File name: Pandora139s1_BlueHillMA_20210203_L2Fit_fout2c8d20200818p1-8.txt File generation date: 20260515T063253.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 139 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora139_OF_v3d20200209.txt Instrument calibration file used: Pandora139s1_CF_v8d20200818.txt Level 1 file used: Pandora139s1_BlueHillMA_20210203_L1_smca1c8d20200818p1-8.txt Full location name: Blue Hill, Department of Environmental Protection, MA Short location name: BlueHillMA Country of location: United States Location latitude [deg]: 42.2118 Location longitude [deg]: -71.1145 Location altitude [m]: 188 Local noon date: 20210203 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 240 382 Nominal wavelengths inside fitting window [nm]: 305.0623 305.2031 305.3438 305.4844 305.6251 305.7658 305.9064 306.0471 306.1877 306.3283 306.4689 306.6095 306.7501 306.8907 307.0312 307.1718 307.3123 307.4528 307.5933 307.7338 307.8743 308.0148 308.1552 308.2957 308.4361 308.5765 308.7170 308.8574 308.9977 309.1381 309.2785 309.4188 309.5592 309.6995 309.8398 309.9801 310.1204 310.2607 310.4009 310.5412 310.6814 310.8217 310.9619 311.1021 311.2423 311.3825 311.5226 311.6628 311.8029 311.9431 312.0832 312.2233 312.3634 312.5035 312.6435 312.7836 312.9236 313.0637 313.2037 313.3437 313.4837 313.6237 313.7637 313.9036 314.0436 314.1835 314.3234 314.4634 314.6033 314.7432 314.8830 315.0229 315.1628 315.3026 315.4424 315.5822 315.7220 315.8618 316.0016 316.1414 316.2811 316.4209 316.5606 316.7003 316.8401 316.9798 317.1194 317.2591 317.3988 317.5384 317.6781 317.8177 317.9573 318.0969 318.2365 318.3761 318.5156 318.6552 318.7947 318.9343 319.0738 319.2133 319.3528 319.4923 319.6317 319.7712 319.9106 320.0501 320.1895 320.3289 320.4683 320.6077 320.7470 320.8864 321.0258 321.1651 321.3044 321.4437 321.5830 321.7223 321.8616 322.0009 322.1401 322.2794 322.4186 322.5578 322.6970 322.8362 322.9754 323.1146 323.2537 323.3929 323.5320 323.6711 323.8102 323.9493 324.0884 324.2275 324.3665 324.5056 324.6446 324.7837 324.9227 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20210203T130021.6Z 7704.541917 419 1 19.21 2 80.12 122.95 67.99 234.68 0.00 1 0.00 1 0 17 5.232e-01 1.828e-02 3.670e-01 1.044e-02 7.814153e-01 5.850432e-03 8.699242e-03 -6.000000e+00 3.068121e-01 224.27 -2.00 3.53 -2.00 321.57 0.00e+00 6.819433e-03 2.857441e-03 1.202005e-03 -6.000000e+00 1.376178e-02 273.07 -2.00 20.00 -2.00 321.13 0.00e+00 5.575 0.003 302.00 328.00 3 2.0958e+00 1.9697e-02 6.8578e-02 -6.0000e+00 7.5838e-01 3.0765e-01 2.8299e-02 4.3570e-02 -6.0000e+00 8.2857e-01 -4.0319e-01 3.0917e-02 2.5193e-02 -6.0000e+00 4.8636e-01 1.6893e-01 1.4654e-02 1.1737e-02 -6.0000e+00 2.0553e-01 1.2191e-04 -9.4070e-04 2.9768e-04 1.4504e-04 -6.0000e+00 1.5092e-02 -3.4601e-04 0.0000e+00 12 9 9 12 1 1 96.94 23.64 0.30 -0.00035 -0.00741 10 5 1 5 0 1730.250 26.73 19.99 23.64 42.2 963.57 -147814 900000 -32947 -29694 900000 900000 900000 -221717 -21334 241269 -63777 -71505 -126838 900000 -180584 -68759 -83612 147884 60580 167824 900000 8867 5050 -116977 32836 -42824 65812 -79918 -33247 900000 -41524 171994 -32321 