File name: Pandora139s1_BlueHillMA_20200913_L2Fit_fout2c8d20200818p1-8.txt File generation date: 20260515T060624.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 139 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora139_OF_v2d20200209.txt Instrument calibration file used: Pandora139s1_CF_v8d20200818.txt Level 1 file used: Pandora139s1_BlueHillMA_20200913_L1_smca1c8d20200818p1-8.txt Full location name: Blue Hill, Department of Environmental Protection, MA Short location name: BlueHillMA Country of location: United States Location latitude [deg]: 42.2118 Location longitude [deg]: -71.1145 Location altitude [m]: 188 Local noon date: 20200913 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 240 382 Nominal wavelengths inside fitting window [nm]: 305.0623 305.2031 305.3438 305.4844 305.6251 305.7658 305.9064 306.0471 306.1877 306.3283 306.4689 306.6095 306.7501 306.8907 307.0312 307.1718 307.3123 307.4528 307.5933 307.7338 307.8743 308.0148 308.1552 308.2957 308.4361 308.5765 308.7170 308.8574 308.9977 309.1381 309.2785 309.4188 309.5592 309.6995 309.8398 309.9801 310.1204 310.2607 310.4009 310.5412 310.6814 310.8217 310.9619 311.1021 311.2423 311.3825 311.5226 311.6628 311.8029 311.9431 312.0832 312.2233 312.3634 312.5035 312.6435 312.7836 312.9236 313.0637 313.2037 313.3437 313.4837 313.6237 313.7637 313.9036 314.0436 314.1835 314.3234 314.4634 314.6033 314.7432 314.8830 315.0229 315.1628 315.3026 315.4424 315.5822 315.7220 315.8618 316.0016 316.1414 316.2811 316.4209 316.5606 316.7003 316.8401 316.9798 317.1194 317.2591 317.3988 317.5384 317.6781 317.8177 317.9573 318.0969 318.2365 318.3761 318.5156 318.6552 318.7947 318.9343 319.0738 319.2133 319.3528 319.4923 319.6317 319.7712 319.9106 320.0501 320.1895 320.3289 320.4683 320.6077 320.7470 320.8864 321.0258 321.1651 321.3044 321.4437 321.5830 321.7223 321.8616 322.0009 322.1401 322.2794 322.4186 322.5578 322.6970 322.8362 322.9754 323.1146 323.2537 323.3929 323.5320 323.6711 323.8102 323.9493 324.0884 324.2275 324.3665 324.5056 324.6446 324.7837 324.9227 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200913T114112.0Z 7561.486945 715 1 30.03 2 76.38 97.75 27.59 126.88 0.00 1 0.00 1 0 17 8.019e-02 5.615e-03 2.832e-02 1.627e-03 4.687685e-01 8.485494e-04 5.472201e-03 -6.000000e+00 4.672786e-02 229.20 -2.00 3.53 -2.00 319.93 0.00e+00 9.127665e-04 2.736253e-04 4.828088e-04 -6.000000e+00 2.081014e-03 286.10 -2.00 20.00 -2.00 319.21 0.00e+00 4.147 0.001 302.00 328.00 3 1.1574e+00 2.4921e-03 4.7462e-02 -6.0000e+00 1.1631e-01 1.2789e-03 3.0065e-03 2.4949e-02 -6.0000e+00 1.2593e-01 2.0587e-02 2.4796e-03 1.2360e-02 -6.0000e+00 7.5080e-02 -1.7084e-02 1.2795e-03 3.6066e-03 -6.0000e+00 3.1891e-02 1.7337e-03 -2.5308e-04 4.8264e-05 4.2091e-05 -6.0000e+00 