File name: Pandora139s1_BlueHillMA_20210312_L2Fit_fout2c8d20200818p1-8.txt File generation date: 20260515T063943.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 139 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora139_OF_v3d20200209.txt Instrument calibration file used: Pandora139s1_CF_v8d20200818.txt Level 1 file used: Pandora139s1_BlueHillMA_20210312_L1_smca1c8d20200818p1-8.txt Full location name: Blue Hill, Department of Environmental Protection, MA Short location name: BlueHillMA Country of location: United States Location latitude [deg]: 42.2118 Location longitude [deg]: -71.1145 Location altitude [m]: 188 Local noon date: 20210312 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 240 382 Nominal wavelengths inside fitting window [nm]: 305.0623 305.2031 305.3438 305.4844 305.6251 305.7658 305.9064 306.0471 306.1877 306.3283 306.4689 306.6095 306.7501 306.8907 307.0312 307.1718 307.3123 307.4528 307.5933 307.7338 307.8743 308.0148 308.1552 308.2957 308.4361 308.5765 308.7170 308.8574 308.9977 309.1381 309.2785 309.4188 309.5592 309.6995 309.8398 309.9801 310.1204 310.2607 310.4009 310.5412 310.6814 310.8217 310.9619 311.1021 311.2423 311.3825 311.5226 311.6628 311.8029 311.9431 312.0832 312.2233 312.3634 312.5035 312.6435 312.7836 312.9236 313.0637 313.2037 313.3437 313.4837 313.6237 313.7637 313.9036 314.0436 314.1835 314.3234 314.4634 314.6033 314.7432 314.8830 315.0229 315.1628 315.3026 315.4424 315.5822 315.7220 315.8618 316.0016 316.1414 316.2811 316.4209 316.5606 316.7003 316.8401 316.9798 317.1194 317.2591 317.3988 317.5384 317.6781 317.8177 317.9573 318.0969 318.2365 318.3761 318.5156 318.6552 318.7947 318.9343 319.0738 319.2133 319.3528 319.4923 319.6317 319.7712 319.9106 320.0501 320.1895 320.3289 320.4683 320.6077 320.7470 320.8864 321.0258 321.1651 321.3044 321.4437 321.5830 321.7223 321.8616 322.0009 322.1401 322.2794 322.4186 322.5578 322.6970 322.8362 322.9754 323.1146 323.2537 323.3929 323.5320 323.6711 323.8102 323.9493 324.0884 324.2275 324.3665 324.5056 324.6446 324.7837 324.9227 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20210312T122017.4Z 7741.514090 369 1 50.79 2 76.41 107.14 78.30 119.17 0.00 1 0.00 1 0 17 3.256e-01 1.336e-02 2.889e-01 9.305e-03 5.499048e-01 4.987296e-03 6.449036e-03 -6.000000e+00 1.884142e-01 225.80 -2.00 3.53 -2.00 320.78 0.00e+00 5.064248e-03 1.950084e-03 1.618224e-03 -6.000000e+00 8.715653e-03 274.83 -2.00 20.00 -2.00 320.28 0.00e+00 4.157 0.001 302.00 328.00 3 3.6169e+00 1.5322e-02 4.9831e-02 -6.0000e+00 4.6791e-01 7.6383e-02 1.9510e-02 2.9355e-02 -6.0000e+00 5.0966e-01 -3.4254e-02 1.9125e-02 1.7458e-02 -6.0000e+00 3.0284e-01 9.3231e-03 9.5888e-03 7.8093e-03 -6.0000e+00 1.2900e-01 1.2735e-04 -4.8646e-04 2.8321e-04 9.5575e-05 -6.0000e+00 9.3034e-03 1.5635e-03 0.0000e+00 12 8 8 10 0 0 99.98 23.87 0.35 0.00156 -0.00209 37 7 1 5 0 1372.520 26.94 20.00 23.87 43.0 971.07 -178825 900000 56983 900000 -120373 54735 -2587 -106087 29337 -15922 900000 -33237 4982 23713 106057 25433 65494 900000 -56980 131002 -44935 128365 -7573 89693 31853 -11932 -22303 -23558 59924 -19470 14765 -21953 13458 23158 -9140 15322 -2515 13018 24032 -8431 -1907 -3902 5202 -8543 -1581 -2658 16488 -15301 3513 -5276 6171 4145 -1281 9941 2009 3895 1616 1371 -3884 5731 8182 30 4364 1480 7597 292 -556 2779 4253 2932 -742 6040 -1948 171 576 2675 -4723 1132 -2358 -3482 194 -359 1839 -1594 -812 -2848 -132 1022 -1641 991 -139 -5 -1832 -445 -982 -1022 88 99 2641 -827 -153 -1957 -585 -4074 184 291 -1304 582 -791 599 -279 1379 -168 355 -326 -736 886 -520 -638 510 362 -93 1192 1059 -229 2055 -1082 1385 -839 1047 469 -669 -110 -669 -119 -218 392 266 766 -327 -271 -203 -756 -5192 900000 517 900000 -2375 496 -23 -2124 266 -169 900000 -478 62 313 962 469 946 900000 -2748 1300 -2115 1349 -268 1454 904 -513 -1059 -1114 1379 -944 609 -1440 729 1218 -621 838 -174 908 1808 -985 -233 -518 670 -1281 -227 -394 2103 -2659 532 -915 1045 791 -278 2086 476 939 408 346 -1010 1353 1961 8 1325 510 2574 104 -194 950 1562 1234 -356 2844 -983 81 251 1038 -1832 413 -972 -1679 104 -219 1193 -1131 -609 -2315 -110 872 -1432 818 -109 -4 -1297 -313 -759 -895 87 110 3113 -1016 -177 -2102 -572 -4123 191 318 -1524 706 -1048 860 -440 2239 -277 561 -490 -1060 1253 -772 -1001 829 592 -150 1829 1577 -331 2807 -1467 1868 -1266 1715 838 -1274 -217 -1386 -260 -501 918 635 1819 -765 -605 -430 -1557 SU 20210312T123917.3Z 7741.527283 468 1 10.51 2 73.08 110.64 75.31 122.67 0.00 1 0.00 1 0 17 8.438e-02 6.946e-03 7.207e-02 4.565e-03 4.610420e-01 2.331703e-03 5.404661e-03 -6.000000e+00 4.852283e-02 225.81 -2.00 3.53 -2.00 319.48 0.00e+00 1.287086e-03 6.289102e-04 5.238987e-04 -6.000000e+00 2.089583e-03 274.83 -2.00 20.00 -2.00 318.93 0.00e+00 3.384 0.001 302.00 328.00 3 2.8598e+00 6.5094e-03 4.0701e-02 -6.0000e+00 1.2028e-01 5.2306e-02 7.6273e-03 2.3870e-02 -6.0000e+00 1.3082e-01 -5.0707e-03 6.2208e-03 1.2201e-02 -6.0000e+00 7.7678e-02 -5.8781e-03 3.2871e-03 3.8425e-03 -6.0000e+00 3.2877e-02 6.2827e-04 -3.5107e-04 1.3335e-04 4.2869e-05 -6.0000e+00 2.3607e-03 1.6928e-03 0.0000e+00 12 9 1 12 1 1 99.95 23.85 0.13 0.00169 -0.00095 10 10 1 5 0 939.470 26.94 20.00 23.85 42.9 969.88 -54634 47897 -19639 15588 15440 -19299 25592 -3699 29173 3771 3591 -17695 -2424 145 2398 -9687 -14742 -3246 -17005 -1390 3911 -1839 4416 -1998 928 -12461 -4645 -9065 -2607 -1447 11341 4179 7738 -3474 -1630 -3672 -5674 580 497 3277 -1069 -645 436 -2746 2448 2130 1272 514 -913 -444 -230 450 -2156 2253 -603 2602 -322 1936 -651 -168 660 1473 1028 590 