File name: Pandora132s1_Berlin_20220819_L2Fit_fout2c13d20210422p1-8.txt File generation date: 20241123T181119.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Thomas Ruhtz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 132 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora132_OF_v1d20200910.txt Instrument calibration file used: Pandora132s1_CF_v13d20210422.txt Level 1 file used: Pandora132s1_Berlin_20220819_L1_smca1c13d20210422p1-8.txt Full location name: Institute of Space Sciences FU Berlin Short location name: Berlin Country of location: Germany Location latitude [deg]: 52.4600 Location longitude [deg]: 13.3100 Location altitude [m]: 100 Local noon date: 20220819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 11, but different RefDay (April 2021). First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.1071 305.2480 305.3889 305.5298 305.6707 305.8116 305.9524 306.0932 306.2341 306.3749 306.5157 306.6565 306.7973 306.9380 307.0788 307.2195 307.3603 307.5010 307.6417 307.7824 307.9231 308.0638 308.2044 308.3451 308.4857 308.6264 308.7670 308.9076 309.0482 309.1888 309.3293 309.4699 309.6104 309.7510 309.8915 310.0320 310.1725 310.3130 310.4534 310.5939 310.7344 310.8748 311.0152 311.1556 311.2960 311.4364 311.5768 311.7172 311.8575 311.9979 312.1382 312.2785 312.4188 312.5591 312.6994 312.8397 312.9800 313.1202 313.2604 313.4007 313.5409 313.6811 313.8213 313.9615 314.1016 314.2418 314.3819 314.5221 314.6622 314.8023 314.9424 315.0825 315.2225 315.3626 315.5026 315.6427 315.7827 315.9227 316.0627 316.2027 316.3427 316.4827 316.6226 316.7626 316.9025 317.0424 317.1823 317.3222 317.4621 317.6020 317.7418 317.8817 318.0215 318.1613 318.3012 318.4410 318.5807 318.7205 318.8603 319.0000 319.1398 319.2795 319.4192 319.5589 319.6986 319.8383 319.9780 320.1177 320.2573 320.3969 320.5366 320.6762 320.8158 320.9554 321.0949 321.2345 321.3741 321.5136 321.6531 321.7927 321.9322 322.0717 322.2111 322.3506 322.4901 322.6295 322.7689 322.9084 323.0478 323.1872 323.3266 323.4659 323.6053 323.7447 323.8840 324.0233 324.1627 324.3020 324.4413 324.5805 324.7198 324.8591 324.9983 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220819T050301.1Z 8266.210429 196 1 50.13 2 81.03 80.68 32.84 184.76 0.00 1 0.00 1 0 17 4.465e-01 3.146e-02 3.578e-01 2.504e-02 7.012142e-01 1.501716e-02 9.672963e-03 -6.000000e+00 2.707108e-01 232.08 -2.00 3.85 -2.00 321.73 0.00e+00 1.666887e-02 7.467298e-03 5.103726e-03 -6.000000e+00 1.376614e-02 282.44 -2.00 20.00 -2.00 321.22 0.00e+00 6.071 0.005 302.00 328.00 3 3.1784e+00 5.3451e-02 7.4665e-02 -6.0000e+00 6.8199e-01 6.7835e-01 6.7815e-02 4.3833e-02 -6.0000e+00 7.4045e-01 -1.0049e+00 5.5949e-02 2.7978e-02 -6.0000e+00 4.3607e-01 4.3526e-01 2.6873e-02 1.5099e-02 -6.0000e+00 1.8860e-01 