2.2461e-03 9.3031e-04 0.0000e+00 10 0 0 10 0 0 99.96 23.68 0.19 0.00093 -0.00097 142 142 1 5 0 211.460 26.73 20.00 23.68 14.9 1003.02 -37626 -11759 -31097 -28014 -31425 -16892 -30641 -31654 -13386 -24999 -17656 -24528 -5143 -12652 -4406 1209 -6320 -1779 -2863 -4776 -5308 3275 -2801 3638 1845 1800 826 -4679 485 -4228 680 1960 2686 -2737 -4255 134 -4207 -430 -1610 27 -1158 -273 34 -807 1178 -183 -731 -1152 378 -448 614 1069 679 1242 639 1187 590 303 36 575 959 1343 2298 1949 1422 -145 39 -1136 -76 1128 662 1180 284 766 64 -570 -1243 -1866 -1453 -851 -1085 -1094 -1413 -1682 -1186 -438 344 551 957 1093 552 228 -421 -509 -61 -3 253 655 866 51 -151 -1122 -1405 -771 -378 -1032 -584 -423 -85 588 743 845 313 270 -139 -508 -397 -355 18 180 -92 -175 257 281 387 418 -295 116 370 106 158 -200 -463 -156 1 67 -73 422 304 174 -131 -251 -506 -652 -180 -566 -519 -557 -255 -575 -638 -276 -577 -394 -644 -133 -434 -156 47 -292 -85 -149 -267 -309 177 -168 221 116 119 56 -324 33 -293 51 166 255 -289 -442 13 -477 -56 -243 5 -231 -58 8 -184 267 -43 -172 -276 91 -114 168 320 209 408 223 428 220 113 13 209 359 544 1028 959 728 -73 19 -554 -40 666 409 763 185 476 39 -318 -642 -950 -794 -533 -741 -842 -1188 -1426 -1069 -420 346 571 990 1094 519 211 -366 -442 -57 -3 287 790 1128 67 -189 -1290 -1585 -872 -434 -1269 -753 -576 -117 885 1210 1369 505 436 -211 -732 -568 -529 29 299 -149 -291 411 434 572 622 -423 168 554 176 270 -360 -870 -294 3 140 -153 894 649 362 -273 -499 -977 SS 20200913T114320.2Z 7561.488428 717 1 30.35 2 75.99 98.12 27.29 127.69 0.00 1 0.00 1 0 25 7.787e-02 5.931e-03 5.534e-02 3.050e-03 4.596440e-01 1.593420e-03 5.338936e-03 -6.000000e+00 4.537080e-02 229.20 -2.00 3.53 -2.00 320.07 0.00e+00 -9.617231e-05 5.329143e-04 2.494797e-04 -6.000000e+00 2.020791e-03 286.10 -2.00 20.00 -2.00 319.35 0.00e+00 4.038 0.001 302.00 328.00 3 2.2192e+00 4.7451e-03 4.6298e-02 -6.0000e+00 1.1293e-01 -1.3113e-02 5.7679e-03 2.4444e-02 -6.0000e+00 1.2228e-01 4.4636e-02 4.7805e-03 1.2043e-02 -6.0000e+00 7.2902e-02 -2.6816e-02 2.4486e-03 3.3980e-03 -6.0000e+00 3.0961e-02 6.7141e-04 -2.1464e-04 9.1840e-05 3.9373e-05 -6.0000e+00 2.1813e-03 1.8155e-03 0.0000e+00 10 0 0 10 0 0 99.99 23.68 0.16 0.00182 0.00020 94 94 1 5 0 319.340 26.73 20.00 23.68 14.8 1002.61 -41701 -12215 -20273 -19885 148 -39150 -13038 -38270 7973 -29766 1788 -18084 -14468 569 -17098 3564 -2279 13845 -805 4055 -1446 658 -2861 3313 8817 4415 1432 5400 4705 -929 -1963 2191 -3856 7385 -1772 -76 -2963 -3893 -1101 420 -417 -2367 207 -2224 1821 -2478 914 -2634 -1843 -1015 535 1680 395 2261 61 1149 -104 -334 514 -777 1152 1792 2082 1573 1765 40 -1078 -870 -329 959 471 574 557 1042 571 -547 -896 -2508 -808 -829 -352 -1139 -1619 -1540 -809 -852 91 825 1137 1184 894 380 -551 -472 -166 -105 467 966 926 -43 -291 -1362 -1409 -227 -665 -458 -786 -361 -482 566 843 809 514 252 -114 -875 -116 -468 83 -112 -263 -98 169 261 7 449 -136 410 118 86 67 -21 -375 -322 172 -4 -35 400 304 120 12 -115 -653 -734 -191 -355 -336 2 -720 -210 -865 138 -748 36 -462 -416 17 -690 138 -101 565 -40 203 -78 35 -166 193 531 289 98 348 296 -64 -150 181 -369 678 -173 -7 -315 -491 -163 71 -79 -484 43 -485 385 -554 199 -598 -423 -242 136 459 119 708 21 400 -38 -122 182 -277 415 697 885 736 838 19 -492 -399 -163 527 283 362 351 627 324 -287 -441 -1227 -418 -487 -234 -845 -1295 -1289 -719 -800 90 833 1146 1154 827 332 -461 -393 -147 -103 505 1152 1178 -56 -359 -1573 -1536 -246 -770 -563 -1005 -480 -680 852 1351 1334 842 399 -172 -1272 -169 -700 130 -183 -437 -160 268 406 11 646 -191 580 179 141 117 -38 -699 -623 348 -8 -76 875 670 261 26 -234 -1297 SS 20200913T114839.6Z 7561.492125 765 1 9.14 2 75.02 99.05 26.54 129.75 0.00 1 0.00 1 0 17 6.525e-02 6.824e-03 5.305e-02 4.724e-03 4.317218e-01 2.436437e-03 5.072482e-03 -6.000000e+00 3.802099e-02 229.20 -2.00 3.53 -2.00 319.34 0.00e+00 1.737948e-04 6.492130e-04 4.943013e-04 -6.000000e+00 1.693233e-03 286.10 -2.00 20.00 -2.00 318.59 0.00e+00 3.792 0.001 302.00 328.00 3 2.5599e+00 6.8831e-03 4.3460e-02 -6.0000e+00 9.4638e-02 1.8617e-02 8.0602e-03 2.2900e-02 -6.0000e+00 1.0247e-01 7.1044e-03 6.0566e-03 1.1173e-02 -6.0000e+00 6.1090e-02 -9.5474e-03 3.1700e-03 3.1035e-03 -6.0000e+00 2.5949e-02 6.1632e-04 -4.3978e-05 1.3910e-04 3.5023e-05 -6.0000e+00 1.8276e-03 8.1429e-04 0.0000e+00 12 9 1 12 9 1 99.94 23.67 0.14 0.00081 0.00048 10 37 1 5 0 815.220 26.73 20.00 23.67 14.9 1002.06 -44770 -7559 -25298 -2189 -24482 -20460 -15949 -3860 -17946 -7972 -25594 -8408 -8919 -4856 -2370 1886 -4629 -5940 -3003 912 143 -11697 -5212 3611 -11924 2042 -123 2439 -670 -3491 2440 -2423 -1508 -2346 -744 -3888 -6 1582 5846 2215 -1486 942 1485 -550 -41 165 1173 -2145 -887 -1102 -194 2044 503 1869 1714 1205 -425 -108 -88 -756 992 838 2161 2380 1576 383 184 -857 1716 698 788 62 -556 1995 1294 -1722 -1180 -2070 -1448 -689 -1013 -1439 -1288 -1579 -938 22 -396 406 483 1173 326 -202 -274 -620 556 2 81 206 860 200 -390 -661 -1976 -1045 101 -692 -459 -431 -402 684 559 484 532 -72 -170 -234 -7 -430 203 -301 80 43 816 446 739 445 -605 150 470 -102 392 12 -205 -312 220 371 -149 -204 80 533 -285 -353 -621 -1381 -190 -773 -53 -672 -532 -430 -106 -617 -268 -1029 -314 -385 -239 -133 116 -323 -449 -234 72 12 -1071 -468 321 -1311 208 -13 241 -66 -360 263 -307 -208 -341 -104 -555 -1 272 1157 527 -403 265 432 -166 -12 50 356 -671 -278 -359 -67 753 201 780 749 546 -200 -51 -41 -349 466 422 1172 1384 940 223 104 -487 1023 465 565 46 -420 1436 881 -1111 -707 -1224 -903 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