File name: Pandora139s1_BlueHillMA_20210928_L2Fit_fwvt1c8d20200818p1-8.txt File generation date: 20260515T070739.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 139 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora139_OF_v3d20200209.txt Instrument calibration file used: Pandora139s1_CF_v8d20200818.txt Level 1 file used: Pandora139s1_BlueHillMA_20210928_L1_smca1c8d20200818p1-8.txt Full location name: Blue Hill, Department of Environmental Protection, MA Short location name: BlueHillMA Country of location: United States Location latitude [deg]: 42.2118 Location longitude [deg]: -71.1145 Location altitude [m]: 188 Local noon date: 20210928 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1664 1814 Nominal wavelengths inside fitting window [nm]: 492.0351 492.1557 492.2763 492.3968 492.5173 492.6378 492.7583 492.8788 492.9992 493.1197 493.2401 493.3605 493.4809 493.6012 493.7216 493.8419 493.9622 494.0825 494.2028 494.3231 494.4433 494.5636 494.6838 494.8040 494.9242 495.0443 495.1645 495.2846 495.4047 495.5248 495.6449 495.7650 495.8850 496.0050 496.1250 496.2450 496.3650 496.4850 496.6049 496.7248 496.8447 496.9646 497.0845 497.2044 497.3242 497.4440 497.5638 497.6836 497.8034 497.9231 498.0429 498.1626 498.2823 498.4020 498.5217 498.6413 498.7609 498.8806 499.0002 499.1197 499.2393 499.3589 499.4784 499.5979 499.7174 499.8369 499.9563 500.0758 500.1952 500.3146 500.4340 500.5534 500.6728 500.7921 500.9114 501.0307 501.1500 501.2693 501.3886 501.5078 501.6270 501.7462 501.8654 501.9846 502.1037 502.2229 502.3420 502.4611 502.5802 502.6992 502.8183 502.9373 503.0563 503.1753 503.2943 503.4133 503.5322 503.6511 503.7700 503.8889 504.0078 504.1267 504.2455 504.3643 504.4831 504.6019 504.7207 504.8395 504.9582 505.0769 505.1956 505.3143 505.4330 505.5516 505.6703 505.7889 505.9075 506.0260 506.1446 506.2632 506.3817 506.5002 506.6187 506.7372 506.8556 506.9741 507.0925 507.2109 507.3293 507.4477 507.5660 507.6844 507.8027 507.9210 508.0393 508.1575 508.2758 508.3940 508.5122 508.6304 508.7486 508.8668 508.9849 509.1031 509.2212 509.3393 509.4573 509.5754 509.6934 509.8115 509.9295 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20210928T110003.1Z 7941.458369 238 1 50.58 2 86.87 95.84 19.95 216.35 0.00 1 0.00 1 0 29 9.278e-03 9.122e-03 4.425e-04 4.407e-04 1.847445e+04 3.061248e+01 1.292722e+03 -6.000000e+00 4.917044e+02 284.41 -2.00 20.00 -2.00 505.42 0.00e+00 2.582039e-03 1.198478e-05 1.415834e-04 -6.000000e+00 2.557667e-04 284.41 -2.00 20.00 -2.00 500.97 0.00e+00 8.854908e-01 8.275127e-03 9.243948e-02 -6.000000e+00 1.792985e-01 227.62 -2.00 3.53 -2.00 502.48 0.00e+00 13.215 0.043 489.00 513.00 1 3.6788e+00 6.3218e-04 2.1426e-02 -6.0000e+00 1.3714e-02 -6.9041e-02 1.6013e-04 2.7889e-03 -6.0000e+00 3.6222e-03 6.8710e-03 1.1029e-02 3.2971e-05 1.5865e-04 -6.0000e+00 7.8076e-04 8.3169e-02 -7.0119e-04 12 8 8 10 0 0 20.11 24.41 3.55 0.08317 0.15967 83 15 1 4 0 609.360 27.35 19.99 24.41 56.9 975.02 -1821 -790 207 961 1252 1647 1944 1694 1276 698 257 -89 -745 -1016 -923 -628 -280 410 755 631 416 386 440 620 810 825 745 181 -641 -1736 -1710 -1416 -605 403 972 607 47 -196 -637 -580 -486 -55 330 714 956 910 735 321 -28 -714 -1375 -2016 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624 991 1330 1429 1733 1662 1533 930 535 102 44 355 841 890 810 802 522 483 637 172 -497 -852 -890 -903 -238 298 396 456 457 419 612 854 909 940 455 -358 -1181 -1551 -1402 SQ 20210928T121914.1Z 7941.513358 266 1 50.07 2 72.61 109.82 31.40 247.90 0.00 1 0.00 1 0 22 3.585e-03 3.553e-03 2.134e-04 2.129e-04 5.602118e+03 1.313667e+01 4.245712e+02 -6.000000e+00 1.900089e+02 284.41 -2.00 20.00 -2.00 505.28 0.00e+00 7.727096e-04 5.754376e-06 4.360236e-05 -6.000000e+00 9.881636e-05 284.41 -2.00 20.00 -2.00 500.46 0.00e+00 2.260100e-01 4.068644e-03 2.911965e-02 -6.000000e+00 6.918592e-02 227.62 -2.00 3.53 -2.00 502.05 0.00e+00 3.298 0.001 489.00 513.00 1 3.6969e+00 3.1102e-04 5.4016e-03 -6.0000e+00 5.2932e-03 -1.5363e-02 8.0506e-05 8.3929e-04 -6.0000e+00 1.3953e-03 2.9569e-02 8.9344e-03 1.7177e-05 5.3784e-05 -6.0000e+00 3.0154e-04 -6.9438e-03 -4.2109e-05 10 0 0 10 0 0 99.96 24.43 1.64 -0.00694 0.05503 435 79 1 4 0 115.080 27.45 20.00 24.43 56.6 976.36 -785 -310 87 508 503 567 705 616 388 214 -1 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1328.730 27.45 20.01 24.44 56.6 977.08 -806 -398 102 461 450 705 741 632 462 286 -161 -260 -432 -557 -484 -250 -140 224 244 209 17 196 87 52 473 300 319 28 -208 -469 -562 -406 -271 53 501 195 179 -198 -330 -157 -184 107 49 172 315 325 470 -26 172 -201 -452 -770 -1007 -682 -191 111 371 172 57 201 151 126 576 526 241 268 56 -355 -397 -312 -509 -350 -212 -161 172 356 -320 -700 -433 -365 -492 -389 -356 -372 76 20 97 -151 -192 -174 -194 -78 281 526 263 180 -79 172 -175 -629 -783 -649 -462 60 228 244 -30 65 -595 -313 -179 34 105 338 711 555 276 430 532 222 275 279 -20 -24 252 -96 72 430 175 84 279 159 -108 -190 -251 -551 -226 32 34 31 148 158 326 142 408 626 288 -86 -417 -739 -479 -786 -384 102 462 461 736 765 658 479 292 -167 -268 -437 -556 -481 -250 -142 227 254 219 18 205 92 55 500 318 337 29 -211 -472 -559 -405 -278 54 518 203 189 -207 -340 -160 -188 110 51 177 327 337 483 -27 177 -201 -453 -754 -976 -666 -186 112 383 174 58 202 152 128 585 534 243 273 56 -354 -391 -303 -490 -338 -207 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