File name: Pandora132s1_Berlin_20240401_L2Fit_fout2c13d20210422p1-8.txt File generation date: 20241123T213230.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Thomas Ruhtz Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 132 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora132_OF_v1d20200910.txt Instrument calibration file used: Pandora132s1_CF_v13d20210422.txt Level 1 file used: Pandora132s1_Berlin_20240401_L1_smca1c13d20210422p1-8.txt Full location name: Institute of Space Sciences FU Berlin Short location name: Berlin Country of location: Germany Location latitude [deg]: 52.4600 Location longitude [deg]: 13.3100 Location altitude [m]: 100 Local noon date: 20240401 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 11, but different RefDay (April 2021). First and last pixel inside fitting window: 243 385 Nominal wavelengths inside fitting window [nm]: 305.1071 305.2480 305.3889 305.5298 305.6707 305.8116 305.9524 306.0932 306.2341 306.3749 306.5157 306.6565 306.7973 306.9380 307.0788 307.2195 307.3603 307.5010 307.6417 307.7824 307.9231 308.0638 308.2044 308.3451 308.4857 308.6264 308.7670 308.9076 309.0482 309.1888 309.3293 309.4699 309.6104 309.7510 309.8915 310.0320 310.1725 310.3130 310.4534 310.5939 310.7344 310.8748 311.0152 311.1556 311.2960 311.4364 311.5768 311.7172 311.8575 311.9979 312.1382 312.2785 312.4188 312.5591 312.6994 312.8397 312.9800 313.1202 313.2604 313.4007 313.5409 313.6811 313.8213 313.9615 314.1016 314.2418 314.3819 314.5221 314.6622 314.8023 314.9424 315.0825 315.2225 315.3626 315.5026 315.6427 315.7827 315.9227 316.0627 316.2027 316.3427 316.4827 316.6226 316.7626 316.9025 317.0424 317.1823 317.3222 317.4621 317.6020 317.7418 317.8817 318.0215 318.1613 318.3012 318.4410 318.5807 318.7205 318.8603 319.0000 319.1398 319.2795 319.4192 319.5589 319.6986 319.8383 319.9780 320.1177 320.2573 320.3969 320.5366 320.6762 320.8158 320.9554 321.0949 321.2345 321.3741 321.5136 321.6531 321.7927 321.9322 322.0717 322.2111 322.3506 322.4901 322.6295 322.7689 322.9084 323.0478 323.1872 323.3266 323.4659 323.6053 323.7447 323.8840 324.0233 324.1627 324.3020 324.4413 324.5805 324.7198 324.8591 324.9983 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240401T054230.4Z 8857.237852 147 1 9.46 2 81.38 93.44 83.49 195.93 0.00 1 0.00 1 0 25 5.648e-01 4.418e-02 4.611e-01 3.480e-02 1.055736e+00 2.065736e-02 1.214512e-02 -6.000000e+00 3.338486e-01 226.53 -2.00 3.85 -2.00 322.16 0.00e+00 7.455251e-03 9.623248e-03 2.243469e-03 -6.000000e+00 1.633498e-02 270.64 -2.00 20.00 -2.00 321.74 0.00e+00 6.300 0.005 302.00 328.00 3 2.4234e+00 6.9193e-02 8.9458e-02 -6.0000e+00 8.3487e-01 1.5312e+00 8.5244e-02 6.8449e-02 -6.0000e+00 9.1447e-01 -1.9762e+00 7.0816e-02 3.1728e-02 -6.0000e+00 5.3482e-01 8.0007e-01 3.6778e-02 