File name: Pandora132s1_Berlin_20220609_L2Fit_fout2c13d20210422p1-8.txt File generation date: 20241123T172437.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Thomas Ruhtz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 132 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora132_OF_v1d20200910.txt Instrument calibration file used: Pandora132s1_CF_v13d20210422.txt Level 1 file used: Pandora132s1_Berlin_20220609_L1_smca1c13d20210422p1-8.txt Full location name: Institute of Space Sciences FU Berlin Short location name: Berlin Country of location: Germany Location latitude [deg]: 52.4600 Location longitude [deg]: 13.3100 Location altitude [m]: 100 Local noon date: 20220609 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 11, but different RefDay (April 2021). First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.1071 305.2480 305.3889 305.5298 305.6707 305.8116 305.9524 306.0932 306.2341 306.3749 306.5157 306.6565 306.7973 306.9380 307.0788 307.2195 307.3603 307.5010 307.6417 307.7824 307.9231 308.0638 308.2044 308.3451 308.4857 308.6264 308.7670 308.9076 309.0482 309.1888 309.3293 309.4699 309.6104 309.7510 309.8915 310.0320 310.1725 310.3130 310.4534 310.5939 310.7344 310.8748 311.0152 311.1556 311.2960 311.4364 311.5768 311.7172 311.8575 311.9979 312.1382 312.2785 312.4188 312.5591 312.6994 312.8397 312.9800 313.1202 313.2604 313.4007 313.5409 313.6811 313.8213 313.9615 314.1016 314.2418 314.3819 314.5221 314.6622 314.8023 314.9424 315.0825 315.2225 315.3626 315.5026 315.6427 315.7827 315.9227 316.0627 316.2027 316.3427 316.4827 316.6226 316.7626 316.9025 317.0424 317.1823 317.3222 317.4621 317.6020 317.7418 317.8817 318.0215 318.1613 318.3012 318.4410 318.5807 318.7205 318.8603 319.0000 319.1398 319.2795 319.4192 319.5589 319.6986 319.8383 319.9780 320.1177 320.2573 320.3969 320.5366 320.6762 320.8158 320.9554 321.0949 321.2345 321.3741 321.5136 321.6531 321.7927 321.9322 322.0717 322.2111 322.3506 322.4901 322.6295 322.7689 322.9084 323.0478 323.1872 323.3266 323.4659 323.6053 323.7447 323.8840 324.0233 324.1627 324.3020 324.4413 324.5805 324.7198 324.8591 324.9983 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220609T035032.7Z 8195.160100 144 1 49.94 2 82.68 61.49 118.31 314.44 0.00 1 0.00 1 0 25 6.531e-01 3.929e-02 5.017e-01 2.903e-02 9.049033e-01 1.777433e-02 1.072822e-02 -6.000000e+00 3.919841e-01 233.02 -2.00 3.85 -2.00 322.13 0.00e+00 -1.428349e-02 9.065704e-03 6.434445e-03 -6.000000e+00 1.901577e-02 279.18 -2.00 20.00 -2.00 321.68 0.00e+00 7.247 0.008 302.00 328.00 3 1.9485e+00 6.6300e-02 1.0263e-01 -6.0000e+00 9.9284e-01 1.1072e+00 8.4327e-02 8.9890e-02 -6.0000e+00 1.0758e+00 -1.5645e+00 6.6177e-02 3.2151e-02 -6.0000e+00 6.3171e-01 6.4093e-01 3.1713e-02 1.4672e-02 -6.0000e+00 