File name: Pandora139s1_BlueHillMA_20200909_L2Fit_fout2c8d20200818p1-8.txt File generation date: 20260515T055843.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 139 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora139_OF_v2d20200209.txt Instrument calibration file used: Pandora139s1_CF_v8d20200818.txt Level 1 file used: Pandora139s1_BlueHillMA_20200909_L1_smca1c8d20200818p1-8.txt Full location name: Blue Hill, Department of Environmental Protection, MA Short location name: BlueHillMA Country of location: United States Location latitude [deg]: 42.2118 Location longitude [deg]: -71.1145 Location altitude [m]: 188 Local noon date: 20200909 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 240 382 Nominal wavelengths inside fitting window [nm]: 305.0623 305.2031 305.3438 305.4844 305.6251 305.7658 305.9064 306.0471 306.1877 306.3283 306.4689 306.6095 306.7501 306.8907 307.0312 307.1718 307.3123 307.4528 307.5933 307.7338 307.8743 308.0148 308.1552 308.2957 308.4361 308.5765 308.7170 308.8574 308.9977 309.1381 309.2785 309.4188 309.5592 309.6995 309.8398 309.9801 310.1204 310.2607 310.4009 310.5412 310.6814 310.8217 310.9619 311.1021 311.2423 311.3825 311.5226 311.6628 311.8029 311.9431 312.0832 312.2233 312.3634 312.5035 312.6435 312.7836 312.9236 313.0637 313.2037 313.3437 313.4837 313.6237 313.7637 313.9036 314.0436 314.1835 314.3234 314.4634 314.6033 314.7432 314.8830 315.0229 315.1628 315.3026 315.4424 315.5822 315.7220 315.8618 316.0016 316.1414 316.2811 316.4209 316.5606 316.7003 316.8401 316.9798 317.1194 317.2591 317.3988 317.5384 317.6781 317.8177 317.9573 318.0969 318.2365 318.3761 318.5156 318.6552 318.7947 318.9343 319.0738 319.2133 319.3528 319.4923 319.6317 319.7712 319.9106 320.0501 320.1895 320.3289 320.4683 320.6077 320.7470 320.8864 321.0258 321.1651 321.3044 321.4437 321.5830 321.7223 321.8616 322.0009 322.1401 322.2794 322.4186 322.5578 322.6970 322.8362 322.9754 323.1146 323.2537 323.3929 323.5320 323.6711 323.8102 323.9493 324.0884 324.2275 324.3665 324.5056 324.6446 324.7837 324.9227 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200909T120748.5Z 7557.505423 1571 1 7.04 2 70.75 101.05 36.77 242.78 0.00 1 0.00 1 0 17 3.187e-02 7.607e-03 2.158e-02 3.873e-03 3.604200e-01 1.988324e-03 4.285908e-03 -6.000000e+00 1.861344e-02 229.54 -2.00 3.53 -2.00 318.25 0.00e+00 7.681945e-04 3.799786e-04 2.089209e-04 -6.000000e+00 8.281307e-04 286.42 -2.00 20.00 -2.00 317.46 0.00e+00 2.997 0.000 302.00 328.00 3 2.8485e+00 5.3832e-03 3.4887e-02 -6.0000e+00 4.6367e-02 1.5255e-02 6.1165e-03 1.8927e-02 -6.0000e+00 5.0170e-02 -2.0383e-03 3.9805e-03 9.2277e-03 -6.0000e+00 2.9908e-02 -2.2785e-03 2.0591e-03 2.6175e-03 -6.0000e+00 1.2714e-02 1.0612e-03 -2.8801e-04 1.1318e-04 2.8827e-05 -6.0000e+00 8.9236e-04 -6.2365e-03 0.0000e+00 12 9 1 12 1 1 98.46 24.21 0.10 -0.00624 -0.00840 6 31 1 5 0 979.960 27.26 19.99 24.21 14.8 1003.43 -11170 -11818 -10813 205 -12614 -15914 -3210 -13273 7560 -4076 -3330 -2723 -2685 -4618 -3971 3211 -6316 3982 -1172 3531 2279 -521 2395 1368 1303 4479 104 -3384 636 -1847 3047 -176 744 -947 -1572 -2549 -4689 712 -1369 -381 -1838 -372 812 138 -1325 -1175 -1215 -831 -851 96 1023 1872 1104 2094 1329 1385 1339 296 228 37 -938 2543 2140 2136 1155 501 -730 -1939 335 1332 236 1173 145 663 -234 -56 -1093 -2281 -1452 -976 -1401 -1169 -1606 -1758 -1284 -528 -141 784 710 1130 973 -11 -719 -224 142 -318 -5 445 941 139 128 -1576 -996 -1227 -38 -438 -751 -490 -372 773 362 820 546 96 -379 -444 -440 -463 364 339 109 57 265 706 521 694 -490 58 372 509 218 12 -355 -135 253 411 -269 78 59 330 25 -535 -1012 -614 -724 -683 11 -717 -904 -173 -870 459 -290 -240 -205 -228 -466 -461 390 -894 541 -175 528 354 -83 382 233 236 824 20 -645 112 -335 570 -37 170 -229 -369 -595 -1198 199 -456 -144 -766 -161 358 62 -607 -541 -558 -378 -388 44 492 955 599 1180 779 831 820 183 139 23 -588 1639 1484 1565 866 364 -513 -1361 242 1044 200 1022 127 568 -192 -43 -790 -1618 -1061 -775 -1222 -1096 -1592 -1809 -1376 -589 -163 922 837 1308 1081 -12 -729 -223 146 -352 -6 565 1247 186 165 -1955 -1180 -1468 -47 -567 -1005 -675 -531 1147 561 1292 853 145 -552 -623 -613 -661 537 519 170 88 402 1048 753 976 -675 80 531 764 342 20 -580 -226 436 733 -489 143 110 604 45 -939 -1747 SS 20200909T121053.8Z 7557.507567 1574 1 9.55 2 70.19 101.61 37.27 243.63 0.00 1 0.00 1 0 17 5.493e-02 8.029e-03 2.971e-02 4.815e-03 3.502737e-01 2.472578e-03 4.163234e-03 -6.000000e+00 3.207268e-02 229.54 -2.00 3.53 -2.00 318.23 0.00e+00 8.466061e-04 4.699617e-04 2.033478e-04 -6.000000e+00 1.427338e-03 286.42 -2.00 20.00 -2.00 317.44 0.00e+00 2.918 0.000 302.00 328.00 3 3.5206e+00 6.6823e-03 3.3936e-02 -6.0000e+00 7.9893e-02 2.4592e-02 7.5951e-03 1.8387e-02 -6.0000e+00 8.6453e-02 8.4252e-03 4.9589e-03 8.9812e-03 -6.0000e+00 5.1538e-02 -1.0646e-02 2.5662e-03 2.5631e-03 -6.0000e+00 2.1902e-02 5.8786e-04 -4.8664e-04 1.4128e-04 2.8054e-05 -6.0000e+00 1.5381e-03 -4.5287e-03 0.0000e+00 12 9 1 12 9 1 99.82 24.22 0.20 -0.00453 -0.00819 4 17 1 5 0 1802.880 27.26 20.00 24.22 14.8 1003.46 40626 -5036 -10036 15732 7449 34370 -13935 -1965 -8686 -9382 -309 -8978 -6310 -3084 4392 -3912 -194 -4605 5334 214 3632 5953 -3207 1973 -399 624 -3838 -3532 -1681 -2021 -1806 -3955 -1105 -583 -1653 -4538 -6085 -1991 -46 1008 -2024 923 -220 649 -501 1408 -888 -174 694 794 1336 586 1015 264 1879 2263 1272 1261 114 140 78 1797 398 2777 1338 -835 -21 -2028 196 135 964 136 370 279 1025 -1040 -1271 -1603 -219 -384 -1729 -874 -2249 -2092 -1314 -520 -2 895 1351 455 -167 