File name: Pandora83s1_BondvilleIL_20250921_L2Fit_fout2c8d20241002p1-8.txt File generation date: 20250922T062326.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Kevin Mishoe Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 83 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora83_OF_v4d20231115.txt Instrument calibration file used: Pandora83s1_CF_v8d20241002.txt Level 1 file used: Pandora83s1_BondvilleIL_20250921_L1_smca1c8d20241002p1-8.txt Full location name: Bondville, Illinois EPA Castnet Site Short location name: BondvilleIL Country of location: United States Location latitude [deg]: 40.0520 Location longitude [deg]: -88.3725 Location altitude [m]: 213 Local noon date: 20250921 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0376 305.1782 305.3189 305.4595 305.6001 305.7407 305.8813 306.0219 306.1625 306.3031 306.4436 306.5841 306.7247 306.8652 307.0057 307.1462 307.2867 307.4271 307.5676 307.7081 307.8485 307.9889 308.1293 308.2697 308.4101 308.5505 308.6909 308.8312 308.9716 309.1119 309.2522 309.3925 309.5328 309.6731 309.8134 309.9537 310.0939 310.2342 310.3744 310.5146 310.6548 310.7950 310.9352 311.0754 311.2155 311.3557 311.4958 311.6359 311.7761 311.9162 312.0563 312.1963 312.3364 312.4765 312.6165 312.7565 312.8966 313.0366 313.1766 313.3166 313.4565 313.5965 313.7365 313.8764 314.0163 314.1563 314.2962 314.4361 314.5760 314.7158 314.8557 314.9955 315.1354 315.2752 315.4150 315.5548 315.6946 315.8344 315.9742 316.1139 316.2537 316.3934 316.5331 316.6728 316.8125 316.9522 317.0919 317.2316 317.3712 317.5109 317.6505 317.7901 317.9297 318.0693 318.2089 318.3485 318.4880 318.6276 318.7671 318.9066 319.0462 319.1857 319.3251 319.4646 319.6041 319.7435 319.8830 320.0224 320.1618 320.3013 320.4407 320.5800 320.7194 320.8588 320.9981 321.1375 321.2768 321.4161 321.5554 321.6947 321.8340 321.9733 322.1125 322.2518 322.3910 322.5302 322.6694 322.8086 322.9478 323.0870 323.2262 323.3653 323.5045 323.6436 323.7827 323.9218 324.0609 324.2000 324.3391 324.4781 324.6172 324.7562 324.8952 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250921T124344.8Z 9395.530379 63 1 53.36 2 78.78 98.96 76.64 100.64 0.00 1 0.00 1 0 33 7.583e-01 5.864e-02 2.025e-01 4.667e-03 6.073013e-01 2.538529e-03 6.905567e-03 -6.000000e+00 4.407229e-01 228.52 -2.00 3.49 -2.00 320.64 0.00e+00 -3.680828e-02 1.033495e-03 2.396393e-03 -6.000000e+00 2.219737e-02 286.72 -2.00 20.00 -2.00 319.94 0.00e+00 4.959 0.002 302.00 328.00 3 3.2226e+00 8.1735e-03 6.9231e-02 -6.0000e+00 1.1001e+00 2.2843e-01 1.0534e-02 6.8170e-02 -6.0000e+00 1.1939e+00 -6.1463e-01 9.1198e-03 3.7685e-02 -6.0000e+00 7.0617e-01 2.9359e-01 4.4813e-03 4.6325e-02 -6.0000e+00 3.0383e-01 1.0325e-04 -1.1216e-03 1.3842e-04 3.8358e-04 -6.0000e+00 