File name: Pandora139s1_BlueHillMA_20210508_L2Fit_fout2c8d20200818p1-8.txt File generation date: 20260515T065159.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 139 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora139_OF_v3d20200209.txt Instrument calibration file used: Pandora139s1_CF_v8d20200818.txt Level 1 file used: Pandora139s1_BlueHillMA_20210508_L1_smca1c8d20200818p1-8.txt Full location name: Blue Hill, Department of Environmental Protection, MA Short location name: BlueHillMA Country of location: United States Location latitude [deg]: 42.2118 Location longitude [deg]: -71.1145 Location altitude [m]: 188 Local noon date: 20210508 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 240 382 Nominal wavelengths inside fitting window [nm]: 305.0623 305.2031 305.3438 305.4844 305.6251 305.7658 305.9064 306.0471 306.1877 306.3283 306.4689 306.6095 306.7501 306.8907 307.0312 307.1718 307.3123 307.4528 307.5933 307.7338 307.8743 308.0148 308.1552 308.2957 308.4361 308.5765 308.7170 308.8574 308.9977 309.1381 309.2785 309.4188 309.5592 309.6995 309.8398 309.9801 310.1204 310.2607 310.4009 310.5412 310.6814 310.8217 310.9619 311.1021 311.2423 311.3825 311.5226 311.6628 311.8029 311.9431 312.0832 312.2233 312.3634 312.5035 312.6435 312.7836 312.9236 313.0637 313.2037 313.3437 313.4837 313.6237 313.7637 313.9036 314.0436 314.1835 314.3234 314.4634 314.6033 314.7432 314.8830 315.0229 315.1628 315.3026 315.4424 315.5822 315.7220 315.8618 316.0016 316.1414 316.2811 316.4209 316.5606 316.7003 316.8401 316.9798 317.1194 317.2591 317.3988 317.5384 317.6781 317.8177 317.9573 318.0969 318.2365 318.3761 318.5156 318.6552 318.7947 318.9343 319.0738 319.2133 319.3528 319.4923 319.6317 319.7712 319.9106 320.0501 320.1895 320.3289 320.4683 320.6077 320.7470 320.8864 321.0258 321.1651 321.3044 321.4437 321.5830 321.7223 321.8616 322.0009 322.1401 322.2794 322.4186 322.5578 322.6970 322.8362 322.9754 323.1146 323.2537 323.3929 323.5320 323.6711 323.8102 323.9493 324.0884 324.2275 324.3665 324.5056 324.6446 324.7837 324.9227 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20210508T110532.9Z 7798.462186 454 1 1.81 2 74.06 80.99 62.49 118.38 0.00 1 0.00 1 0 17 3.578e-01 1.556e-02 2.347e-01 1.213e-02 5.843331e-01 6.458398e-03 6.762294e-03 -6.000000e+00 2.110412e-01 230.32 -2.00 3.53 -2.00 319.85 0.00e+00 2.098608e-03 2.028845e-03 1.095788e-03 -6.000000e+00 9.614002e-03 281.03 -2.00 20.00 -2.00 319.23 0.00e+00 3.580 0.001 302.00 328.00 3 2.2865e+00 1.8624e-02 4.7041e-02 -6.0000e+00 5.2860e-01 5.8209e-02 2.2442e-02 3.1049e-02 -6.0000e+00 5.7338e-01 -6.8641e-02 1.9454e-02 1.5965e-02 -6.0000e+00 3.3828e-01 2.8906e-02 1.0076e-02 5.1516e-03 -6.0000e+00 1.4390e-01 7.8248e-04 -2.6641e-04 3.4212e-04 5.9013e-05 -6.0000e+00 1.0271e-02 2.4947e-03 0.0000e+00 12 9 9 12 1 1 999.00 23.55 0.24 0.00249 0.00049 1 11 1 5 0 815.640 26.62 20.00 23.55 50.2 954.19 900000 -98428 900000 -118802 120529 -61909 900000 242395 -32602 900000 -59818 135211 -73160 900000 -32382 87937 83575 -54050 99164 -37095 35579 -10949 22498 -37657 -4492 -15020 -13552 39560 -32150 9205 -551 10620 -7149 6737 -2762 -18630 10973 -7341 25480 -8241 10204 -3374 -3193 -409 -2272 10053 1887 6081 -4081 8446 -1450 -3117 1895 3014 6859 988 5652 950 2395 -905 2713 4229 1301 6171 1441 1714 -3519 -3434 -1261 2226 1908 2189 1888 -1176 3281 -4167 890 -4526 -2692 -862 224 -1419 -1917 -1993 -2061 -1533 16 1182 1208 2260 845 -2104 759 -3803 -892 -437 379 1144 112 256 -132 778 -3141 -1537 121 -537 -657 -1967 724 -167 2119 337 1885 -1899 455 -326 166 -1216 762 956 -354 406 292 1445 665 557 -799 -744 1953 -234 198 -1031 -190 -518 -102 1216 113 355 -247 -595 -24 73 -826 900000 -2282 900000 -3414 1424 -996 900000 2864 -549 900000 -1441 1598 -2661 900000 -1228 1342 1468 -3482 1768 -2317 1203 -563 898 -2750 -263 -1015 -914 1633 -2473 520 -39 789 -699 617 -268 -2074 1023 -943 2929 -1490 1745 -693 -684 -87 -501 2025 415 1319 -998 1956 -397 -952 599 1008 2335 366 2064 360 881 -338 1014 1681 585 2897 728 852 -1787 -1772 -687 1311 1216 1443 1244 -763 1931 -2399 465 -2465 -1556 -553 160 -1123 -1625 -1769 -1916 -1485 16 1191 1219 2211 797 -1925 660 -3436 -844 -452 428 1400 145 333 -167 915 -3583 -1736 141 -656 -828 -2608 993 -245 3256 540 2995 -3018 687 -479 242 -1842 1180 1524 -569 638 450 2160 974 796 -1125 -1061 2914 -379 338 -1830 -344 -972 -198 2414 229 726 -506 -1202 -48 138 -1535 SU 20210508T110745.4Z 7798.463719 456 1 50.70 2 73.66 81.35 62.14 118.84 0.00 1 0.00 1 0 17 1.655e-01 5.633e-03 4.793e-02 1.591e-03 5.757345e-01 8.449484e-04 6.540494e-03 -6.000000e+00 9.680405e-02 230.32 -2.00 3.53 -2.00 320.56 0.00e+00 6.824890e-04 3.265313e-04 6.482361e-04 -6.000000e+00 4.205297e-03 281.03 -2.00 20.00 -2.00 319.97 0.00e+00 3.496 0.001 302.00 328.00 3 1.5670e+00 2.5839e-03 4.6225e-02 -6.0000e+00 2.4203e-01 3.9414e-02 3.2914e-03 3.0907e-02 -6.0000e+00 2.6210e-01 -1.5144e-02 3.1367e-03 1.5791e-02 -6.0000e+00 1.5564e-01 -4.1952e-03 1.5694e-03 4.7313e-03 -6.0000e+00 6.5603e-02 1.7592e-03 -3.8220e-04 4.6302e-05 5.5246e-05 -6.0000e+00 4.6376e-03 3.2005e-03 0.0000e+00 10 0 0 10 0 0 98.89 23.56 0.20 0.00320 0.00033 180 33 1 5 0 281.640 26.62 19.99 23.56 50.2 954.40 -58529 -48174 -62256 -42429 -73115 -54937 -70863 -42567 -55043 -27264 -39746 -53631 -29742 -19960 -16858 -12823 -3982 -3008 -6496 -350 -13365 2089 -8816 -1459 -1050 -1378 744 -9848 -5271 -7741 19 -2108 920 -2310 -3760 -5526 -4902 -1109 -988 1684 179 142 -310 -208 157 -813 -299 -1981 -957 -1777 -259 588 2174 1900 1176 1500 1198 513 -128 467 982 1583 1970 2799 1989 35 -575 -1345 279 1119 1171 1366 819 389 208 -577 -1461 -2059 -1342 -700 -684 -723 -1526 -1765 -1088 -704 241 694 932 1065 803 337 -488 -494 -229 38 0 1017 752 7 -184 -1009 -1479 -729 -506 -908 -723 -622 -180 277 808 636 474 166 -465 -526 -408 -171 77 255 -15 164 385 493 212 306 -344 -132 442 256 96 -175 -490 -272 -72 67 -92 381 391 192 -48 -151 -614 -512 -442 -703 -383 -835 -519 -860 -450 -753 -308 -538 -860 -462 -354 -358 -308 -98 -81 -181 -10 -436 64 -293 -49 -39 -54 29 -414 -208 -331 1 -116 56 -155 -250 -372 -361 -87 -96 189 23 20 -45 -31 24 -126 -47 -322 -159 -317 -50 125 500 474 313 416 343 148 -36 130 279 488 680 1063 796 14 -224 -538 120 547 589 719 431 209 103 -259 -613 -864 -612 -369 -419 -469 -1092 -1345 -878 -604 216 636 851 938 662 259 -385 -367 -186 35 0 1208 972 9 -228 -1138 -1542 -755 -558 -1066 -890 -813 -254 402 1276 1059 790 266 -706 -760 -625 -254 122 418 -25 262 592 779 322 445 -483 -189 693 421 172 -334 -977 -570 -150 148 -208 874 899 429 -102 -321 -1265 SU 20210508T110933.6Z 7798.464972 458 1 51.18 2 73.33 81.63 61.84 119.21 0.00 1 0.00 1 0 17 1.699e-01 5.746e-03 4.658e-02 1.689e-03 5.660965e-01 8.934635e-04 6.445614e-03 -6.000000e+00 9.933384e-02 230.32 -2.00 3.53 -2.00 320.51 0.00e+00 8.974308e-04 3.408655e-04 6.825146e-04 -6.000000e+00 4.315184e-03 281.03 -2.00 20.00 -2.00 319.91 0.00e+00 3.431 0.001 302.00 328.00 3 1.7756e+00 2.7297e-03 4.5405e-02 -6.0000e+00 2.4836e-01 3.8106e-02 3.4603e-03 3.0361e-02 -6.0000e+00 2.6895e-01 -1.1590e-02 3.2644e-03 1.5507e-02 -6.0000e+00 1.5970e-01 -5.2682e-03 1.6350e-03 4.7064e-03 -6.0000e+00 6.7318e-02 1.5318e-03 -2.8722e-04 4.9360e-05 5.4817e-05 -6.0000e+00 4.7588e-03 3.1794e-03 0.0000e+00 10 0 0 10 0 0 91.69 23.57 0.19 0.00318 0.00102 148 27 1 5 0 343.470 26.62 19.99 23.57 50.2 954.86 -73751 -47378 -50899 -62658 -68617 -62981 -56765 -49932 -46183 -57940 -33424 -42639 -20375 -23724 -14649 -46 -17634 -6883 -16877 706 -4462 49 -1457 -3213 -4820 1648 -1266 -10402 -496 -4708 -5744 1621 2719 1803 -5597 -2098 -2825 -817 -3356 -711 96 -852 -99 -976 1280 -102 -51 -1256 -2309 -1077 1510 2188 705 1576 1347 922 958 573 682 160 1342 1689 2540 2554 2055 526 -470 -1633 -102 1410 1084 995 1016 1001 98 -791 -1551 -2245 -1682 -1408 -674 -1089 -1721 -1830 -998 -432 19 648 883 1100 910 380 -571 -352 -176 -39 178 789 590 77 -227 -991 -1316 -545 -560 -757 -841 -545 -128 560 694 655 463 155 -422 -611 -332 -283 110 402 87 74 363 384 173 198 -463 30 244 279 213 -264 -458 -244 -53 57 -67 401 452 194 -66 -248 -587 -817 -468 -556 -750 -811 -698 -646 -613 -622 -875 -455 -655 -308 -466 -324 -1 -489 -188 -552 20 -141 1 -47 -116 -194 66 -53 -461 -20 -205 -291 90 170 121 -394 -142 -212 -67 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