2.6935e-01 2.3715e-05 9.2764e-05 8.5410e-04 1.4247e-04 -6.0000e+00 1.8571e-02 5.7043e-03 0.0000e+00 12 8 8 10 0 0 42.28 17.14 0.66 0.00570 0.00640 37 8 4 8 0 1348.970 14.98 17.14 23.75 21.38 21.88 26.5 1006.45 -43943 900000 -31773 900000 -36173 71870 13222 -131512 900000 -109677 900000 46331 76677 -44116 -15924 158196 40616 900000 51176 267414 -67956 900000 46575 139697 45994 7897 900000 -55377 -28923 -107073 273428 3044 900000 83586 88724 87789 73878 174426 -265 208892 29167 136673 39962 91237 134322 49699 142966 6420 165376 -18306 900000 69920 19126 150593 52914 101397 6700 79460 22896 83529 10517 35331 25254 46552 39386 19116 31048 8881 32228 10480 40109 32349 25944 5908 -2767 21356 -12308 9414 -17768 10909 2537 2680 3413 -8228 1508 -9012 553 -7911 11281 3186 3191 2847 -7156 3869 -10768 -615 -8855 -2104 -4653 -1815 -810 -7379 -2288 -2747 -349 -5355 4574 -4983 3187 -3142 -564 3998 -2912 2513 -3234 1473 -2491 2512 470 -1835 4212 862 7566 -1260 2050 -1287 2773 1320 -723 2708 -961 1123 -1204 2155 -1850 1718 -269 -249 1794 -1194 -237 -3246 900000 -1552 900000 -980 900000 -1022 2031 374 -9798 900000 -7326 900000 1309 2167 -2153 -655 4470 1148 900000 1446 7557 -4714 900000 1316 3948 1300 325 900000 -3414 -1263 -10728 7727 133 900000 2362 2507 2481 2088 4929 -19 5903 1948 3862 2597 3352 3796 2528 4040 508 4673 -2121 900000 4149 2054 4681 4635 5731 984 5389 2523 4721 1248 3594 3212 5262 4897 2863 4211 1631 5373 2458 7481 6582 5352 1352 -610 3319 -2609 1729 -5021 2775 824 902 1245 -3593 635 -4445 257 -4024 4608 1334 1380 1191 -3070 1815 -6224 -379 -6915 -1746 -4220 -1567 -632 -5478 -1522 -1906 -253 -4333 3584 -4724 3185 -3858 -757 5443 -4301 3435 -4520 1937 -3514 3556 713 -2861 5952 1195 9486 -1680 2564 -1610 3362 1807 -1181 4897 -1990 2449 -2888 5398 -5153 4784 -776 -716 4926 -3164 -572 -7522 900000 SS 20220609T035853.1Z 8195.165892 148 1 47.62 2 81.56 63.06 119.20 316.49 0.00 1 0.00 1 0 17 5.187e-01 1.977e-02 4.397e-01 1.618e-02 8.211396e-01 9.673023e-03 1.004755e-02 -6.000000e+00 3.092764e-01 233.02 -2.00 3.85 -2.00 321.99 0.00e+00 7.364139e-03 5.148769e-03 1.940687e-03 -6.000000e+00 1.418283e-02 279.18 -2.00 20.00 -2.00 321.54 0.00e+00 6.406 0.006 302.00 328.00 3 2.0985e+00 3.5955e-02 8.1594e-02 -6.0000e+00 7.8325e-01 5.7636e-01 4.9166e-02 5.2363e-02 -6.0000e+00 8.4730e-01 -8.0006e-01 4.8233e-02 2.8694e-02 -6.0000e+00 4.9675e-01 3.2957e-01 2.2548e-02 1.2157e-02 -6.0000e+00 2.1130e-01 4.9236e-05 -5.0946e-04 4.7586e-04 1.8070e-04 -6.0000e+00 1.4542e-02 6.0750e-03 0.0000e+00 12 9 9 12 1 1 96.93 17.13 0.51 0.00608 0.00225 43 10 4 8 0 1078.210 15.00 17.13 24.33 21.38 21.88 26.4 1008.78 -145088 -53603 -213916 900000 -206394 60454 -154639 72632 900000 900000 -122896 -57303 21356 -146242 180437 -23377 207080 -61777 12200 -34820 -75177 