File name: Pandora80s1_BeltsvilleMD_20230912_L2Fit_fout2c8d20220601p1-8.txt File generation date: 20230914T115212.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: John Sullivan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 80 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora80_OF_v4d20220517.txt Instrument calibration file used: Pandora80s1_CF_v8d20220601.txt Level 1 file used: Pandora80s1_BeltsvilleMD_20230912_L1_smca1c8d20220601p1-8.txt Full location name: Howard University-Beltsville Campus, Beltsville, MD Short location name: BeltsvilleMD Country of location: United States Location latitude [deg]: 39.0567 Location longitude [deg]: -76.8758 Location altitude [m]: 70 Local noon date: 20230912 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 337 Nominal wavelengths inside fitting window [nm]: 305.1296 305.2706 305.4117 305.5527 305.6937 305.8347 305.9757 306.1167 306.2576 306.3986 306.5396 306.6805 306.8214 306.9623 307.1032 307.2441 307.3850 307.5259 307.6667 307.8076 307.9484 308.0893 308.2301 308.3709 308.5117 308.6524 308.7932 308.9340 309.0747 309.2155 309.3562 309.4969 309.6376 309.7783 309.9190 310.0596 310.2003 310.3409 310.4816 310.6222 310.7628 310.9034 311.0440 311.1846 311.3252 311.4657 311.6063 311.7468 311.8873 312.0278 312.1683 312.3088 312.4493 312.5898 312.7302 312.8707 313.0111 313.1515 313.2919 313.4323 313.5727 313.7131 313.8535 313.9938 314.1342 314.2745 314.4148 314.5551 314.6954 314.8357 314.9760 315.1162 315.2565 315.3967 315.5370 315.6772 315.8174 315.9576 316.0978 316.2380 316.3781 316.5183 316.6584 316.7985 316.9386 317.0788 317.2188 317.3589 317.4990 317.6391 317.7791 317.9191 318.0592 318.1992 318.3392 318.4792 318.6192 318.7591 318.8991 319.0390 319.1790 319.3189 319.4588 319.5987 319.7386 319.8785 320.0183 320.1582 320.2980 320.4378 320.5777 320.7175 320.8573 320.9971 321.1368 321.2766 321.4163 321.5561 321.6958 321.8355 321.9752 322.1149 322.2546 322.3943 322.5339 322.6736 322.8132 322.9528 323.0925 323.2321 323.3716 323.5112 323.6508 323.7903 323.9299 324.0694 324.2089 324.3485 324.4880 324.6274 324.7669 324.9064 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230912T121820.8Z 8655.512741 154 1 52.09 2 72.97 98.68 45.64 103.18 0.00 1 0.00 1 0 17 6.061e-02 6.471e-03 1.609e-02 1.177e-03 4.134770e-01 6.012603e-04 4.871107e-03 -6.000000e+00 3.432089e-02 229.51 -2.00 3.47 -2.00 319.57 0.00e+00 1.200854e-03 1.696608e-04 1.065007e-03 -6.000000e+00 1.540700e-03 289.04 -2.00 20.00 -2.00 318.78 0.00e+00 3.363 0.001 302.00 328.00 3 2.2922e+00 1.7291e-03 3.9862e-02 -6.0000e+00 8.5527e-02 -5.4737e-03 2.0510e-03 2.2202e-02 -6.0000e+00 9.2501e-02 -1.5352e-02 1.6030e-03 1.0934e-02 -6.0000e+00 5.5194e-02 7.9260e-04 8.4378e-04 3.0647e-03 -6.0000e+00 2.3990e-02 1.1920e-03 -4.2651e-05 3.2715e-05 3.2852e-05 -6.0000e+00 1.5344e-03 -1.5641e-02 7.3331e-05 11 8 0 10 0 0 99.02 24.48 0.51 -0.01564 -0.01596 168 25 1 5 0 310.020 26.94 20.00 24.48 29.94 4.6 1000.60 -24842 -9584 -15812 -20083 -29472 -23456 -20556 -8873 -12856 -14618 -16344 -19814 -10103 -14034 -3226 -5593 -2732 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994 811 476 -205 -472 -359 -352 -268 610 892 119 -505 -1441 -1923 -1323 -851 -1422 -1063 -927 -448 558 967 988 851 659 130 -398 -131 -83 325 533 401 489 941 880 397 636 -491 181 408 -78 253 -483 -423 -900 -159 175 -135 1046 639 -28 -326 -698 -948 SS 20230912T122455.3Z 8655.517307 158 1 52.23 2 71.71 99.78 44.43 104.51 0.00 1 0.00 1 0 17 4.256e-02 6.443e-03 5.280e-03 4.994e-04 3.881275e-01 2.546313e-04 4.595343e-03 -6.000000e+00 2.409978e-02 229.51 -2.00 3.47 -2.00 319.25 0.00e+00 9.706141e-04 6.478228e-05 8.637068e-04 -6.000000e+00 1.081891e-03 289.04 -2.00 20.00 -2.00 318.45 0.00e+00 3.145 0.000 302.00 328.00 3 9.2531e-01 7.1176e-04 3.7248e-02 -6.0000e+00 6.0056e-02 -1.0869e-02 8.3224e-04 2.0583e-02 -6.0000e+00 6.4954e-02 -6.3778e-03 6.2311e-04 1.0113e-02 -6.0000e+00 3.8757e-02 -2.8654e-03 3.3117e-04 2.8402e-03 -6.0000e+00 1.6845e-02 5.9414e-03 -1.3380e-04 1.3951e-05 2.9602e-05 -6.0000e+00 1.0776e-03 -1.5914e-02 5.3342e-05 11 8 0 10 0 0 10.64 24.51 0.57 -0.01591 -0.01692 792 119 1 5 0 65.860 26.94 20.00 24.51 30.47 4.6 1004.41 -11418 -12473 -10605 -14629 -17822 -15555 -17539 -10444 -11175 -11747 -14679 -9869 -7275 -4529 -1674 -3283 -279 -2255 -271 -108 -1488 -1285 -788 -284 -1501 -203 -2920 -2431 -4189 -1457 -1010 228 536 -3457 -4668 -5281 -3256 -1824 -259 82 -491 -88 -352 400 274 281 -185 -185 -505 290 1434 753 1624 1000 1170 1154 583 410 106 545 1025 1946 2539 2282 287 235 -741 -321 1051 917 1093 563 780 375 -393 -946 -2034 -1775 -1377 -1369 -1247 -1646 -1924 -1116 -552 46 481 887 957 588 707 -288 -475 -303 -241 -74 599 677 -40 -339 -1112 -1420 -1158 -588 -1199 -866 -734 -387 437 624 775 553 426 -20 -210 20 -81 247 297 139 288 555 543 380 410 -382 279 267 47 115 -235 -339 -522 -133 38 -77 464 380 -24 -138 -358 -518 -288 -349 -298 -429 -485 -421 -537 -341 -412 -453 -581 -413 -357 -258 -110 -243 -21 -188 -23 -10 -137 -117 -76 -30 -167 -23 -340 -262 -442 -159 -124 31 81 -540 -678 -800 -552 -366 -63 23 -149 -28 -115 131 90 93 -61 -61 -169 101 541 309 708 467 512 520 269 186 52 267 481 999 1435 1386 172 131 -402 -177 646 645 823 437 589 268 -257 -556 -1128 -990 -863 -993 -1022 -1500 -1853 -1034 -550 48 529 990 1054 611 673 -279 -434 -286 -233 -80 731 919 -51 -456 -1391 -1617 -1275 -698 -1545 -1161 -1037 -532 641 995 1303 931 685 -30 -292 27 -112 365 471 230 468 878 834 556 573 -555 391 370 73 189 -410 -608 -901 -242 74 -156 950 796 -50 -272 -679 -945 SS 20230912T123052.3Z 8655.521439 161 1 52.27 2 70.58 100.79 43.35 105.75 0.00 1 0.00 1 0 17 3.502e-02 6.543e-03 4.004e-03 4.663e-04 3.682779e-01 2.362299e-04 4.368204e-03 -6.000000e+00 1.983108e-02 229.51 -2.00 3.47 -2.00 318.98 0.00e+00 9.217556e-04 5.537321e-05 7.435336e-04 -6.000000e+00 8.902437e-04 289.04 -2.00 20.00 -2.00 318.16 0.00e+00 2.972 0.000 302.00 328.00 3 1.0126e+00 6.5590e-04 3.5222e-02 -6.0000e+00 4.9419e-02 -9.1683e-03 7.5943e-04 1.9433e-02 -6.0000e+00 5.3448e-02 -6.9101e-03 5.4308e-04 9.5061e-03 -6.0000e+00 3.1892e-02 -2.2359e-03 2.8798e-04 2.6485e-03 -6.0000e+00 1.3862e-02 6.5817e-03 -9.5670e-05 1.2874e-05 2.6729e-05 -6.0000e+00 8.8665e-04 -1.6068e-02 5.5289e-05 11 8 0 10 0 0 28.58 24.53 0.54 -0.01607 -0.01679 783 118 1 5 0 66.580 26.94 20.01 24.53 31.12 4.6 1011.23 -7725 -8506 -6383 -13182 -16271 -14933 -10682 -9459 -9881 -8304 -12163 -8638 -6563 -3685 -2449 -1756 -660 -1207 14 542 -1018 -435 -863 -452 -992 -420 -1917 -3173 -3132 -1174 -919 526 800 -3039 -4270 -4637 -3119 -1587 59 -13 -290 -319 83 194 481 267 49 -202 -537 329 1202 884 1429 1228 1001 1095 796 582 280 511 1201 1788 2528 2030 223 189 -864 -400 899 787 1085 589 618 379 -482 -990 -2089 -1905 -1337 -1495 -1180 -1659 -1998 -1236 -604 -10 401 925 894 648 556 -312 -513 -367 -164 -37 612 669 -3 -337 -1041 -1505 -1153 -578 -1259 -773 -746 -330 339 584 773 633 478 -11 -237 -49 -3 250 343 155 300 582 521 337 369 -325 240 344 36 169 -211 -348 -477 -165 123 -111 402 350 -19 -105 -375 -531 -240 -320 -240 -481 -550 -505 -383 -383 -449 -386 -582 -440 -391 -253 -196 -154 -61 -119 1 58 -111 -47 -99 -56 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