File name: Pandora139s1_BlueHillMA_20210527_L2Fit_fout2c8d20200818p1-8.txt File generation date: 20260515T065511.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 139 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora139_OF_v3d20200209.txt Instrument calibration file used: Pandora139s1_CF_v8d20200818.txt Level 1 file used: Pandora139s1_BlueHillMA_20210527_L1_smca1c8d20200818p1-8.txt Full location name: Blue Hill, Department of Environmental Protection, MA Short location name: BlueHillMA Country of location: United States Location latitude [deg]: 42.2118 Location longitude [deg]: -71.1145 Location altitude [m]: 188 Local noon date: 20210527 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 240 382 Nominal wavelengths inside fitting window [nm]: 305.0623 305.2031 305.3438 305.4844 305.6251 305.7658 305.9064 306.0471 306.1877 306.3283 306.4689 306.6095 306.7501 306.8907 307.0312 307.1718 307.3123 307.4528 307.5933 307.7338 307.8743 308.0148 308.1552 308.2957 308.4361 308.5765 308.7170 308.8574 308.9977 309.1381 309.2785 309.4188 309.5592 309.6995 309.8398 309.9801 310.1204 310.2607 310.4009 310.5412 310.6814 310.8217 310.9619 311.1021 311.2423 311.3825 311.5226 311.6628 311.8029 311.9431 312.0832 312.2233 312.3634 312.5035 312.6435 312.7836 312.9236 313.0637 313.2037 313.3437 313.4837 313.6237 313.7637 313.9036 314.0436 314.1835 314.3234 314.4634 314.6033 314.7432 314.8830 315.0229 315.1628 315.3026 315.4424 315.5822 315.7220 315.8618 316.0016 316.1414 316.2811 316.4209 316.5606 316.7003 316.8401 316.9798 317.1194 317.2591 317.3988 317.5384 317.6781 317.8177 317.9573 318.0969 318.2365 318.3761 318.5156 318.6552 318.7947 318.9343 319.0738 319.2133 319.3528 319.4923 319.6317 319.7712 319.9106 320.0501 320.1895 320.3289 320.4683 320.6077 320.7470 320.8864 321.0258 321.1651 321.3044 321.4437 321.5830 321.7223 321.8616 322.0009 322.1401 322.2794 322.4186 322.5578 322.6970 322.8362 322.9754 323.1146 323.2537 323.3929 323.5320 323.6711 323.8102 323.9493 324.0884 324.2275 324.3665 324.5056 324.6446 324.7837 324.9227 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20210527T110426.0Z 7817.461412 615 1 50.08 2 71.75 77.35 100.41 246.05 0.00 1 0.00 1 0 17 2.105e-01 1.073e-02 1.513e-01 7.351e-03 4.059213e-01 3.848681e-03 4.734616e-03 -6.000000e+00 1.238859e-01 231.68 -2.00 3.53 -2.00 319.85 0.00e+00 1.573319e-04 1.148388e-03 5.030900e-04 -6.000000e+00 5.393212e-03 283.05 -2.00 20.00 -2.00 319.15 0.00e+00 3.151 0.001 302.00 328.00 3 4.5250e+00 1.1183e-02 3.7811e-02 -6.0000e+00 3.1058e-01 2.2851e-02 1.3307e-02 2.1885e-02 -6.0000e+00 3.3572e-01 9.8945e-03 1.0569e-02 1.0764e-02 -6.0000e+00 1.9937e-01 -1.0416e-02 5.4382e-03 3.0195e-03 -6.0000e+00 8.4092e-02 1.5896e-04 -3.9972e-04 2.2574e-04 3.4934e-05 -6.0000e+00 5.8967e-03 -5.9767e-03 0.0000e+00 12 8 8 10 0 0 99.91 24.19 0.31 -0.00598 -0.00898 18 3 1 5 0 2781.980 27.15 19.99 24.19 49.7 991.70 -53719 137261 -59533 141600 -41301 -25052 31301 -39894 32692 -14247 -30335 -28728 -30992 -4664 21931 26376 -18760 32751 756 29562 31387 11634 15658 -2721 -3553 7970 -9640 -3032 -14177 1262 7992 -8769 6535 1601 1090 3708 -10769 12639 -4117 9337 -691 1528 -2343 3222 2852 -1919 -3362 -1052 1043 -3037 -525 2390 4572 -2522 2114 1147 1022 -1431 -2405 1393 -406 2841 1679 3236 -687 501 -1297 -4921 2251 751 -415 976 427 1698 1113 691 -1965 -268 -1919 -3747 -3180 -1247 -1455 -1872 519 -149 2663 865 1914 553 31 506 -762 -679 279 -577 29 502 906 342 464 -1757 -1346 -2162 -954 450 -1310 -1258 -232 27 591 1372 993 173 -617 -1513 -850 -446 -20 1062 384 99 373 923 522 -55 -1187 -588 570 700 65 198 -88 -475 620 334 -855 -29 261 357 -136 -407 -248 -1600 984 -2183 1015 -1165 -597 487 -1302 630 -441 -1113 -1102 -1388 -195 845 1098 -1264 1478 48 1516 1636 731 981 -216 -304 644 -926 -264 -1318 103 667 -961 684 184 122 400 -1441 1592 -730 1712 -155 358 -593 788 705 -501 -889 -272 266 -831 -150 726 1466 -923 775 439 402 -578 -967 533 -163 1191 783 1614 -365 252 -631 -2459 1127 431 -264 647 286 1082 667 377 -1011 -131 -1006 -2265 -2177 -934 -1181 -1614 465 -144 2630 900 1978 565 30 450 -643 -561 243 -561 31 603 1165 445 571 -2043 -1464 -2386 -1111 547 -1696 -1707 -332 41 963 2291 1649 276 -931 -2187 -1205 -654 -31 1713 633 163 593 1416 771 -78 -1648 -813 832 1107 110 349 -160 -903 1227 696 -1849 -64 574 773 -284 -822 -486 SU 20210527T111133.7Z 7817.466362 638 1 51.39 2 70.46 78.46 101.57 247.10 0.00 1 0.00 1 0 17 1.696e-01 1.288e-02 1.477e-01 1.122e-02 3.902275e-01 5.881363e-03 4.545849e-03 -6.000000e+00 9.979270e-02 231.68 -2.00 3.53 -2.00 319.70 0.00e+00 5.850294e-04 1.657281e-03 4.456601e-04 -6.000000e+00 4.401166e-03 283.05 -2.00 20.00 -2.00 318.99 0.00e+00 2.956 0.000 302.00 328.00 3 5.0221e+00 1.6910e-02 3.5719e-02 -6.0000e+00 2.5019e-01 3.9960e-02 1.9899e-02 2.0858e-02 -6.0000e+00 2.7043e-01 3.8354e-02 1.5261e-02 1.0262e-02 -6.0000e+00 1.6070e-01 -2.9988e-02 7.8918e-03 2.8969e-03 -6.0000e+00 6.8025e-02 1.1612e-04 -7.6183e-04 3.4599e-04 3.3330e-05 -6.0000e+00 4.7573e-03 -5.9633e-03 0.0000e+00 12 8 8 10 0 0 99.96 24.17 0.27 -0.00596 -0.01169 30 5 1 5 0 1712.860 27.15 20.00 24.17 49.9 991.41 -32401 134483 900000 38251 -30827 -34755 -54636 -44121 32677 -16731 18854 -25932 7561 -38174 -2609 15192 -16578 -16898 44801 21594 14746 -610 17319 9966 29959 127 9437 -7722 5799 30126 1023 21182 -8330 15563 -7098 -12930 -5984 -1777 1190 7241 -631 -2629 -3153 2902 3109 -463 -646 -4519 -3986 -2077 3384 3599 349 2692 1675 632 1987 -4918 30 -2156 2384 1376 3330 1275 -199 -554 -2731 1061 -2602 