1.4200e-02 -6.0000e+00 2.2836e-01 2.4733e-05 -3.2389e-04 8.8290e-04 1.7138e-04 -6.0000e+00 1.6815e-02 -2.4717e-02 0.0000e+00 12 9 9 12 1 1 -988.52 16.20 0.12 -0.02472 -0.02715 3 4 2 8 0 2362.870 14.98 16.20 17.72 22.50 22.80 29.8 980.19 900000 -38105 900000 900000 -9181 900000 -56530 900000 -53267 900000 28094 900000 900000 -78863 -18485 27226 900000 -35852 52619 9523 -22534 -10681 900000 900000 -57445 25292 -88989 900000 18012 900000 161207 -62970 300333 -29934 900000 -58001 900000 58498 243665 41020 41660 19624 69169 900000 -9248 900000 23673 68673 5324 116356 117270 45117 900000 80692 175196 89586 56441 46884 160366 57921 -7731 60318 24799 92511 -14130 18900 20677 60910 35021 3307 77784 18036 31658 14066 15375 -18051 47975 33084 8084 11802 12959 28224 -11119 18660 -13055 4542 -1328 3901 10933 -6078 10117 -12590 4197 -8154 5056 -18 -4053 2071 -3622 5882 -11719 2971 -14512 7837 1416 -1452 -3459 -8932 -3684 -1424 1170 -6388 1943 -512 -661 -5266 2582 -778 -1798 3743 1716 5730 4855 4309 302 4671 2041 629 -859 -1343 2861 -1156 1829 663 1291 -146 -733 1896 -1910 565 -2660 1943 -3604 900000 -2255 900000 900000 -310 900000 -2071 900000 -1801 900000 950 900000 900000 -5999 -938 997 900000 -2727 1779 429 -1270 -482 900000 900000 -3885 855 -7271 900000 609 900000 5451 -6032 10155 -2277 900000 -4903 900000 1978 8239 2143 2305 1387 2976 900000 -824 900000 1528 2955 458 3934 3965 3467 900000 4961 5924 5232 4511 3891 5422 3739 -974 4264 2897 6256 -2707 2847 3114 6553 5490 736 9563 3710 5838 2767 2599 -3773 5014 4373 1640 2829 3359 7237 -4637 6099 -6143 1869 -599 1682 4282 -2671 3535 -5286 1514 -3699 2393 -11 -3038 1698 -3175 5072 -11062 2109 -10999 4726 965 -1076 -2787 -8381 -3789 -1555 1430 -9171 2648 -708 -889 -7286 3378 -1105 -2693 5315 2366 7078 6252 5427 385 5514 2473 857 -1308 -2413 5558 -2546 4215 1668 3195 -380 -1934 4849 -4935 1432 -6309 4007 -7602 SS 20240401T055029.6Z 8857.243398 151 1 49.73 2 80.17 95.04 83.83 197.59 0.00 1 0.00 1 0 17 7.590e-01 1.510e-02 3.512e-01 7.545e-03 9.760373e-01 4.325742e-03 1.116183e-02 -6.000000e+00 4.318289e-01 226.53 -2.00 3.85 -2.00 322.18 0.00e+00 3.240116e-03 2.266944e-03 3.447652e-03 -6.000000e+00 1.827597e-02 270.65 -2.00 20.00 -2.00 321.77 0.00e+00 5.599 0.004 302.00 328.00 3 1.6311e+00 1.5300e-02 8.3361e-02 -6.0000e+00 1.0737e+00 5.6253e-01 2.4163e-02 6.7286e-02 -6.0000e+00 1.1711e+00 -7.3070e-01 2.7663e-02 3.4814e-02 -6.0000e+00 6.9356e-01 2.9735e-01 1.2646e-02 1.1654e-02 -6.0000e+00 2.8995e-01 1.4000e-04 -7.1810e-04 1.9607e-04 1.4981e-04 -6.0000e+00 2.0812e-02 -2.2921e-02 0.0000e+00 12 8 8 10 0 0 98.54 16.30 0.27 -0.02292 -0.02832 102 22 4 8 0 487.420 15.03 16.30 18.01 22.50 22.80 29.6 981.11 -300710 -239078 -234510 -269446 19718 -223073 -184406 -269680 -212366 -206086 -241196 -141831 -225663 900000 -75583 45683 -115238 -30713 -78655 -58670 -53255 -117395 -28056 -96344 -57584 -131150 -90342 -41001 -50324 -23917 -54977 -42329 -44169 82193 -46243 7217 -23792 -21954 -1340 10641 63881 -273 38045 6639 45106 9719 23737 32828 20815 40566 17236 47008 11275 29235 12418 30125 20328 11351 34096 4214 20214 11484 23774 12310 10220 16687 6039 8755 8412 11656 4597 11521 5433 7650 2739 4993 4858 -4382 719 -4684 3387 -336 2384 -653 224 865 1232 312 -1238 1598 -56 1009 -3794 -244 -1613 -1659 -973 -1469 -1029 -1447 266 -2613 -672 -1149 -1864 -1308 -1700 -1709 -337 -566 -826 205 -405 -118 -340 -1137 378 -491 822 -578 794 882 1330 1254 2073 1019 -518 1384 579 879 70 270 110 120 277 -486 214 314 -123 -181 403 -676 -1488 -4827 -2398 -2353 -3604 145 -1641 -1357 -3788 -1846 -1792 -3226 -1043 -4226 900000 -612 336 -1773 -249 -1099 -691 -588 -2418 -248 -1843 -805 -3956 -1794 -483 -666 -282 -1132 -965 -1202 665 -1293 117 -578 -630 -38 321 1269 -11 1092 264 1228 386 856 1159 903 1612 989 2282 871 2065 1105 2349 1780 1061 2408 388 1636 1141 2449 1639 1496 2320 960 1462 1609 2253 1036 2481 1195 1504 552 882 833 -893 166 -1269 1013 -121 920 -277 99 401 593 154 -608 726 -24 413 -1644 -112 -887 -1095 -756 -1327 -1009 -1422 236 -2097 -478 -820 -1425 -1050 -1455 -1602 -355 -697 -1160 308 -626 -178 -498 -1639 547 -750 1295 -929 1204 1253 1796 1645 2612 1252 -643 1848 917 1617 145 606 265 313 768 -1292 571 915 -352 -488 985 -1537 -3320 SS 20240401T055908.8Z 8857.249408 155 1 49.48 2 78.85 96.78 84.24 199.38 0.00 1 0.00 1 0 17 7.089e-01 1.246e-02 3.100e-01 6.437e-03 8.848118e-01 3.612832e-03 1.031567e-02 -6.000000e+00 4.033239e-01 226.53 -2.00 3.85 -2.00 321.93 0.00e+00 7.115716e-03 1.809151e-03 1.709162e-03 -6.000000e+00 1.715622e-02 270.65 -2.00 20.00 -2.00 321.51 0.00e+00 4.994 0.003 302.00 328.00 3 2.0558e+00 1.2312e-02 7.3556e-02 -6.0000e+00 1.0028e+00 3.5855e-01 1.9029e-02 5.8161e-02 -6.0000e+00 1.0941e+00 -4.5521e-01 2.2003e-02 2.9930e-02 -6.0000e+00 6.4774e-01 1.8870e-01 1.0197e-02 1.2793e-02 -6.0000e+00 2.7274e-01 1.7821e-04 -6.0141e-04 1.7013e-04 1.4875e-04 -6.0000e+00 1.9468e-02 -2.2667e-02 0.0000e+00 12 8 8 10 0 0 99.88 16.36 0.28 -0.02267 -0.02719 111 24 4 8 0 445.650 15.03 16.36 18.27 22.50 22.80 29.6 982.05 900000 -299525 -172541 -227873 -302770 -217208 -251510 -146403 -220051 -46692 -269056 -203147 -171903 -134427 -122295 -60652 -103696 -26462 -56405 -14202 -83235 -47568 5647 4557 -80576 -62703 -25640 -32130 -76968 -40182 -19262 -3792 -20802 -25086 -5495 -40513 13124 -7950 33981 -1072 26007 -2494 31379 -4780 14163 16291 5646 4531 4204 10533 5734 20916 17322 14930 11423 8004 11857 4389 9773 7218 5977 6696 6898 12470 8545 9056 5634 8158 7569 5168 4922 5966 5721 3070 2175 -2366 3910 -188 -1094 515 -1049 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