900000 900000 -24240 8031 33880 -44808 -71452 -13617 -102631 54725 -1883 900000 45877 11199 127709 -40540 -8362 -35839 109503 -33142 37708 8526 31356 47472 -11093 53312 16575 50113 -19773 27176 6076 8615 6853 24555 30677 9058 11578 3498 9442 -4249 39703 9198 13364 18975 17745 12430 10761 9959 502 14201 20040 7581 9834 -5333 -674 -1421 1469 -8018 -2100 -3346 -773 -3335 764 120 -106 1936 -1882 1703 2694 4174 -3573 -2216 -2888 -3127 421 -2738 796 -1831 -232 -1533 -1476 128 -5216 -1552 -4073 1141 -3886 1520 -706 142 6 -744 -190 -1087 1006 -1687 531 1046 372 586 609 2675 495 1148 513 733 1465 1233 320 -156 502 -268 1158 -945 -381 147 684 -187 151 136 -2165 900000 -2286 -845 -6129 900000 -4435 953 -2437 1145 900000 900000 -1937 -903 337 -4399 2843 -368 3263 -1416 192 -648 -2046 900000 900000 -458 127 534 -1059 -2139 -236 -5013 862 -50 900000 868 282 2012 -1916 -343 -2315 1898 -2611 1545 484 1433 1870 -804 2100 993 2290 -1994 1927 594 896 777 2438 2949 1085 1314 413 1041 -569 3879 1406 2190 3050 2852 2135 2018 2150 123 3580 4832 1983 2309 -1303 -142 -296 322 -2287 -682 -1174 -300 -1443 337 57 -53 993 -1016 871 1296 1854 -1633 -1003 -1444 -1832 282 -2220 710 -1791 -219 -1339 -1146 92 -4080 -1254 -3571 1013 -3969 1668 -905 200 9 -1117 -275 -1521 1357 -2412 784 1619 586 891 881 3656 671 1495 649 928 2031 1989 593 -320 1090 -625 2864 -2545 -1058 412 1916 -518 393 327 -5005 900000 SS 20220609T041704.4Z 8195.178523 153 1 49.98 2 79.05 66.46 121.03 321.09 0.00 1 0.00 1 0 17 4.991e-01 1.033e-02 2.134e-01 4.026e-03 6.938674e-01 2.285267e-03 8.641722e-03 -6.000000e+00 2.952873e-01 233.02 -2.00 3.85 -2.00 321.48 0.00e+00 5.061239e-03 1.118881e-03 2.194207e-03 -6.000000e+00 1.260543e-02 279.18 -2.00 20.00 -2.00 320.99 0.00e+00 5.072 0.003 302.00 328.00 3 1.3937e+00 7.8868e-03 6.6138e-02 -6.0000e+00 7.4407e-01 1.2194e-01 1.1105e-02 4.3858e-02 -6.0000e+00 8.0261e-01 -1.7340e-01 1.1632e-02 2.5099e-02 -6.0000e+00 4.7477e-01 6.9204e-02 5.4785e-03 9.6783e-03 -6.0000e+00 2.0346e-01 4.1703e-04 -2.7511e-04 1.1757e-04 1.3042e-04 -6.0000e+00 1.3766e-02 5.0165e-03 0.0000e+00 12 8 8 10 0 0 30.27 17.13 0.26 0.00502 0.00295 212 45 4 8 0 233.480 14.99 17.13 25.00 21.38 21.88 26.2 1011.12 900000 -210376 -87165 -199137 -54109 -201857 -191745 -134776 -188887 -82991 -164076 69048 -154014 -8291 -90411 -37155 10952 -42819 15941 -73853 -38134 -104136 -26631 -53751 -17944 -20502 -47696 -13316 -64586 8201 -31602 26490 -22720 -6801 -16215 -16867 15277 -12348 13543 -1589 13216 -5363 8963 7662 10123 10067 816 18396 888 13385 439 10473 7164 5374 7991 4098 7689 -321 6139 -1246 6214 4349 3625 8141 4421 6492 635 4480 1973 3490 1379 1245 2559 1689 1606 -1526 1594 -3025 1212 -452 -205 -1097 -3084 -680 -2675 233 -652 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