2.1271e-02 1.9066e-02 0.0000e+00 12 9 8 11 8 0 96.91 25.00 -0.08 0.01907 0.01064 22 2 1 5 0 2425.060 33.75 20.00 25.00 22.57 2.0 1100.00 -5418 10895 900000 317660 900000 22729 52991 900000 115676 900000 407054 900000 900000 57675 900000 128309 55788 27907 99575 16052 20851 271151 101785 81174 63089 125531 169538 137207 146723 306650 230555 80015 99972 92701 66730 30270 44397 32243 82797 83480 99126 66502 55162 -93323 40670 42187 69146 33254 29633 15696 29304 10280 26578 40906 36981 38434 24221 41393 32498 23668 32913 18490 25472 9055 11125 -1655 4069 9983 11336 4132 9442 7469 5883 15739 13622 7398 10596 1267 -7799 -2938 -6034 -5406 1785 -9345 -2520 1780 -63 1056 1545 -798 -218 -2419 -211 8108 -566 -1052 -2487 -6373 -5344 -6439 -3611 -118 -2688 -2934 -1438 -3084 -2844 -547 -1280 -531 763 461 198 913 2889 2539 1403 687 -339 -719 680 1186 768 833 1027 1880 6074 195 150 -164 356 306 -29 906 -664 1288 60 -101 -14 231 -1150 -1774 -1120 -130 225 900000 1444 900000 319 679 900000 1386 900000 1850 900000 900000 1573 900000 2041 1851 1230 2172 817 1023 1232 2544 3136 3670 4450 3853 3742 3001 1394 1781 2982 3317 3455 3093 1981 2785 2828 5720 7247 8560 8463 7772 -49624 5748 5484 6474 4307 3986 2533 4515 2140 5182 7604 7849 8804 6891 10121 8286 6088 7345 4882 6796 3099 3868 -632 1413 3344 4137 1878 4566 3924 3171 7382 6017 3107 3905 495 -3513 -1437 -3527 -3270 1119 -7050 -1910 1389 -53 908 1318 -673 -171 -1819 -148 5296 -439 -924 -2508 -6891 -6248 -7756 -4025 -126 -2730 -2996 -1560 -3645 -3229 -642 -1631 -745 1169 758 333 1480 4351 3641 2002 1020 -537 -1207 1138 1929 1210 1275 1513 2644 7847 269 226 -279 611 559 -56 1824 -1454 2727 133 -228 -32 505 -2584 -3759 -2255 SS 20250921T124950.7Z 9395.534615 66 1 54.19 2 77.63 99.98 75.54 101.67 0.00 1 0.00 1 0 17 3.588e-01 1.006e-02 1.870e-01 2.682e-03 5.472789e-01 1.409423e-03 6.379536e-03 -6.000000e+00 2.084217e-01 228.52 -2.00 3.49 -2.00 320.23 0.00e+00 1.932203e-03 5.172204e-04 1.493571e-03 -6.000000e+00 9.695027e-03 286.72 -2.00 20.00 -2.00 319.54 0.00e+00 4.532 0.002 302.00 328.00 3 2.7028e+00 4.2723e-03 5.2849e-02 -6.0000e+00 5.1977e-01 2.4352e-02 5.3452e-03 2.9621e-02 -6.0000e+00 5.6373e-01 -2.9489e-02 4.8192e-03 1.5084e-02 -6.0000e+00 3.3357e-01 3.4903e-03 2.4537e-03 4.4856e-03 -6.0000e+00 1.4220e-01 2.3732e-04 -3.8108e-05 7.5681e-05 5.3970e-05 -6.0000e+00 9.9981e-03 1.8997e-02 0.0000e+00 12 8 8 10 0 0 61.32 25.00 0.22 0.01900 0.01871 46 5 1 5 0 1177.890 33.75 20.00 25.00 22.82 2.0 1100.00 -129655 6252 179148 205550 900000 41305 -65234 900000 -96658 900000 48463 37522 135388 -52319 172081 16397 -32931 -46815 6812 -40496 -22308 13065 -3882 -28089 -24110 8779 7937 -4061 10912 38254 13277 7375 7734 3393 -6693 -13483 255 -10249 -704 5376 1414 -3612 -7261 -7417 -2666 