File name: Pandora38s1_BayonneNJ_20210618_L2Fit_fout2c6d20210317p1-8.txt File generation date: 20250227T135213.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 38 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora38_OF_v4d20201028.txt Instrument calibration file used: Pandora38s1_CF_v6d20210317.txt Level 1 file used: Pandora38s1_BayonneNJ_20210618_L1_smca1c6d20210317p1-8.txt Full location name: Bayonne NJDEP (USEPA AQS ID 34-017-0006) Short location name: BayonneNJ Country of location: USA Location latitude [deg]: 40.6703 Location longitude [deg]: -74.1261 Location altitude [m]: 3 Local noon date: 20210618 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 259 401 Nominal wavelengths inside fitting window [nm]: 305.1058 305.2465 305.3872 305.5279 305.6685 305.8092 305.9498 306.0904 306.2310 306.3716 306.5122 306.6528 306.7933 306.9339 307.0744 307.2150 307.3555 307.4960 307.6365 307.7770 307.9174 308.0579 308.1983 308.3388 308.4792 308.6196 308.7600 308.9004 309.0408 309.1812 309.3215 309.4619 309.6022 309.7425 309.8828 310.0231 310.1634 310.3037 310.4439 310.5842 310.7244 310.8647 311.0049 311.1451 311.2853 311.4255 311.5656 311.7058 311.8460 311.9861 312.1262 312.2663 312.4064 312.5465 312.6866 312.8267 312.9667 313.1068 313.2468 313.3868 313.5268 313.6668 313.8068 313.9468 314.0868 314.2267 314.3666 314.5066 314.6465 314.7864 314.9263 315.0662 315.2060 315.3459 315.4857 315.6256 315.7654 315.9052 316.0450 316.1848 316.3246 316.4643 316.6041 316.7438 316.8836 317.0233 317.1630 317.3027 317.4424 317.5820 317.7217 317.8613 318.0010 318.1406 318.2802 318.4198 318.5594 318.6990 318.8386 318.9781 319.1177 319.2572 319.3967 319.5362 319.6757 319.8152 319.9547 320.0941 320.2336 320.3730 320.5124 320.6518 320.7912 320.9306 321.0700 321.2094 321.3487 321.4881 321.6274 321.7667 321.9060 322.0453 322.1846 322.3239 322.4631 322.6024 322.7416 322.8808 323.0201 323.1593 323.2984 323.4376 323.5768 323.7159 323.8551 323.9942 324.1333 324.2724 324.4115 324.5506 324.6897 324.8287 324.9678 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210618T100642.6Z 7839.421326 91 1 48.71 2 83.96 64.16 132.79 335.19 0.00 1 0.00 1 0 25 5.628e-01 3.361e-02 4.869e-01 3.136e-02 1.031446e+00 1.951638e-02 1.127281e-02 -6.000000e+00 3.441357e-01 232.92 -2.00 3.51 -2.00 322.55 0.00e+00 -6.829336e-03 1.144402e-02 7.584420e-03 -6.000000e+00 1.681206e-02 287.15 -2.00 20.00 -2.00 322.09 0.00e+00 8.478 0.011 302.00 328.00 3 7.7279e-01 8.2570e-02 1.1070e-01 -6.0000e+00 8.6900e-01 1.6741e+00 1.0274e-01 7.8134e-02 -6.0000e+00 9.4499e-01 -2.1042e+00 6.6578e-02 3.3202e-02 -6.0000e+00 5.5807e-01 8.1004e-01 3.2678e-02 7.9533e-03 -6.0000e+00 2.3263e-01 1.6755e-05 -9.6035e-04 8.8680e-04 1.8064e-04 -6.0000e+00 1.7782e-02 6.8800e-03 2.3607e-05 12 8 8 10 0 0 85.46 21.33 0.53 0.00688 -0.00034 49 11 1 5 0 994.010 26.51 20.00 21.33 24.82 16.1 962.82 140651 -72 900000 900000 -60175 -50258 -17760 900000 -81022 32727 8851 900000 184031 -61303 85823 23923 900000 -3261 900000 -61771 -31312 900000 -20908 900000 67324 133393 -73930 900000 -83870 -36259 267942 24620 900000 -23341 82562 -35304 900000 31676 92103 93939 41566 221953 72758 900000 47733 66714 57892 77045 900000 30617 900000 40987 101423 31253 85613 151799 45095 135468 20829 67799 42299 76479 50118 32819 34218 15806 37335 31141 48336 18539 46954 43368 10384 12178 -7650 -277 -14944 172 -4926 20437 2013 -2493 8105 -5407 19160 -1428 5716 -9074 2579 4795 8374 3911 -17569 -2670 -3840 6686 3209 -12540 293 -3678 -1385 -6053 4481 -421 -4493 -2112 -1720 1999 -7784 -1775 -3779 2289 60 -27 -1407 1006 555 -3405 2940 -603 -1132 -335 1723 2524 3888 3862 1210 1882 -200 1175 2039 1488 1252 -1219 989 -1336 605 -537 -126 147 -646 1623 -3004 4290 -3 900000 900000 -3003 -2090 -542 900000 -4942 998 270 900000 5613 -4590 2618 929 900000 -172 900000 -5310 -1823 900000 -1044 900000 2053 4069 -5945 900000 -6279 -1810 8172 887 900000 -1424 2518 -2154 900000 1230 2809 2865 2075 6770 2623 900000 1985 2442 2295 2585 900000 1698 900000 2500 4022 2426 4439 4630 3576 4132 1675 3515 2838 3966 3822 3303 3549 1797 3872 3704 5455 2879 6445 6217 1785 2043 -1252 -41 -2507 27 -947 3678 469 -698 2247 -1829 5366 -515 1981 -3673 908 1569 2485 1171 -6674 -970 -1661 3115 1833 -9666 215 -2805 -960 -3928 2398 -237 -2791 -1358 -1183 1463 -7209 -1806 -4485 2786 78 -34 -1795 1239 703 -4711 3995 -858 -1563 -435 2103 2967 4387 4262 1383 2353 -300 2030 3952 3186 2912 -3150 2685 -3883 1756 -1582 -362 395 -1616 3672 -6914 SS 20210618T101712.6Z 7839.428618 94 1 48.35 2 82.15 65.77 133.58 338.46 0.00 1 0.00 1 0 17 5.799e-01 1.625e-02 3.968e-01 8.373e-03 9.033363e-01 5.037839e-03 9.747443e-03 -6.000000e+00 3.534049e-01 232.92 -2.00 3.51 -2.00 322.35 0.00e+00 5.818683e-03 3.389036e-03 1.464435e-03 -6.000000e+00 1.619452e-02 287.15 -2.00 20.00 -2.00 321.87 0.00e+00 6.824 0.006 302.00 328.00 3 7.5027e-01 2.2449e-02 8.6902e-02 -6.0000e+00 8.8941e-01 6.1038e-01 3.3068e-02 5.9135e-02 -6.0000e+00 9.6507e-01 -8.6672e-01 3.1616e-02 2.7754e-02 -6.0000e+00 5.7086e-01 3.5335e-01 1.3865e-02 1.1463e-02 -6.0000e+00 2.3571e-01 1.1107e-04 -1.0454e-03 2.4327e-04 1.6509e-04 -6.0000e+00 1.7438e-02 5.7004e-03 3.5569e-05 12 8 8 10 0 0 -20.81 21.32 0.33 0.00570 -0.00216 158 36 1 5 0 305.990 26.51 20.00 21.32 25.71 16.0 967.24 -279450 900000 -147688 -86050 900000 -201564 900000 -286536 -98416 -185605 -86069 -144268 -68457 -12580 -132269 900000 -70095 900000 -71309 900000 38770 52789 5017 -29773 135459 -66632 14939 -75059 38696 82354 -42314 123704 -58027 35409 -53887 51846 97 17159 104813 -16926 46081 -8427 55839 10287 37520 24943 26461 39428 2635 31611 -6799 41520 21683 36015 17350 13971 37316 1027 21995 -3523 27379 19745 19574 31682 11089 28708 9107 17088 4496 14643 8691 5801 10634 955 13213 -1313 3736 -7894 5062 2659 1984 3893 -1181 -145 -3145 1868 887 1510 4006 -846 986 -3498 1244 -2698 -799 -2366 355 -1199 -1895 -1358 -1901 -1481 -2692 -152 -1496 -2070 -2001 -2393 -282 -1945 -159 -1155 70 51 -1258 -2 164 795 -344 558 546 1208 1741 521 1901 224 2745 -210 490 589 298 726 41 86 -438 500 -133 274 -134 -273 99 -780 -880 -6838 900000 -1205 -702 900000 -2092 900000 -7861 -803 -2064 -702 -1391 -558 -103 -2452 900000 -1029 900000 -1221 900000 316 431 41 -364 1105 -1250 122 -1469 316 672 -897 1009 -1988 491 -1758 592 2 364 1111 -704 1128 -378 1366 403 1132 875 950 1318 138 1366 -488 2066 1450 2262 1387 1196 2557 99 1650 -336 2010 1755 2012 3256 1483 3255 1292 2411 814 2475 1688 1187 2203 201 2209 -230 606 -1552 1028 670 543 1201 -422 -55 -1306 780 390 672 1717 -364 392 -1395 477 -1174 -398 -1424 246 -971 -1673 -1190 -1562 -1087 -1842 -102 -1078 -1592 -1646 -2167 -283 -2283 -207 -1629 100 72 -1731 -3 223 1129 -519 848 807 1689 2326 681 2374 277 3304 -283 757 1047 594 1567 95 216 -1181 1397 -382 788 -380 -737 246 -1835 -2018 SS 20210618T102713.9Z 7839.435578 97 1 47.63 2 80.41 67.29 134.24 341.65 0.00 1 0.00 1 0 17 6.357e-01 5.811e-03 2.746e-01 3.592e-03 7.935153e-01 2.056235e-03 8.645867e-03 -6.000000e+00 3.801505e-01 232.92 -2.00 3.51 -2.00 321.91 0.00e+00 3.112947e-03 1.256994e-03 1.273386e-03 -6.000000e+00 1.686851e-02 287.15 -2.00 20.00 -2.00 321.37 0.00e+00 5.719 0.003 302.00 328.00 3 6.6442e-01 8.3381e-03 7.2419e-02 -6.0000e+00 9.5413e-01 1.1608e-01 1.2740e-02 4.5796e-02 -6.0000e+00 1.0315e+00 -1.5751e-01 1.3174e-02 2.4590e-02 -6.0000e+00 6.1371e-01 5.6311e-02 5.8562e-03 8.8318e-03 -6.0000e+00 2.5557e-01 4.0693e-04 -3.3994e-04 1.0388e-04 1.2438e-04 -6.0000e+00 1.8786e-02 5.0364e-03 2.3254e-05 10 0 0 10 0 0 10.24 21.33 0.26 0.00504 0.00248 325 74 1 5 0 146.530 26.51 20.00 21.33 26.38 16.1 971.90 -219307 -244494 -168984 -191537 -212084 -241152 -50587 -190446 -232185 -199374 -157222 -185614 -100084 -79084 -94819 -70581 -102902 -57754 -61216 -24026 -44495 -79133 6825 -39021 -68655 -32055 -64358 -62205 -66487 -51427 -22668 -13884 -11512 -10149 -11195 -20850 -20900 -980 -5702 -10654 369 -3809 -753 -4148 670 -4536 -2596 6860 4334 -2319 5799 3775 3251 9088 3435 1688 3013 -53 3102 2736 963 3329 4201 5877 1645 2132 4112 802 3663 3215 2712 1587 422 332 -674 -654 -1185 -102 -72 -105 381 -200 -1122 -1185 -363 4 -172 162 770 506 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