900000 -72769 4986 42183 -14323 86704 -25515 62677 21626 21132 -21412 35365 15844 68052 47197 -1578 18069 -16391 32957 477 25985 12554 23997 25107 -2156 9850 -8185 6613 -226 22892 15548 4127 5513 1196 16088 -1190 10851 -1504 5710 5731 2966 1485 1456 7191 -5500 -2339 -4076 4221 311 352 -3072 -2954 1061 -2942 1178 320 599 3833 -757 1146 -4090 1434 -5346 -318 -1454 -1002 452 -284 -431 -3044 -564 -2625 262 -1783 -162 -1277 807 834 553 579 -1480 633 -562 -352 -689 -365 2101 559 406 100 1869 -814 566 -64 1635 347 38 1230 -1225 67 72 578 -475 174 548 134 568 -1126 -254 -1023 -1503 900000 -335 -302 900000 900000 900000 -4295 -217 2454 -649 -727 -1865 900000 -7131 -1202 -1908 1504 616 1707 900000 110 66 -4881 377 -1018 669 -2629 -732 900000 -1313 1749 -1316 900000 -4435 150 981 -637 1869 -1742 2182 1162 1199 -1828 1854 1014 2840 2478 -136 1413 -1940 2794 59 2780 1607 2872 3039 -332 1322 -1271 926 -37 3448 2827 897 1192 269 3287 -314 2913 -497 1842 1830 917 426 377 1665 -1473 -684 -1440 1625 142 177 -1695 -1724 634 -1906 756 207 374 2196 -427 619 -2410 903 -4145 -273 -1443 -1082 492 -297 -408 -2695 -478 -2387 246 -1790 -172 -1498 1039 1193 848 905 -2324 940 -815 -508 -1037 -574 3335 891 623 148 2659 -1147 767 -86 2214 529 66 2307 -2495 143 160 1358 -1172 435 1383 339 1390 -2645 -559 -2185 SU 20210203T130226.5Z 7704.543362 421 1 50.96 2 79.80 123.34 68.30 235.11 0.00 1 0.00 1 0 17 5.305e-01 1.503e-02 2.526e-01 6.045e-03 7.711858e-01 3.362959e-03 8.713702e-03 -6.000000e+00 3.060858e-01 224.27 -2.00 3.53 -2.00 321.65 0.00e+00 5.994726e-03 1.657302e-03 2.357747e-03 -6.000000e+00 1.391368e-02 273.07 -2.00 20.00 -2.00 321.22 0.00e+00 5.415 0.003 302.00 328.00 3 1.7000e+00 1.1452e-02 6.7235e-02 -6.0000e+00 7.5827e-01 2.7624e-01 1.6446e-02 4.2914e-02 -6.0000e+00 8.2745e-01 -3.5947e-01 1.7924e-02 2.5610e-02 -6.0000e+00 4.8902e-01 1.4774e-01 8.4619e-03 1.0616e-02 -6.0000e+00 2.0709e-01 2.1370e-04 -1.0882e-03 1.7330e-04 1.5345e-04 -6.0000e+00 1.4870e-02 -1.0767e-05 0.0000e+00 12 9 8 11 8 0 95.82 23.63 0.23 -0.00001 -0.00819 55 10 1 5 0 926.350 26.73 20.00 23.63 42.0 963.72 -36879 -253240 900000 -193338 -219082 900000 -189925 -127450 -237143 900000 -216889 -61246 -43215 -29182 1929 -91244 30699 -97448 900000 -42999 78585 -48389 -9197 -65320 -41761 51485 9632 -28205 -60832 1946 5162 9016 14512 -11084 70596 -37755 20520 -12050 31919 23894 12437 12189 -4932 38575 16812 17642 12962 20039 6507 13034 23454 8306 25900 -658 34375 81 12517 7820 4247 8007 973 17352 4947 13772 6292 11043 485 2700 6722 2757 8085 2201 6549 -3403 2458 -1840 -3413 -4534 -5759 3595 -2336 -99 -1142 -367 -318 -768 162 -2584 1610 739 3667 -2801 -1845 -3203 -1654 -2215 -1749 773 -612 503 -1226 -738 -1601 -1908 -795 -2827 -555 -1337 -215 -194 1200 257 -134 211 -911 53 -364 713 -306 1220 300 345 1051 942 1495 92 1512 -370 402 387 115 140 -324 -256 -500 543 12 236 294 8 -341 -1041 -225 -217 -5716 900000 -2703 -3595 900000 -2445 -1024 -5572 900000 -4784 -380 -292 -226 14 -1894 244 -2685 900000 -821 514 -982 -136 -1693 -925 519 144 -581 -1695 34 106 214 380 -386 1179 -1609 566 -511 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