File name: Pandora139s1_BlueHillMA_20210421_L2Fit_fout2c8d20200818p1-8.txt File generation date: 20260515T064717.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 139 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora139_OF_v3d20200209.txt Instrument calibration file used: Pandora139s1_CF_v8d20200818.txt Level 1 file used: Pandora139s1_BlueHillMA_20210421_L1_smca1c8d20200818p1-8.txt Full location name: Blue Hill, Department of Environmental Protection, MA Short location name: BlueHillMA Country of location: United States Location latitude [deg]: 42.2118 Location longitude [deg]: -71.1145 Location altitude [m]: 188 Local noon date: 20210421 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 240 382 Nominal wavelengths inside fitting window [nm]: 305.0623 305.2031 305.3438 305.4844 305.6251 305.7658 305.9064 306.0471 306.1877 306.3283 306.4689 306.6095 306.7501 306.8907 307.0312 307.1718 307.3123 307.4528 307.5933 307.7338 307.8743 308.0148 308.1552 308.2957 308.4361 308.5765 308.7170 308.8574 308.9977 309.1381 309.2785 309.4188 309.5592 309.6995 309.8398 309.9801 310.1204 310.2607 310.4009 310.5412 310.6814 310.8217 310.9619 311.1021 311.2423 311.3825 311.5226 311.6628 311.8029 311.9431 312.0832 312.2233 312.3634 312.5035 312.6435 312.7836 312.9236 313.0637 313.2037 313.3437 313.4837 313.6237 313.7637 313.9036 314.0436 314.1835 314.3234 314.4634 314.6033 314.7432 314.8830 315.0229 315.1628 315.3026 315.4424 315.5822 315.7220 315.8618 316.0016 316.1414 316.2811 316.4209 316.5606 316.7003 316.8401 316.9798 317.1194 317.2591 317.3988 317.5384 317.6781 317.8177 317.9573 318.0969 318.2365 318.3761 318.5156 318.6552 318.7947 318.9343 319.0738 319.2133 319.3528 319.4923 319.6317 319.7712 319.9106 320.0501 320.1895 320.3289 320.4683 320.6077 320.7470 320.8864 321.0258 321.1651 321.3044 321.4437 321.5830 321.7223 321.8616 322.0009 322.1401 322.2794 322.4186 322.5578 322.6970 322.8362 322.9754 323.1146 323.2537 323.3929 323.5320 323.6711 323.8102 323.9493 324.0884 324.2275 324.3665 324.5056 324.6446 324.7837 324.9227 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20210421T104400.9Z 7781.447233 201 1 51.79 2 81.81 81.18 115.40 339.84 0.00 1 0.00 1 0 25 6.577e-01 4.778e-02 4.140e-01 3.192e-02 9.471629e-01 2.000639e-02 1.055580e-02 -6.000000e+00 4.104510e-01 228.84 -2.00 3.53 -2.00 322.19 0.00e+00 2.021632e-03 9.765318e-03 3.442559e-03 -6.000000e+00 2.269233e-02 279.11 -2.00 20.00 -2.00 321.73 0.00e+00 6.581 0.005 302.00 328.00 3 2.4478e+00 7.3669e-02 8.5136e-02 -6.0000e+00 1.0213e+00 1.3493e+00 8.9560e-02 5.8301e-02 -6.0000e+00 1.1169e+00 -1.8550e+00 6.3549e-02 2.6573e-02 -6.0000e+00 6.5556e-01 7.5473e-01 3.2008e-02 8.2559e-03 -6.0000e+00 2.7894e-01 2.3566e-05 -2.0471e-03 9.4123e-04 1.2333e-04 -6.0000e+00 2.0153e-02 6.1341e-03 0.0000e+00 12 8 8 10 0 0 99.89 23.58 0.59 0.00613 -0.00925 19 3 1 5 0 2725.050 26.73 20.00 23.58 50.9 954.93 900000 -65370 900000 15758 900000 900000 8569 900000 -50825 900000 -83623 900000 900000 49934 900000 7777 294370 -32315 900000 -2688 900000 900000 52200 900000 -49936 900000 8741 900000 -42554 900000 900000 59906 900000 15779 900000 253852 900000 -37104 143908 8272 900000 900000 8106 