642 286 -573 341 458 -67 817 30 553 -304 -882 -1694 -751 -382 -1004 -410 -373 222 241 1111 459 0 681 -293 -557 -554 -55 42 484 604 -332 390 529 581 -145 -115 -213 334 257 21 459 -488 -485 -254 314 -57 904 466 166 -331 -774 -725 1423 -294 -635 761 358 1263 -831 -118 -615 -708 -22 -722 -561 -310 478 -512 -26 -682 761 33 563 907 -542 337 -74 120 -767 -679 -306 -371 -354 -871 -258 -141 -389 -1077 -1575 -570 -15 379 -853 397 -99 293 -230 640 -411 -79 314 365 645 304 555 152 1102 1356 784 778 70 86 49 1170 281 2040 1007 -617 -15 -1427 142 107 816 120 326 241 838 -803 -920 -1129 -158 -303 -1512 -821 -2242 -2164 -1411 -583 -2 1057 1595 531 -187 677 288 -569 351 503 -80 1036 41 738 -395 -1088 -2012 -896 -474 -1307 -549 -514 316 360 1718 726 -1 1029 -425 -780 -769 -78 62 739 938 -515 593 786 838 -204 -158 -292 475 384 33 733 -795 -810 -439 560 -103 1655 861 303 -592 -1360 -1251 SS 20200909T121408.4Z 7557.509820 1578 1 6.83 2 69.60 102.20 37.79 244.50 0.00 1 0.00 1 0 25 2.057e-02 6.859e-03 1.097e-02 2.364e-03 3.400131e-01 1.213137e-03 4.073486e-03 -6.000000e+00 1.201563e-02 229.54 -2.00 3.53 -2.00 317.94 0.00e+00 6.286960e-04 2.111884e-04 2.231332e-04 -6.000000e+00 5.345525e-04 286.42 -2.00 20.00 -2.00 317.14 0.00e+00 2.839 0.000 302.00 328.00 3 2.1446e+00 3.2555e-03 3.3006e-02 -6.0000e+00 2.9931e-02 3.8917e-03 3.6814e-03 1.7853e-02 -6.0000e+00 3.2386e-02 -2.6815e-05 2.3215e-03 8.6950e-03 -6.0000e+00 1.9307e-02 -2.7860e-03 1.1858e-03 2.4306e-03 -6.0000e+00 8.2077e-03 2.5788e-03 -3.7413e-04 6.9061e-05 2.7166e-05 -6.0000e+00 5.7601e-04 -6.6385e-03 0.0000e+00 12 9 1 12 9 1 99.80 24.22 0.20 -0.00664 -0.00945 14 68 1 5 0 443.430 27.26 20.00 24.22 14.8 1003.76 -8072 556 -1334 -322 -12647 -3448 -6591 2631 -7881 -1213 -4044 -8392 -538 -2030 976 -1532 3154 -120 1472 523 -512 -1127 -1284 1892 -2051 1412 -2271 -620 -1812 -1707 704 771 120 -947 -923 -4271 -1474 -1165 491 -586 -347 87 -1302 726 -162 415 -1002 -167 322 -989 1171 1445 1503 1093 1195 572 1469 1236 -411 732 649 999 1542 2030 1204 134 -685 -1486 379 963 214 603 673 745 388 -709 -1111 -1245 -1686 -1072 -1460 -1083 -1613 -2009 -1342 -564 66 494 579 868 366 243 -213 -43 -98 -56 -35 725 569 162 -627 -974 -1385 -756 -686 -727 -189 -554 -293 489 1006 710 644 269 -293 -491 18 156 -132 695 -150 -81 11 485 501 491 -199 512 457 269 534 -25 -395 -226 -62 157 -306 331 345 10 -76 -436 -910 -545 39 -98 -22 -900 -218 -456 188 -679 -104 -361 -821 -55 -243 130 -232 489 -20 254 95 -97 -214 -250 380 -452 314 -518 -135 -384 -360 156 187 31 -260 -243 -1139 -413 -371 179 -247 -158 41 -641 356 -80 206 -501 -83 158 -495 609 793 873 660 744 365 949 801 -266 469 423 690 1125 1556 938 102 -503 -1079 285 787 187 546 604 659 328 -564 -832 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