File name: Pandora80s1_BeltsvilleMD_20221003_L2Fit_fwvt1c8d20220601p1-8.txt File generation date: 20241115T015308.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: John Sullivan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 80 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora80_OF_v4d20220517.txt Instrument calibration file used: Pandora80s1_CF_v8d20220601.txt Level 1 file used: Pandora80s1_BeltsvilleMD_20221003_L1_smca1c8d20220601p1-8.txt Full location name: Howard University-Beltsville Campus, Beltsville, MD Short location name: BeltsvilleMD Country of location: United States Location latitude [deg]: 39.0567 Location longitude [deg]: -76.8758 Location altitude [m]: 70 Local noon date: 20221003 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1614 1763 Nominal wavelengths inside fitting window [nm]: 492.1005 492.2218 492.3431 492.4643 492.5855 492.7068 492.8280 492.9491 493.0703 493.1915 493.3126 493.4337 493.5548 493.6759 493.7970 493.9180 494.0390 494.1601 494.2811 494.4020 494.5230 494.6440 494.7649 494.8858 495.0067 495.1276 495.2485 495.3693 495.4901 495.6109 495.7317 495.8525 495.9733 496.0940 496.2148 496.3355 496.4562 496.5768 496.6975 496.8182 496.9388 497.0594 497.1800 497.3006 497.4211 497.5417 497.6622 497.7827 497.9032 498.0237 498.1441 498.2646 498.3850 498.5054 498.6258 498.7462 498.8665 498.9869 499.1072 499.2275 499.3478 499.4681 499.5883 499.7085 499.8288 499.9490 500.0692 500.1893 500.3095 500.4296 500.5497 500.6698 500.7899 500.9100 501.0300 501.1501 501.2701 501.3901 501.5101 501.6300 501.7500 501.8699 501.9898 502.1097 502.2296 502.3495 502.4693 502.5892 502.7090 502.8288 502.9485 503.0683 503.1880 503.3078 503.4275 503.5472 503.6668 503.7865 503.9061 504.0258 504.1454 504.2650 504.3845 504.5041 504.6236 504.7431 504.8627 504.9821 505.1016 505.2211 505.3405 505.4599 505.5793 505.6987 505.8181 505.9374 506.0567 506.1761 506.2954 506.4146 506.5339 506.6531 506.7724 506.8916 507.0108 507.1300 507.2491 507.3683 507.4874 507.6065 507.7256 507.8447 507.9637 508.0828 508.2018 508.3208 508.4398 508.5587 508.6777 508.7966 508.9155 509.0344 509.1533 509.2722 509.3910 509.5099 509.6287 509.7475 509.8663 509.9850 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221003T155858.1Z 8311.665950 203 1 46.72 2 45.18 159.56 126.95 97.17 0.00 1 0.00 1 0 15 3.169e-03 3.143e-03 6.279e-04 6.260e-04 2.047908e+03 3.628541e+01 1.425731e+02 -6.000000e+00 1.714248e+02 286.70 -2.00 20.00 -2.00 505.26 0.00e+00 4.124384e-04 1.705290e-05 2.359959e-05 -6.000000e+00 8.836598e-05 286.70 -2.00 20.00 -2.00 500.42 0.00e+00 4.087729e-02 1.205236e-02 1.544977e-02 -6.000000e+00 6.118173e-02 227.42 -2.00 3.47 -2.00 502.02 0.00e+00 1.417 0.000 489.00 513.00 1 6.8195e+00 9.2315e-04 2.4603e-03 -6.0000e+00 4.6895e-03 1.3156e-02 2.4101e-04 3.7139e-04 -6.0000e+00 1.2255e-03 1.7326e-03 7.9177e-04 5.2795e-05 1.7478e-05 -6.0000e+00 2.7353e-04 -3.1374e-03 2.7761e-05 12 1 1 12 1 1 99.19 24.14 1.66 -0.00314 0.00235 34 6 1 4 0 1329.920 26.62 20.01 24.14 20.91 3.5 920.39 -938 -641 -259 14 215 194 447 449 239 42 -22 -164 -284 -467 -306 -265 -12 103 -8 349 168 105 329 233 315 438 413 -165 -159 -508 -527 -369 -82 119 189 316 -64 -201 -268 -282 -39 283 282 615 589 568 471 457 85 -159 -527 -713 -598 -437 -191 -52 113 184 176 -112 285 202 480 218 76 110 -144 -246 -330 -367 -469 -158 84 -51 62 -6 -76 -358 -434 -333 -298 -274 -202 -163 2 84 7 -200 -12 -65 246 312 369 444 235 235 -116 -412 -486 -619 -426 -257 -169 97 32 -107 -236 -352 -284 -195 -6 164 344 476 486 534 475 355 249 6 165 190 19 159 232 205 309 304 213 -33 67 -229 -447 -347 -310 -160 