918e+00 222.98 -2.00 3.51 -2.00 502.06 0.00e+00 20.446 0.157 489.00 513.00 1 9.5346e+00 9.3717e-02 3.7126e-02 -6.0000e+00 1.0247e-01 1.1330e-01 2.4119e-02 2.1901e-03 -6.0000e+00 2.6833e-02 6.7649e-06 -7.9353e-03 5.3396e-03 4.0636e-05 -6.0000e+00 6.1124e-03 3.4351e-02 -2.4868e-04 12 8 8 10 0 0 -93.64 21.92 12.26 0.03435 -0.02069 8 2 1 4 0 4000.000 26.21 20.00 21.92 900000 -4172 -5559 -8711 -1488 -6018 -6405 -256 6433 -3436 -5052 -6537 -6892 -5820 186 11374 2401 -1292 2750 4121 1547 10596 -5549 -848 548 -1395 10904 -2567 -6824 -80 1132 8057 -5963 1176 -5751 -254 8525 -8106 15220 953 -4711 -345 4826 11015 14016 469 -716 4528 2579 3618 -6923 6287 3248 3549 1224 13432 5806 9181 -9661 -2840 5514 -12661 -1245 3336 11964 8470 15334 -7914 14128 -7752 3226 2922 -5652 7041 454 -5239 -7769 -2064 -9752 9866 16152 16456 3286 -2665 2701 -3371 2093 -16318 10797 -341 -10200 2721 5638 -8060 4923 6039 11646 -4169 9549 10979 -8468 -7267 -1007 -4732 1582 5012 4259 3324 5330 -1042 7958 -1523 1410 5628 -1459 8260 2021 9602 398 4422 -5844 3828 -1999 -4062 2788 10198 566 -10661 -17578 -9 4113 6402 -7012 -6720 4096 -4226 6786 -3157 -119 3835 -9616 -3235 -1653 -3728 -7775 5279 -1794 -3744 2836 6025 2815 900000 -3998 -5491 -9149 -1514 -6575 -7172 -275 6526 -3807 -5606 -7257 -7583 -6222 185 10121 2336 -1324 2778 4222 1634 10306 -6306 -920 589 -1539 10648 -2839 -7785 -83 1122 7351 -6257 1172 -6394 -276 8542 -9412 13919 993 -5118 -362 4858 10552 13209 508 -786 4688 2687 3666 -7529 5834 3031 3271 1167 11703 5610 8775 -11170 -3062 5479 -15006 -1326 3410 11275 8132 13615 -8659 12326 -8251 3026 2730 -5757 6431 446 -5495 -8291 -2037 -10202 8390 12927 13212 3023 -2597 2513 -3381 2006 -18651 9434 -330 -10947 2585 5288 -8814 4724 5634 10129 -4118 8032 8853 -8096 -6868 -912 -4616 1515 4726 4045 3145 4856 -1003 7077 -1508 1378 5377 -1500 7741 2028 9013 411 4344 -6217 3658 -1978 -4085 2662 9100 553 -11677 -20456 -9 3880 5841 -7118 -6710 3664 -4075 6010 -3156 -117 3689 -10636 -3377 -1706 -3953 -8629 5143 -1857 -3863 2664 5386 2601 SO 20181220T122415.0Z 6928.516840 3 1 32.01 2 89.57 122.06 115.28 321.01 0.00 1 0.00 1 0 15 4.822e-02 4.712e-02 4.242e-02 4.210e-02 4.640951e+03 2.572932e+03 3.069041e+02 -6.000000e+00 2.519203e+03 277.12 -2.00 20.00 -2.00 505.39 0.00e+00 2.192805e-03 1.137510e-03 6.223443e-05 -6.000000e+00 1.314520e-03 277.12 -2.00 20.00 -2.00 500.64 0.00e+00 2.459867e+00 8.101736e-01 4.334406e-02 -6.000000e+00 9.334064e-01 222.98 -2.00 3.51 -2.00 502.22 0.00e+00 19.973 0.147 489.00 513.00 1 9.0986e+00 6.2066e-02 3.5719e-02 -6.0000e+00 7.1317e-02 5.5962e-02 1.5782e-02 2.1597e-03 -6.0000e+00 1.8692e-02 1.0180e-05 2.2616e-03 3.6031e-03 4.2376e-05 -6.0000e+00 4.2533e-03 4.6685e-02 -3.7641e-04 12 8 8 10 0 0 58.58 21.93 2.62 0.04668 0.06237 8 2 1 4 0 4000.000 26.32 20.00 21.93 900000 1503 -73 3859 -3376 -3925 1658 -3034 -4566 -1085 1476 -3669 -180 3044 6889 1820 1338 -8177 -1599 1263 2799 1631 14689 1040 11468 1211 623 3333 1075 -43 -1262 -902 -4175 121 -5286 -2330 -1601 4021 -1603 -4597 -7710 -4813 6384 8006 -2896 -2969 -4941 4292 -2526 -1200 -2092 4034 -6045 5592 -3900 8172 -2392 13744 -3216 9312 -2680 10129 -2847 10674 -2799 140 -4057 5292 5303 -1205 -3931 2057 2770 -1132 -3611 4519 2003 1916 -10460 -8417 -5781 -5197 -3269 -671 11464 -5903 4828 -5730 6747 7862 1861 4281 8655 -11571 876 2448 6232 -6939 -2045 8658 -2010 887 -1570 -1332 2286 -5016 2959 4356 -2085 2512 -226 -2398 -331 -3247 -2440 -4166 1807 1746 751 4483 -6723 2204 2685 470 5336 8341 -1962 -766 2138 3110 -4141 216 -873 1691 2395 -23 -537 -3156 -1739 3530 11042 -1615 -542 2828 -2687 1535 -1833 2939 -3387 -3809 -3953 900000 1321 -66 3535 -3441 -4084 1667 -3250 -4985 -1133 1479 -3827 -178 2875 6208 1731 1294 -8823 -1665 1305 2861 1689 13371 1081 10892 1273 658 3409 1102 -43 -1242 -884 -4287 123 -5871 -2561 -1736 4071 -1697 -4963 -8571 -5238 6289 7869 -3195 -3302 -5592 4384 -2722 -1247 -2125 3742 -6100 5027 -3921 7595 -2528 12636 -3489 8875 -2873 9609 -3076 10155 -3011 144 -4283 5046 4964 -1184 -3920 1934 2612 -1123 -3697 4297 1908 1788 -10889 -8516 -5700 -5147 -3201 -639 9845 -6069 4471 -5874 6088 7026 1763 4007 7957 -12973 864 2329 5622 -6901 -1880 7032 -1788 775 -1448 -1281 2202 -5222 2822 4032 -2029 2342 -221 -2423 -332 -3400 -2553 -4459 1839 1793 778 4410 -7234 2147 2575 461 5070 7720 -2006 -775 2097 3030 -4330 213 -854 1599 2236 -22 -533 -3295 -1817 3547 10397 -1724 -576 2929 -2951 1611 -1958 2915 -3497 -3925 -4120 SO 20181220T122607.0Z 6928.518137 5 1 32.00 2 89.27 122.37 115.49 321.42 0.00 1 0.00 1 0 15 2.755e-02 2.721e-02 2.343e-02 2.331e-02 6.234267e+03 1.443795e+03 6.714126e+02 -6.000000e+00 1.439219e+03 277.12 -2.00 20.00 -2.00 505.43 0.00e+00 6.187497e-03 6.279070e-04 3.182789e-04 -6.000000e+00 7.510028e-04 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