File name: Pandora139s1_BlueHillMA_20210927_L2Fit_fout2c8d20200818p1-8.txt File generation date: 20260515T071519.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 139 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora139_OF_v3d20200209.txt Instrument calibration file used: Pandora139s1_CF_v8d20200818.txt Level 1 file used: Pandora139s1_BlueHillMA_20210927_L1_smca1c8d20200818p1-8.txt Full location name: Blue Hill, Department of Environmental Protection, MA Short location name: BlueHillMA Country of location: United States Location latitude [deg]: 42.2118 Location longitude [deg]: -71.1145 Location altitude [m]: 188 Local noon date: 20210927 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 240 382 Nominal wavelengths inside fitting window [nm]: 305.0623 305.2031 305.3438 305.4844 305.6251 305.7658 305.9064 306.0471 306.1877 306.3283 306.4689 306.6095 306.7501 306.8907 307.0312 307.1718 307.3123 307.4528 307.5933 307.7338 307.8743 308.0148 308.1552 308.2957 308.4361 308.5765 308.7170 308.8574 308.9977 309.1381 309.2785 309.4188 309.5592 309.6995 309.8398 309.9801 310.1204 310.2607 310.4009 310.5412 310.6814 310.8217 310.9619 311.1021 311.2423 311.3825 311.5226 311.6628 311.8029 311.9431 312.0832 312.2233 312.3634 312.5035 312.6435 312.7836 312.9236 313.0637 313.2037 313.3437 313.4837 313.6237 313.7637 313.9036 314.0436 314.1835 314.3234 314.4634 314.6033 314.7432 314.8830 315.0229 315.1628 315.3026 315.4424 315.5822 315.7220 315.8618 316.0016 316.1414 316.2811 316.4209 316.5606 316.7003 316.8401 316.9798 317.1194 317.2591 317.3988 317.5384 317.6781 317.8177 317.9573 318.0969 318.2365 318.3761 318.5156 318.6552 318.7947 318.9343 319.0738 319.2133 319.3528 319.4923 319.6317 319.7712 319.9106 320.0501 320.1895 320.3289 320.4683 320.6077 320.7470 320.8864 321.0258 321.1651 321.3044 321.4437 321.5830 321.7223 321.8616 322.0009 322.1401 322.2794 322.4186 322.5578 322.6970 322.8362 322.9754 323.1146 323.2537 323.3929 323.5320 323.6711 323.8102 323.9493 324.0884 324.2275 324.3665 324.5056 324.6446 324.7837 324.9227 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210927T111015.1Z 7940.465453 238 1 51.22 2 84.79 97.23 29.39 239.62 0.00 1 0.00 1 0 17 8.210e-01 8.741e-02 4.984e-01 6.393e-02 9.396362e-01 3.858952e-02 1.086905e-02 -6.000000e+00 5.032521e-01 227.74 -2.00 3.53 -2.00 321.99 0.00e+00 -2.800164e-02 1.372886e-02 5.222427e-03 -6.000000e+00 2.801810e-02 284.54 -2.00 20.00 -2.00 321.41 0.00e+00 9.518 0.016 302.00 328.00 3 6.5477e-01 1.3132e-01 1.1956e-01 -6.0000e+00 1.2563e+00 1.8600e+00 1.5291e-01 1.0004e-01 -6.0000e+00 1.3738e+00 -2.1848e+00 8.1073e-02 2.3534e-02 -6.0000e+00 8.0522e-01 7.7569e-01 4.6523e-02 2.6497e-02 -6.0000e+00 3.3924e-01 9.6516e-06 3.4791e-03 1.9013e-03 2.8612e-04 -6.0000e+00 2.4647e-02 -2.4250e-03 0.0000e+00 12 8 8 10 0 0 20.57 23.73 1.07 -0.00243 0.02372 15 3 1 5 0 3414.380 26.83 20.00 23.73 55.2 959.66 205 313658 -26090 -21365 900000 31324 900000 -34460 900000 900000 14003 900000 900000 900000 3890 900000 158768 900000 51743 900000 41760 25508 900000 -14852 900000 900000 137515 -53790 -18550 246184 -52117 -43827 2471 -7192 66958 900000 2397 900000 134484 208123 900000 -47953 900000 14900 509545 9976 -17233 107086 900000 67577 22844 900000 122326 900000 120941 900000 175524 229026 82768 -7141 900000 31929 97376 -18382 -38327 27192 95419 19867 128909 67800 1538 3562 13349 93222 15366 16781 21915 30926 61636 -56639 16329 2593 9025 -11751 15440 71511 -26419 69633 -3475 31480 -21734 -13008 2625 29160 67410 -17922 28400 -2187 3288 -12028 -5518 2423 19840 24196 -4849 -10095 -8672 -274 791 6969 8766 1452 9180 4578 3287 -14719 4259 -1305 -6887 -4424 5816 6745 201 12639 -13199 4894 -7230 -1186 11425 827 -3482 2098 1138 -7228 3947 2309 1665 -2146 -333 2886 1372 -1499 -2393 33 19463 -4450 -2842 900000 1991 900000 -5233 900000 900000 1529 900000 900000 900000 508 900000 9852 900000 3890 900000 2982 2025 900000 -2117 900000 900000 8533 -9206 -1941 15276 -7559 -6383 244 -761 4155 900000 217 900000 8345 12914 900000 -12442 900000 1857 31618 1086 -2303 6645 900000 4306 2445 900000 7590 900000 7504 900000 10891 14211 6316 -1150 900000 3566 6401 -3938 -10152 3835 7116 3206 8295 8790 398 924 3035 9192 2797 2666 3128 4192 7055 -22955 3911 806 2893 -4865 5257 15185 -14368 15639 -1508 9402 -10004 -5290 930 8699 16190 -11028 13138 -1529 2367 -10036 -4066 1500 9601 11302 -3171 -7319 -6594 -208 672 6426 9036 1744 10610 5514 3895 -20231 4972 -1681 -9850 -6322 7376 8108 248 13584 -17698 5407 -8894 -1483 14702 1363 -6708 4185 2468 -18425 9771 6114 4545 -6158 -930 7445 3342 -3499 -5453 SS 20210927T112345.2Z 7940.474829 241 1 50.42 2 82.32 99.54 31.53 243.83 0.00 1 0.00 1 0 17 4.893e-01 2.198e-02 3.112e-01 1.012e-02 8.165924e-01 5.808330e-03 9.121161e-03 -6.000000e+00 2.863463e-01 227.74 -2.00 3.53 -2.00 322.06 0.00e+00 7.927378e-03 3.480263e-03 1.150057e-03 -6.000000e+00 1.363148e-02 284.53 -2.00 20.00 -2.00 321.57 0.00e+00 6.956 0.006 302.00 328.00 3 6.7429e-01 2.3289e-02 8.2524e-02 -6.0000e+00 7.1175e-01 6.0590e-01 3.1039e-02 5.0965e-02 -6.0000e+00 7.7360e-01 -8.6524e-01 2.7486e-02 2.3544e-02 -6.0000e+00 4.5969e-01 3.5544e-01 1.2722e-02 1.2063e-02 -6.0000e+00 1.9475e-01 1.3461e-04 -1.0615e-03 2.9132e-04 1.6499e-04 -6.0000e+00 1.3863e-02 -1.9584e-03 0.0000e+00 12 8 8 10 0 0 21.45 23.76 0.30 -0.00196 -0.00993 69 12 1 5 0 730.690 26.83 20.00 23.76 55.2 962.60 104356 -207738 30371 -204129 900000 -153150 -187544 -8427 -182181 900000 -158662 84117 39404 66743 -119253 -58299 900000 45464 -48640 -41173 900000 -66360 -1601 -30769 900000 11872 -49124 7019 -33868 85481 1476 -1256 -32730 -5231 15270 14258 89460 -27872 17393 4364 45751 11115 45796 62384 -2099 23885 10956 60939 36619 64398 10641 51974 29847 30603 63006 34741 23938 16127 27812 22815 27897 23967 14014 30289 8565 27715 4102 35526 14801 14438 9122 6735 19551 4755 9204 -4962 9457 -9323 3092 1507 -1824 3723 -2871 -1719 -3158 1976 -2197 -504 -1150 -1629 1664 -1035 -505 -3828 -1252 -4880 -2260 -1328 -2803 -52 -1114 801 -1986 -1496 -2890 -1694 -2005 -1191 -1921 -2492 254 -931 -5 -1385 12 -1658 -1206 204 1239 1410 -263 1335 1170 3626 1042 578 1886 836 1914 274 1460 661 396 -162 14 67 -329 196 102 283 -363 -515 -2264 1029 -7610 300 -7046 900000 -2788 -4492 -83 -4620 900000 -3611 830 389 658 -4116 -1415 900000 483 -1302 -1124 900000 -2057 -28 -747 900000 198 -1491 117 -848 843 35 -37 -1429 -184 452 411 1397 -1394 713 221 1840 626 1903 2414 -145 1296 695 2635 1986 3078 899 3258 2565 2636 4438 3129 2439 1749 2578 2160 2751 2521 1870 3923 1487 3991 747 4928 2793 2937 2159 1702 4278 1128 1889 -1049 1728 -1983 705 395 -589 1317 -1207 -764 -1514 956 -1164 -271 -621 -855 795 -479 -226 -1857 -673 -3216 -1715 -1093 -2604 -49 -989 668 -1534 -1125 -2335 -1441 -1814 -1156 -1968 -2938 331 -1335 -8 -2028 17 -2266 -1649 287 1828 2158 -406 1941 1631 5081 1449 782 2456 1147 2957 468 2773 1375 881 -388 35 182 -918 552 286 766 -924 -1219 -5200 SS 20210927T114222.8Z 7940.487764 246 1 50.54 2 78.94 102.78 34.61 248.98 0.00 1 0.00 1 0 25 3.528e-01 7.641e-03 1.566e-01 2.360e-03 6.301929e-01 1.277958e-03 7.125745e-03 -6.000000e+00 2.045483e-01 227.74 -2.00 3.53 -2.00 321.21 0.00e+00 1.530768e-03 6.248413e-04 7.806629e-04 -6.000000e+00 9.095893e-03 284.53 -2.00 20.00 -2.00 320.63 0.00e+00 5.026 0.002 302.00 328.00 3 5.8711e-01 4.3900e-03 5.9509e-02 -6.0000e+00 5.0766e-01 3.8397e-02 5.9916e-03 3.4336e-02 -6.0000e+00 5.5033e-01 -3.9946e-02 5.9225e-03 1.8154e-02 -6.0000e+00 3.2818e-01 6.2293e-03 2.8239e-03 6.0317e-03 -6.0000e+00 1.3967e-01 1.1286e-03 -1.6682e-04 6.9054e-05 7.2680e-05 -6.0000e+00 9.8764e-03 -1.7841e-03 0.0000e+00 11 8 0 10 0 0 9.48 23.77 0.21 -0.00178 -0.00304 220 40 1 5 0 229.690 26.83 20.00 23.77 55.3 966.48 -95640 -133594 35135 -178067 -47216 -177683 -74268 -135345 74341 -86001 -119046 -32173 -92085 21668 -56754 -10731 -51390 15902 -393 -29996 -9675 -41396 3144 -36281 29460 -24845 11165 -18626 -10673 -2675 -24619 6821 -17049 13833 -18591 -6246 -6203 -2624 5814 -4115 8837 -3195 9781 1977 7995 3356 1758 5618 -3941 7176 -99 10348 575 5151 4021 2128 3667 -1871 4888 -3633 3694 792 3182 2527 2007 2237 -1336 2029 -1733 2771 -461 2393 1008 1611 746 -1250 500 -4780 6 -2509 -321 -1024 -1493 -1432 -1541 -14 -509 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