53 51 -21 14 228 31 352 194 246 -176 -239 -486 -561 -445 -906 -632 -265 14 223 204 479 483 256 45 -23 -168 -286 -465 -304 -266 -12 108 -8 376 181 113 354 253 329 455 444 -175 -162 -504 -520 -368 -83 126 198 329 -66 -213 -279 -293 -41 296 299 632 609 586 481 478 87 -159 -510 -678 -590 -422 -191 -53 118 192 183 -116 296 203 483 218 79 112 -144 -244 -321 -353 -452 -153 82 -51 62 -5 -73 -340 -409 -314 -284 -264 -195 -160 2 84 7 -198 -12 -65 248 308 369 440 229 234 -113 -391 -449 -568 -394 -244 -167 96 32 -105 -228 -348 -280 -188 -6 162 345 479 491 542 484 361 249 6 160 182 18 154 224 198 299 292 205 -32 64 -221 -426 -329 -295 -150 51 50 -21 14 226 31 353 195 246 -174 -229 -455 -521 -416 SQ 20221003T160338.6Z 8311.669197 206 1 51.40 2 44.88 161.15 126.09 97.79 0.00 1 0.00 1 0 15 3.639e-03 3.606e-03 9.452e-04 9.418e-04 2.272366e+03 5.501502e+01 1.517710e+02 -6.000000e+00 1.968384e+02 286.70 -2.00 20.00 -2.00 505.25 0.00e+00 4.517075e-04 2.569564e-05 2.638683e-05 -6.000000e+00 1.014684e-04 286.70 -2.00 20.00 -2.00 500.37 0.00e+00 7.370544e-02 1.821008e-02 1.825660e-02 -6.000000e+00 7.024849e-02 227.42 -2.00 3.47 -2.00 501.97 0.00e+00 1.409 0.000 489.00 513.00 1 7.5797e+00 1.3969e-03 2.5884e-03 -6.0000e+00 5.3845e-03 9.7792e-03 3.6362e-04 4.2096e-04 -6.0000e+00 1.4070e-03 8.0820e-04 7.4434e-04 7.9483e-05 1.8120e-05 -6.0000e+00 3.1408e-04 -3.4641e-03 3.4100e-05 10 0 0 10 0 0 98.63 24.15 1.60 -0.00346 0.00170 26 4 1 4 0 1976.880 26.62 20.01 24.15 21.18 3.5 922.54 -1017 -622 -520 62 125 343 359 490 141 18 -163 -255 -135 -457 -151 -228 -64 128 136 395 162 10 364 268 358 319 543 -355 -252 -567 -654 -453 9 79 414 361 53 -152 -255 -147 96 342 445 699 531 375 614 477 86 -377 -668 -847 -721 -390 -225 -44 46 116 300 27 241 220 614 150 350 137 -169 -74 -307 -334 -441 -90 -22 -285 -27 -6 -260 -325 -444 -494 -391 -517 -158 58 49 -24 -57 -101 38 -200 -10 285 412 313 353 206 50 -626 -664 -502 -318 -631 -234 225 133 -118 -199 -479 -337 -113 -64 263 418 517 617 761 517 406 133 115 453 162 39 45 284 353 310 344 351 15 -13 -119 -411 -319 -441 -348 65 74 12 159 343 164 244 122 -11 -37 -341 -714 -469 -783 -995 -621 -513 63 129 361 386 529 151 19 -170 -263 -136 -456 -150 -229 -65 135 146 426 175 11 392 291 389 346 584 -378 -258 -565 -648 -453 9 84 430 373 57 -161 -267 -152 100 359 472 748 547 385 654 501 89 -378 -651 -810 -686 -378 -225 -45 48 122 313 29 252 220 613 150 361 139 -170 -73 -300 -322 -426 -88 -22 -286 -27 -6 -251 -311 -421 -469 -376 -501 -153 56 49 -24 -57 -101 38 -201 -9 280 409 308 341 206 49 -597 -617 -462 -295 -603 -221 220 131 -115 -191 -453 -318 -108 -63 260 416 518 619 767 525 411 132 113 435 154 37 43 274 340 299 329 337 14 -13 -110 -376 -304 -403 -327 62 72 12 157 339 163 244 122 -11 -36 -326 -669 -434 -734 SQ 20221003T160840.6Z 8311.672693 209 1 51.67 2 44.58 162.88 125.17 98.45 0.00 1 0.00 1 0 15 3.478e-03 3.455e-03 8.990e-04 8.968e-04 2.166045e+03 5.222901e+01 1.514299e+02 -6.000000e+00 1.881263e+02 286.70 -2.00 20.00 -2.00 505.28 0.00e+00 4.491392e-04 2.456081e-05 2.437187e-05 -6.000000e+00 9.697646e-05 286.70 -2.00 20.00 -2.00 500.45 0.00e+00 7.136543e-02 1.727759e-02 1.643659e-02 -6.000000e+00 6.714093e-02 227.42 -2.00 3.47 -2.00 502.05 0.00e+00 1.402 0.000 489.00 513.00 1 7.4922e+00 1.3258e-03 2.4935e-03 -6.0000e+00 5.1463e-03 1.0050e-02 3.4375e-04 3.9415e-04 -6.0000e+00 1.3448e-03 8.8335e-04 8.6297e-04 7.5341e-05 1.7898e-05 -6.0000e+00 3.0018e-04 -3.3764e-03 3.1511e-05 12 1 1 12 1 1 99.57 24.16 1.59 -0.00338 0.00261 20 3 1 4 0 2459.940 26.62 20.01 24.16 21.48 3.5 925.20 -1010 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