2.5083e-05 -1.9337e-03 7.7192e-04 2.6424e-04 -6.0000e+00 1.2812e-02 9.2318e-03 0.0000e+00 12 8 8 10 0 0 93.26 17.38 0.70 0.00923 -0.00530 21 4 4 8 0 2386.550 15.01 17.38 27.29 21.58 22.09 27.0 993.42 900000 900000 900000 -112434 900000 -110795 900000 -96868 900000 -131667 -26891 -47205 -60793 -109870 900000 900000 211293 900000 -60131 900000 -24835 900000 9549 -46613 900000 26507 900000 -28991 55246 -45745 25226 56472 14149 -14096 25555 900000 42192 62710 18314 25339 60662 60511 116716 22514 82547 18331 142138 9150 106013 40332 46839 45257 68275 99837 4053 98345 429 5934 28840 44112 27561 27259 58371 4142 24778 12384 36629 4100 1733 10377 816 7201 -9552 520 1552 7770 10461 -10756 -1819 -6598 1251 256 8874 -1064 6045 -2473 -5799 2805 -12307 6581 -7753 4374 -6449 -2273 -2874 1831 -3676 -1882 -3299 -1915 -807 -1850 120 -5833 2417 -3536 -3513 2472 -1883 1283 -1569 -275 454 1238 -970 -114 93 -1234 938 -385 4917 343 1431 1613 3938 517 -323 2661 -1677 921 1246 1520 -1379 1714 -412 -965 1244 -83 -697 -1065 794 -2306 900000 900000 900000 900000 -5973 900000 -4414 900000 -3216 900000 -5829 -655 -1149 -2018 -7782 900000 900000 5144 900000 -4392 900000 -1209 900000 296 -2476 900000 645 900000 -1155 1345 -2531 921 1787 689 -905 1120 900000 1644 2290 1094 1727 3102 3241 3694 1864 3819 1651 3807 958 4388 3437 4105 4408 5652 6320 619 6465 67 854 3511 4618 3624 4048 7248 889 4442 2440 6154 908 441 2733 253 2120 -3192 145 385 1797 2267 -2785 -503 -2293 468 109 3732 -523 2943 -1391 -3530 1596 -8036 3394 -4307 2023 -3269 -1187 -1743 1248 -3091 -1770 -3366 -1895 -726 -1503 90 -4803 1969 -3240 -3429 2468 -2200 1641 -2271 -410 668 1737 -1327 -152 127 -1814 1430 -608 7216 505 2011 2192 5047 660 -414 3587 -2702 1632 2394 3086 -3049 3923 -1025 -2507 3218 -218 -1822 -2656 1811 -5099 900000 SS 20220819T051646.0Z 8266.219977 202 1 49.40 2 78.96 83.36 33.08 190.56 0.00 1 0.00 1 0 17 4.165e-01 1.039e-02 2.976e-01 7.081e-03 6.226084e-01 3.990722e-03 7.824170e-03 -6.000000e+00 2.454186e-01 232.08 -2.00 3.85 -2.00 321.39 0.00e+00 5.643983e-03 1.921239e-03 1.752737e-03 -6.000000e+00 1.058686e-02 282.44 -2.00 20.00 -2.00 320.86 0.00e+00 5.033 0.003 302.00 328.00 3 2.5574e+00 1.3820e-02 6.2466e-02 -6.0000e+00 6.1630e-01 6.3867e-02 1.8761e-02 3.8392e-02 -6.0000e+00 6.6489e-01 -1.4367e-01 1.8577e-02 2.1895e-02 -6.0000e+00 3.9429e-01 6.2117e-02 8.8375e-03 9.0453e-03 -6.0000e+00 1.6853e-01 1.5171e-04 -3.3154e-04 2.1531e-04 1.1618e-04 -6.0000e+00 1.1441e-02 9.8662e-03 0.0000e+00 12 8 8 10 0 0 97.03 17.40 0.39 0.00987 0.00737 74 16 4 8 0 667.490 15.01 17.40 27.88 21.58 22.09 26.7 995.35 -138128 -211051 -77342 -83214 -119330 -141017 -90884 -42680 -109613 -73565 -170638 -122915 -109116 -46402 -35139 -28749 27792 -45033 100808 -83409 -2975 -39965 -31880 6575 