File name: Pandora139s1_BlueHillMA_20200925_L2Fit_fout2c8d20200818p1-8.txt File generation date: 20260515T061038.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 139 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora139_OF_v2d20200209.txt Instrument calibration file used: Pandora139s1_CF_v8d20200818.txt Level 1 file used: Pandora139s1_BlueHillMA_20200925_L1_smca1c8d20200818p1-8.txt Full location name: Blue Hill, Department of Environmental Protection, MA Short location name: BlueHillMA Country of location: United States Location latitude [deg]: 42.2118 Location longitude [deg]: -71.1145 Location altitude [m]: 188 Local noon date: 20200925 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 240 382 Nominal wavelengths inside fitting window [nm]: 305.0623 305.2031 305.3438 305.4844 305.6251 305.7658 305.9064 306.0471 306.1877 306.3283 306.4689 306.6095 306.7501 306.8907 307.0312 307.1718 307.3123 307.4528 307.5933 307.7338 307.8743 308.0148 308.1552 308.2957 308.4361 308.5765 308.7170 308.8574 308.9977 309.1381 309.2785 309.4188 309.5592 309.6995 309.8398 309.9801 310.1204 310.2607 310.4009 310.5412 310.6814 310.8217 310.9619 311.1021 311.2423 311.3825 311.5226 311.6628 311.8029 311.9431 312.0832 312.2233 312.3634 312.5035 312.6435 312.7836 312.9236 313.0637 313.2037 313.3437 313.4837 313.6237 313.7637 313.9036 314.0436 314.1835 314.3234 314.4634 314.6033 314.7432 314.8830 315.0229 315.1628 315.3026 315.4424 315.5822 315.7220 315.8618 316.0016 316.1414 316.2811 316.4209 316.5606 316.7003 316.8401 316.9798 317.1194 317.2591 317.3988 317.5384 317.6781 317.8177 317.9573 318.0969 318.2365 318.3761 318.5156 318.6552 318.7947 318.9343 319.0738 319.2133 319.3528 319.4923 319.6317 319.7712 319.9106 320.0501 320.1895 320.3289 320.4683 320.6077 320.7470 320.8864 321.0258 321.1651 321.3044 321.4437 321.5830 321.7223 321.8616 322.0009 322.1401 322.2794 322.4186 322.5578 322.6970 322.8362 322.9754 323.1146 323.2537 323.3929 323.5320 323.6711 323.8102 323.9493 324.0884 324.2275 324.3665 324.5056 324.6446 324.7837 324.9227 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200925T111053.3Z 7573.465895 151 1 30.58 2 84.32 96.73 160.29 330.98 0.00 1 0.00 1 0 29 8.110e-01 8.466e-02 5.065e-01 5.513e-02 9.363089e-01 3.300363e-02 1.049699e-02 -6.000000e+00 4.855805e-01 227.85 -2.00 3.53 -2.00 321.85 0.00e+00 -9.983189e-03 1.347127e-02 8.522634e-03 -6.000000e+00 2.586776e-02 284.66 -2.00 20.00 -2.00 321.28 0.00e+00 8.911 0.013 302.00 328.00 3 1.1356e+00 1.1248e-01 1.1482e-01 -6.0000e+00 1.2146e+00 1.7428e+00 1.3596e-01 9.1934e-02 -6.0000e+00 1.3259e+00 -1.8300e+00 8.5012e-02 2.8635e-02 -6.0000e+00 7.8373e-01 6.7496e-01 4.4262e-02 1.3256e-02 -6.0000e+00 3.3897e-01 8.6948e-06 -5.8278e-04 1.5254e-03 9.6665e-05 -6.0000e+00 2.4176e-02 -1.3794e-03 0.0000e+00 12 8 8 10 0 0 28.81 23.77 1.44 -0.00138 -0.00576 8 8 1 5 0 3820.750 26.83 20.00 23.77 15.3 996.97 -24820 900000 900000 900000 -81573 40823 -82129 330775 900000 900000 176602 -85787 900000 -16535 136486 36570 106515 900000 -4063 900000 288481 24529 -25277 900000 63946 900000 105198 -77215 900000 -53818 47603 -11040 900000 -45198 83667 900000 30769 900000 107478 137993 56339 900000 249776 223815 -9713 900000 256831 22922 900000 900000 257166 134806 900000 -7851 25265 149506 -14686 155689 -36113 95210 -2409 61692 57907 21320 200435 -31612 96618 -13639 92546 20838 55226 22701 -7968 31367 73005 71668 -3605 31871 -7634 -13301 22344 -7707 62914 -9320 22656 -26501 50088 2739 -478 25370 3372 19504 -6926 28160 -18584 2071 36120 21459 -5619 -9605 -3563 -11161 -6872 -23887 13634 -9668 9616 9113 -7904 -2806 -16079 1213 3601 -504 -2169 -3040 4761 8476 3431 1016 