1849 267 -127 -38 1106 1285 -135 2041 88 612 -637 -840 -1588 -1364 -1694 -1093 -296 -1045 -706 -1816 -1113 -236 422 852 632 1090 88 653 -1325 -270 446 -21 264 486 942 -232 -341 -822 -1018 -792 -822 -1021 -737 -301 31 751 49 343 -5 164 -204 -225 28 148 -101 229 493 6 479 958 331 318 -1073 796 368 138 71 -523 -95 -448 -291 -27 -18 475 638 -57 -139 149 -973 -1539 633 -481 275 254 -418 404 -84 557 95 93 -598 -84 6 112 -571 -994 -212 -1331 -99 273 -136 320 -164 80 -1261 -442 -870 -229 -130 1013 451 897 -467 -210 -476 -816 92 94 706 -265 -169 118 -779 671 590 357 147 -268 -135 -75 159 -837 893 -257 1111 -144 852 -288 -73 294 700 537 334 1066 151 -70 -21 642 832 -95 1475 64 431 -427 -517 -917 -772 -1025 -737 -223 -869 -625 -1697 -1088 -241 447 924 687 1152 89 619 -1217 -245 426 -22 305 612 1245 -311 -439 -993 -1165 -910 -993 -1293 -967 -409 44 1134 78 565 -9 261 -308 -328 40 220 -157 368 798 9 748 1454 489 456 -1512 1113 550 221 119 -915 -170 -827 -557 -54 -37 969 1301 -116 -273 282 -1816 SU 20210312T124111.1Z 7741.528600 470 1 14.12 2 72.75 111.00 75.02 123.02 0.00 1 0.00 1 0 17 9.962e-02 7.957e-03 7.811e-02 5.415e-03 4.504181e-01 2.761965e-03 5.305735e-03 -6.000000e+00 5.727758e-02 225.81 -2.00 3.53 -2.00 319.48 0.00e+00 3.141151e-04 7.434896e-04 3.089954e-04 -6.000000e+00 2.466932e-03 274.83 -2.00 20.00 -2.00 318.94 0.00e+00 3.324 0.001 302.00 328.00 3 3.4274e+00 7.7205e-03 3.9948e-02 -6.0000e+00 1.4198e-01 6.0852e-02 9.0387e-03 2.3451e-02 -6.0000e+00 1.5443e-01 -1.8057e-02 7.2928e-03 1.1725e-02 -6.0000e+00 9.1698e-02 2.0558e-03 3.8465e-03 3.4500e-03 -6.0000e+00 3.8803e-02 3.8266e-04 -3.0599e-04 1.5925e-04 3.9210e-05 -6.0000e+00 2.7872e-03 2.8490e-03 0.0000e+00 12 9 1 12 1 1 99.95 23.84 0.24 0.00285 0.00055 7 5 1 5 0 1742.680 26.83 20.01 23.84 43.0 969.85 62526 -7725 -23316 -21969 -22657 -16201 -37573 -50042 -967 11335 -41145 26015 -13971 5511 -9353 -15433 -2594 956 829 -2818 1720 -13632 10507 -1646 4687 1100 -2031 380 -5840 -873 1008 5511 -10261 1680 6734 -2103 -1657 -3630 3552 -3650 -3209 -1414 1228 1047 2428 1505 -2183 385 -4508 -399 2950 -105 2512 2449 1947 -2662 1351 1674 963 1203 318 1420 1458 3265 431 -105 -760 -18 -672 1321 -65 53 945 1632 1956 -201 -1277 -1519 -1629 -1396 -107 -703 -1504 -1491 -1153 -1077 566 1056 490 1048 -3 65 -446 -527 -810 462 -437 774 512 885 -544 -1164 -733 -283 -624 -798 -1073 -811 606 -35 604 137 736 -73 -733 -355 -177 -593 -379 183 -393 -7 543 230 251 1212 345 328 917 548 494 -569 -6 18 507 3 -170 309 381 224 -357 -375 -1261 671 -172 -624 -559 -540 -359 -1074 -1804 -25 282 -1680 632 -562 222 -505 -1002 -162 62 57 -209 126 -1156 743 -140 403 103 -196 35 -544 -80 100 594 -1419 218 807 -271 -231 -604 664 -852 -828 -380 334 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