1638 -5067 -40394 58985 -56074 14559 -31990 -1154 -4162 10845 29221 -26810 -7824 -8090 2184 -88 14403 -3873 14485 13632 4239 9351 4908 10273 2671 11617 -4345 10810 7627 3584 7506 -4684 8366 1418 5265 3439 8529 3256 6637 8379 1433 4245 -1270 1475 -376 -779 2054 2883 1084 1241 2137 -4949 2635 -2855 1807 -285 892 -133 -3035 -1315 -2889 -264 -826 854 -670 1027 100 713 515 -1886 128 -1280 -573 -537 569 -232 -1045 122 -1101 -524 -1707 -842 -1476 58 328 53 375 457 415 -140 152 -244 834 -134 23 -151 151 471 646 399 -215 103 351 1270 468 -248 316 -572 45 203 165 -662 25 779 -283 -282 42 -507 900000 -1214 -4372 -534 -575 -899 -1328 -628 -295 -1135 -559 -3320 -1952 -1959 -577 -485 -437 269 -995 696 -3052 -49 -966 -748 113 32 -108 -1227 652 -2013 292 -1237 -39 -164 374 807 -1333 -367 -464 137 -7 1024 -353 1150 1120 392 846 478 986 291 1259 -618 1470 1169 558 1178 -862 1371 270 945 634 1596 658 1475 2009 375 1047 -329 394 -117 -276 762 1084 403 430 665 -1500 713 -862 602 -115 412 -70 -1764 -799 -1909 -181 -597 617 -484 694 64 423 301 -1204 91 -1076 -550 -579 640 -257 -1067 111 -971 -481 -1701 -879 -1644 68 429 78 593 742 663 -214 219 -346 1201 -206 37 -252 246 737 976 584 -304 139 471 1823 766 -455 621 -1193 99 473 410 -1720 66 2057 -743 -707 98 -1139 900000 SS 20220819T052342.9Z 8266.224802 205 1 49.44 2 77.91 84.72 33.27 193.47 0.00 1 0.00 1 0 25 2.836e-01 7.498e-03 2.545e-01 5.719e-03 5.847243e-01 3.189782e-03 7.419836e-03 -6.000000e+00 1.670930e-01 232.08 -2.00 3.85 -2.00 321.15 0.00e+00 5.571554e-03 1.432426e-03 1.781804e-03 -6.000000e+00 7.207894e-03 282.44 -2.00 20.00 -2.00 320.59 0.00e+00 4.629 0.002 302.00 328.00 3 2.7048e+00 1.0621e-02 5.7793e-02 -6.0000e+00 4.1961e-01 4.3191e-02 1.4126e-02 3.5746e-02 -6.0000e+00 4.5268e-01 -5.0137e-02 1.3817e-02 2.0768e-02 -6.0000e+00 2.6845e-01 1.1185e-02 6.6794e-03 8.8543e-03 -6.0000e+00 1.1474e-01 1.9483e-04 3.0156e-05 1.7311e-04 1.0900e-04 -6.0000e+00 7.7890e-03 9.5359e-03 0.0000e+00 11 8 0 10 0 0 93.67 17.40 0.36 0.00954 0.00976 71 15 4 8 0 696.290 15.01 17.40 28.11 21.58 22.09 26.7 996.57 -107439 -31652 -59492 -81738 -161658 -87385 -84662 -96770 -87154 -56834 34417 -73222 17078 -64157 -21944 1681 -21975 31396 -43300 -34007 -36520 -39364 -49976 -18224 -25290 -8025 -6084 -23518 -13315 -14455 4136 -11052 14113 -11488 -64 -5482 -7041 -6361 -11064 3658 513 -1742 -10371 4447 5960 7681 2509 1886 9390 3511 6648 252 3547 -1238 1710 6346 1126 5192 -1333 990 72 1563 1623 5470 3700 1606 1972 242 1273 1467 2652 1397 1110 1584 -678 1125 -2771 -1546 -2393 -623 -1521 -2051 -2087 -1932 -1100 -1257 709 -98 885 717 1554 -363 -714 -438 -302 452 -120 226 -543 118 -415 -1089 -433 -683 -1264 -1717 -414 -178 860 533 892 343 94 -230 -269 725 494 101 -15 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