12665 -1116 14904 -6887 3508 5406 -2420 8057 -5084 1237 -909 4978 -2181 -1648 1168 3587 80 -3190 276 -5030 5942 -1524 -575 -2243 900000 900000 900000 -8532 2186 -8028 17713 900000 900000 9457 -10573 900000 -1364 7309 2219 5704 900000 -375 900000 15449 1447 -2374 900000 3424 900000 5634 -11271 900000 -5764 2549 -1012 900000 -6269 4480 900000 1875 900000 5756 7390 4630 900000 13376 11986 -1366 900000 13754 2201 900000 900000 13772 7219 900000 -1521 3761 8006 -3356 8337 -8972 6489 -400 5899 6311 3681 10734 -9241 8655 -3530 9823 4880 10147 5831 -2646 6661 9355 8304 -779 5030 -1954 -4226 5983 -3112 14638 -4525 8574 -16663 15957 1375 -244 9691 1496 7063 -3165 9789 -11420 1222 18118 13957 -5211 -9438 -3107 -9534 -5034 -20199 8498 -7933 6990 7084 -8028 -3127 -23059 1606 4839 -702 -2976 -4080 6026 10764 4742 1479 16320 -1566 17237 -9448 4272 6266 -2964 9360 -7636 2005 -1704 9635 -4797 -3881 2876 9109 212 -8798 740 -13581 13494 -3430 -1215 SS 20200925T111307.5Z 7573.467448 153 1 29.04 2 83.91 97.11 160.48 332.31 0.00 1 0.00 1 0 17 6.276e-01 5.482e-02 4.128e-01 3.768e-02 8.753373e-01 2.295917e-02 1.046955e-02 -6.000000e+00 3.773875e-01 227.85 -2.00 3.53 -2.00 322.01 0.00e+00 2.635105e-02 1.119326e-02 2.011694e-03 -6.000000e+00 2.200862e-02 284.66 -2.00 20.00 -2.00 321.49 0.00e+00 8.433 0.011 302.00 328.00 3 1.1439e+00 8.3231e-02 1.0178e-01 -6.0000e+00 9.4096e-01 1.6511e+00 9.8560e-02 7.8654e-02 -6.0000e+00 1.0318e+00 -1.9123e+00 6.2700e-02 2.2818e-02 -6.0000e+00 6.0616e-01 7.4453e-01 3.2409e-02 2.5994e-02 -6.0000e+00 2.5701e-01 1.4325e-05 -3.0863e-03 1.0820e-03 3.8129e-04 -6.0000e+00 1.8734e-02 -5.2419e-04 0.0000e+00 12 8 8 10 0 0 44.53 23.77 1.04 -0.00052 -0.02372 10 10 1 5 0 2903.170 26.83 20.00 23.77 15.3 996.97 59163 900000 900000 65288 30777 -88279 900000 -93342 152640 900000 900000 146714 -18022 900000 900000 900000 71444 29706 49107 900000 900000 -356 900000 67481 900000 900000 900000 -90251 900000 900000 900000 900000 900000 900000 -14076 313777 123217 91984 77661 900000 213135 55878 900000 20271 150690 99376 134174 43246 23718 86824 23137 257523 80649 84789 47190 77493 -15882 21705 52492 -8671 73047 2382 62190 -11551 52580 9085 32173 -11101 -2038 76045 23817 1960 4838 3549 15555 -14041 46930 -20885 12479 -28317 15561 24649 -18017 6346 26509 14016 6035 6351 292 8566 2971 10957 863 -4776 179 4514 -10529 -12952 6606 -5761 2017 -6154 -4469 -4443 -14610 2141 971 365 -438 1669 -3546 -2611 -849 -1336 1157 -9253 -962 -1405 722 2046 3022 11585 -1690 14159 -2795 416 332 2508 1456 -2181 180 2687 3068 -3160 1942 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-6.000000e+00 3.687498e-01 227.85 -2.00 3.53 -2.00 322.05 0.00e+00 1.040654e-02 9.239563e-03 6.347392e-03 -6.000000e+00 1.791706e-02 284.66 -2.00 20.00 -2.00 321.54 0.00e+00 8.009 0.010 302.00 328.00 3 1.3738e+00 6.3652e-02 9.4075e-02 -6.0000e+00 9.2941e-01 1.1086e+00 8.0302e-02 5.3807e-02 -6.0000e+00 1.0182e+00 -1.4511e+00 6.0523e-02 2.8458e-02 -6.0000e+00 5.9206e-01 5.8502e-01 2.9085e-02 9.7351e-03 -6.0000e+00 2.4773e-01 2.2305e-05 -1.4017e-03 8.0717e-04 2.2240e-04 -6.0000e+00 1.8366e-02 -7.2005e-04 0.0000e+00 12 8 8 10 0 0 64.10 23.76 0.74 -0.00072 -0.01125 13 13 1 5 0 2250.930 26.83 19.99 23.76 15.3 997.04 54813 900000 44358 900000 -7209 900000 -124929 900000 900000 900000 -62388 245672 900000 -116184 900000 -75154 900000 202699 900000 121799 -46661 258904 -65503 900000 -30695 48635 20378 -34949 900000 30044 1498 78398 900000 12335 900000 14632 900000 22404 28091 32571 145376 92620 17277 900000 -21059 178016 28763 68855 19464 21886 237090 27210 160286 -2947 34402 18823 3080 110891 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