1171 12087 1623 2457 -2208 3295 -2015 1043 5196 3507 2868 -3514 373 -845 -1686 7692 2553 5681 1634 46 -948 -309 4550 3188 642 2254 40 4 2536 2100 -246 665 -3177 -3619 -387 -1044 -1644 610 -4135 -830 -48 128 510 129 -215 218 -427 -602 3078 374 -124 573 -724 -350 -1384 -654 458 -385 -770 -866 -1853 -1529 -40 368 604 1208 486 -106 -3 364 544 648 240 -186 -42 1 550 -48 88 -243 -482 1952 -285 107 30 401 420 -77 373 -541 167 -281 -248 -259 239 -370 -369 378 -2157 31 468 537 900000 151 -750 900000 -1996 900000 266 255 425 -1354 585 313 -1153 -2068 191 -1927 -915 379 -139 -1395 -1254 349 324 -182 411 1150 590 411 493 242 -513 -1089 20 -1042 -80 689 213 -616 -1351 -1421 -494 213 2003 305 473 -470 728 -523 288 1487 983 844 -1138 117 -262 -570 2437 844 2052 685 21 -418 -130 1850 1433 340 1305 25 3 1472 1131 -122 301 -1472 -1832 -221 -700 -1157 461 -3478 -720 -44 125 513 130 -212 200 -366 -487 2406 328 -125 607 -882 -432 -1749 -835 523 -407 -817 -986 -2272 -1966 -54 493 893 1819 780 -172 -5 567 802 945 366 -302 -67 2 863 -78 138 -369 -704 2664 -403 165 49 707 784 -141 716 -1119 343 -596 -535 -562 504 -793 -746 731 SS 20250921T125513.6Z 9395.538352 69 1 53.82 2 76.62 100.89 74.57 102.59 0.00 1 0.00 1 0 25 4.918e-01 1.055e-02 1.734e-01 2.763e-03 5.115687e-01 1.442772e-03 5.987021e-03 -6.000000e+00 2.854261e-01 228.52 -2.00 3.49 -2.00 320.02 0.00e+00 2.788171e-03 4.897088e-04 1.021889e-03 -6.000000e+00 1.289147e-02 286.72 -2.00 20.00 -2.00 319.32 0.00e+00 4.213 0.001 302.00 328.00 3 3.0669e+00 4.2803e-03 4.9035e-02 -6.0000e+00 7.1023e-01 2.6120e-02 5.2485e-03 2.7039e-02 -6.0000e+00 7.6974e-01 -2.1304e-02 4.5608e-03 1.4083e-02 -6.0000e+00 4.5695e-01 -7.2600e-04 2.3515e-03 4.7933e-03 -6.0000e+00 1.9473e-01 2.2880e-04 -6.2831e-05 7.8349e-05 5.1292e-05 -6.0000e+00 1.3702e-02 1.9486e-02 0.0000e+00 12 9 8 11 8 0 98.21 25.00 0.22 0.01949 0.01901 39 4 1 5 0 1379.830 33.75 20.00 25.00 23.10 2.0 1100.00 -115761 66296 240387 278239 900000 -29962 -58960 900000 -46674 376555 62532 4936 38474 -34705 84504 -3077 -20580 -33276 -3538 -34156 -14722 20115 -11354 -14579 -27863 2727 16720 -6052 15559 54910 9749 5049 9866 3953 -948 -9545 -1339 -11554 -2116 -1270 5302 -5262 -7049 -1791 -4940 1963 11404 1091 2207 -1688 -277 -1682 2442 5364 4479 3638 -2940 922 -286 -3725 6053 1236 4773 1398 1276 -929 -298 3696 2591 397 1342 716 -956 2507 1984 -106 1214 -1869 -3595 -345 -1379 -1708 764 -4407 -903 71 65 75 499 560 973 -1281 -33 2844 494 -79 1119 -551 -349 -1368 -759 571 -1079 -924 -850 -2354 -1400 -75 155 832 1385 657 -203 -9 488 535 224 -45 -93 -254 -299 475 -548 296 96 66 1837 30 345 -92 93 425 115 476 -312 356 -483 -212 -49 31 -299 -610 241 -2410 260 648 749 900000 -315 -889 900000 -805 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