51478 111125 900000 -28285 134015 900000 120960 156003 168841 31249 62431 339396 30458 132497 -13922 2925 32766 -28120 900000 10864 18413 37011 101666 56133 96260 30505 22323 55341 35901 41450 -5427 20283 19519 21276 4879 -784 17795 -13168 1049 1123 9279 -13165 20316 9577 -8366 7757 -7442 11086 1348 4702 -7620 -8805 -968 -6702 755 -11694 7550 -5052 5741 -8740 -3750 -3627 -7795 11974 -13806 2608 -5799 3759 -143 1574 -2716 -277 2455 -5635 3757 -5907 4714 -379 1670 6788 -1858 7984 -29 7508 -2419 4362 1785 1508 611 -3834 1937 -494 1746 -1297 1813 1551 -323 -722 -3761 -1363 900000 -6229 900000 596 900000 900000 265 900000 -2516 900000 -5349 900000 900000 1546 900000 424 9114 -2748 900000 -167 900000 900000 1631 900000 -4084 900000 386 900000 -2601 900000 900000 2016 900000 898 900000 7859 900000 -3388 4455 651 900000 900000 712 2980 3604 900000 -3183 4149 900000 3923 4830 5227 2957 4733 10508 3266 5631 -2159 368 2963 -4371 900000 1420 2517 4559 7017 5864 7294 4566 4049 8069 6404 6833 -1270 3377 2920 2940 807 -155 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2.1096e-02 3.3152e-03 0.0000e+00 12 8 8 10 0 0 99.91 23.57 0.57 0.00332 -0.00929 20 4 1 5 0 2588.560 26.62 20.00 23.57 50.9 955.22 70187 900000 900000 900000 900000 900000 -75720 900000 -77691 900000 -182564 900000 -94499 -98624 -86484 -125409 900000 -29770 900000 -19546 253503 900000 -41397 900000 39331 19311 116599 900000 -8780 -112352 900000 307269 900000 900000 900000 -46955 36200 900000 25893 174088 96232 58504 -21669 29485 -37174 244735 104571 11753 66923 900000 41443 153804 137773 68830 35537 -12499 63391 52182 126107 147051 -354 12150 3911 10237 26213 90629 9371 61359 60194 15124 15301 3260 17994 14319 2034 -17794 5954 31792 38662 17455 -1803 31517 -7273 5858 4948 7674 -4601 -5728 7946 1634 7229 -9930 -655 -1793 -93 -5552 473 -2067 -2446 -4138 -3133 -2177 -8319 -1062 -267 -7126 -5100 -146 -48 -4733 1193 -12 899 8 -2903 295 -1497 -2834 664 6312 -492 2402 4275 2888 2666 431 1636 -322 4045 -48 -1015 -1008 -407 1101 -1015 697 134 1908 -585 839 -146 -1191 -3092 1698 900000 900000 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6.748812e-03 6.180988e-03 2.425671e-03 -6.000000e+00 1.995551e-02 279.11 -2.00 20.00 -2.00 321.64 0.00e+00 6.023 0.004 302.00 328.00 3 2.4975e+00 4.2201e-02 7.6001e-02 -6.0000e+00 1.0254e+00 7.3886e-01 5.6517e-02 4.8681e-02 -6.0000e+00 1.1214e+00 -1.1595e+00 4.9767e-02 2.7038e-02 -6.0000e+00 6.5505e-01 4.8783e-01 2.3142e-02 1.0412e-02 -6.0000e+00 2.7031e-01 4.8149e-05 -1.6247e-03 5.4858e-04 1.6660e-04 -6.0000e+00 1.9833e-02 5.2076e-03 0.0000e+00 12 8 8 10 0 0 99.97 23.57 0.38 0.00521 -0.00700 27 5 1 5 0 1852.300 26.62 19.99 23.57 51.0 955.43 -34641 81756 243710 -11848 -26911 -125105 900000 -205083 900000 -114154 900000 -92488 -140040 900000 -120739 361166 -26367 900000 45416 900000 152696 67950 14138 -100680 900000 -73290 900000 127210 3195 55128 5729 900000 -3919 900000 157490 43824 201712 90968 136148 51951 122600 11374 93504 5672 45642 142021 143219 61306 11579 91395 8537 89731 5923 70336 7027 19149 37056 33421 18546 7532 64248 12197 43654 39311 51015 2261 20141 8332 12066 16534 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