251 1624 1652 -1916 1275 1448 2021 -1301 -3390 -2485 252 -755 -1774 401 -1395 -3240 75 830 2773 1593 1755 930 217 1043 -1203 -1742 -303 -1446 -467 1300 471 259 -1556 -3038 -1056 -105 -920 -1658 90 369 1501 788 1056 782 472 -26 -1822 -1752 -950 -348 898 1037 1407 -337 -79 332 -499 -2110 -393 484 -293 182 157 -160 -467 499 312 290 1115 -397 188 13 -154 -1125 -975 1471 900000 724 -969 -1100 -2162 -1792 779 -636 546 -1154 288 -2507 -147 823 -1266 -1371 2265 1389 1039 -49 1235 806 2172 13 866 -799 511 2174 103 1993 -1119 1766 -955 -1811 -847 -282 219 1474 -153 -692 -868 769 828 -129 -180 -1301 -1149 -603 995 1152 123 990 652 257 817 -2161 12 -899 982 614 1598 675 -110 -294 -1400 519 -1408 149 1046 1119 -1349 841 894 1125 -683 -1753 -1339 149 -513 -1358 324 -1214 -3048 73 849 2880 1680 1800 902 195 871 -1001 -1544 -294 -1590 -566 1664 614 321 -1806 -3343 -1150 -121 -1136 -2153 121 524 2269 1281 1774 1298 748 -39 -2609 -2470 -1376 -530 1435 1692 2267 -535 -122 487 -706 -2906 -532 691 -458 303 273 -286 -873 975 646 618 2399 -874 405 27 -308 -2197 SU 20210527T111650.4Z 7817.470028 652 1 50.77 2 69.50 79.27 102.44 247.87 0.00 1 0.00 1 0 17 4.225e-02 6.860e-03 2.886e-02 2.863e-03 3.651983e-01 1.487465e-03 4.288666e-03 -6.000000e+00 2.485975e-02 231.68 -2.00 3.53 -2.00 319.35 0.00e+00 7.306338e-04 3.797240e-04 2.202883e-04 -6.000000e+00 1.082182e-03 283.06 -2.00 20.00 -2.00 318.63 0.00e+00 2.826 0.000 302.00 328.00 3 3.5648e+00 4.1940e-03 3.3882e-02 -6.0000e+00 6.2323e-02 8.8634e-03 4.8694e-03 1.9457e-02 -6.0000e+00 6.7367e-02 1.3686e-02 3.5806e-03 9.5466e-03 -6.0000e+00 4.0007e-02 -1.2433e-02 1.8631e-03 2.7380e-03 -6.0000e+00 1.6875e-02 5.9917e-04 -5.9748e-04 8.7111e-05 3.0743e-05 -6.0000e+00 1.1832e-03 -6.3006e-03 0.0000e+00 11 8 0 10 0 0 99.97 24.16 0.19 -0.00630 -0.01079 41 7 1 5 0 1238.010 27.15 20.00 24.16 49.8 990.85 -5971 -6502 -12874 22882 -13051 5359 -4415 5747 -16908 -16694 -18065 -5249 -8678 1145 6343 -3560 904 -1295 -7438 -980 -4621 4760 4913 2228 1277 1142 -4403 -4858 818 -3493 1584 -755 2317 3431 -885 -2995 -5279 -4314 -862 2201 403 1075 -206 24 307 -1285 -655 -859 719 -2043 1724 -934 1896 878 1109 908 -6 1059 355 328 450 1720 1340 2703 829 -204 -876 -2268 644 1087 921 1041 309 812 147 -1439 -1435 -1925 -1901 -674 -1442 -1094 -1487 -2724 -1119 53 813 712 1040 875 1022 -94 -895 -531 -463 220 133 940 691 262 225 -936 -1347 -730 -207 -639 -851 -684 -46 501 793 786 510 128 -413 -625 -1037 -186 -166 264 -2 30 430 675 300 256 -192 -523 217 330 51 -109 -417 -93 3 345 -155 288 307 144 86 -269 -743 -172 -209 -457 572 -415 140 -133 178 -715 -748 -837 -228 -442 63 385 -266 70 -108 -693 -90 -453 428 456 225 139 131 -533 -569 87 -389 182 -99 324 496 -128 -437 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