File name: Pandora83s1_BondvilleIL_20250922_L2Fit_fwvt1c8d20241002p1-8.txt
File generation date: 20250923T070005.1Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c8p1-8
Local principal investigator: Kevin Mishoe
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 83
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora83_OF_v4d20231115.txt
Instrument calibration file used: Pandora83s1_CF_v8d20241002.txt
Level 1 file used: Pandora83s1_BondvilleIL_20250922_L1_smca1c8d20241002p1-8.txt
Full location name: Bondville, Illinois EPA Castnet Site
Short location name: BondvilleIL
Country of location: United States
Location latitude [deg]: 40.0520
Location longitude [deg]: -88.3725
Location altitude [m]: 213
Local noon date: 20250922
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1623 1773
Nominal wavelengths inside fitting window [nm]: 492.0733 492.1940 492.3147 492.4354 492.5561 492.6767 492.7974 492.9180 493.0386 493.1592 493.2798 493.4003 493.5208 493.6414 493.7619 493.8824 494.0028 494.1233 494.2437 494.3642 494.4846 494.6050 494.7253 494.8457 494.9660 495.0863 495.2066 495.3269 495.4472 495.5675 495.6877 495.8079 495.9281 496.0483 496.1685 496.2886 496.4088 496.5289 496.6490 496.7691 496.8892 497.0092 497.1292 497.2493 497.3693 497.4893 497.6092 497.7292 497.8491 497.9690 498.0889 498.2088 498.3287 498.4485 498.5684 498.6882 498.8080 498.9278 499.0475 499.1673 499.2870 499.4067 499.5264 499.6461 499.7658 499.8854 500.0051 500.1247 500.2443 500.3639 500.4834 500.6030 500.7225 500.8420 500.9615 501.0810 501.2005 501.3199 501.4393 501.5588 501.6782 501.7975 501.9169 502.0362 502.1556 502.2749 502.3942 502.5134 502.6327 502.7519 502.8712 502.9904 503.1096 503.2288 503.3479 503.4670 503.5862 503.7053 503.8244 503.9434 504.0625 504.1815 504.3006 504.4196 504.5386 504.6575 504.7765 504.8954 505.0143 505.1332 505.2521 505.3710 505.4898 505.6087 505.7275 505.8463 505.9651 506.0838 506.2026 506.3213 506.4400 506.5587 506.6774 506.7961 506.9147 507.0334 507.1520 507.2706 507.3891 507.5077 507.6263 507.7448 507.8633 507.9818 508.1003 508.2187 508.3372 508.4556 508.5740 508.6924 508.8108 508.9291 509.0474 509.1658 509.2841 509.4024 509.5206 509.6389 509.7571 509.8753 509.9935
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250922T140538.7Z 9396.587254 112 1 53.69 2 63.99 114.11 73.50 112.48 0.00 1 0.00 1 0 15 2.499e-03 2.509e-03 5.937e-04 5.925e-04 4.880965e+03 3.846298e+01 3.001141e+02 -6.000000e+00 1.423269e+02 286.59 -2.00 20.00 -2.00 505.27 0.00e+00 5.853335e-04 1.651362e-05 4.735837e-05 -6.000000e+00 7.093356e-05 286.59 -2.00 20.00 -2.00 500.43 0.00e+00 1.474986e-01 1.172650e-02 4.056253e-02 -6.000000e+00 4.938130e-02 228.41 -2.00 3.49 -2.00 502.03 0.00e+00 2.267 0.000 489.00 513.00 1 6.3477e+00 9.0140e-04 4.7298e-03 -6.0000e+00 3.7980e-03 3.9403e-03 2.2928e-04 8.9680e-04 -6.0000e+00 9.7333e-04 2.4366e-03 -5.3993e-04 5.9489e-05 3.0640e-05 -6.0000e+00 2.6176e-04 1.4806e-02 -1.0799e-04 10 0 0 10 0 0 99.85 25.21 0.86 0.01481 0.01106 37 4 1 4 0 1450.940 33.75 19.99 25.21 25.73 1.9 1100.00 -344 -275 -51 90 235 334 570 673 633 503 135 397 118 286 -73 -168 -166 -197 -150 -243 -134 -223 -32 -141 197 239 -299 -200 -165 -220 -236 83 -216 -308 -148 -223 -242 176 -133 -123 -137 -32 103 109 102 198 109 130 35 -128 -165 -2 -177 -311 -164 -253 -131 18 6 294 520 396 306 281 282 221 259 -17 57 94 2 161 -9 -200 -251 -168 -330 -321 -203 -220 -271 -341 -414 -341 -279 -484 -523 -266 -420 -218 -151 -208 -360 -217 -358 -159 -119 -235 -110 165 51 284 372 424 533 311 191 496 531 428 245 -89 -19 202 131 -66 11 -49 -18 0 26 220 -234 119 -6 18 -44 -97 -180 -96 27 -205 -81 -48 142 -197 -144 -133 157 151 257 325 213 191 203 59 -70 83 114 -32 -194 -338 -274 -50 92 241 349 605 699 656 531 141 407 119 294 -75 -169 -169 -205 -156 -256 -141 -236 -34 -149 208 253 -316 -209 -168 -223 -236 83 -221 -317 -155 -237 -256 183 -137 -126 -140 -33 106 114 108 210 115 135 36 -131 -164 -2 -175 -302 -163 -252 -134 19 6 301 531 406 316 289 288 223 258 -16 56 93 2 157 -8 -200 -247 -164 -327 -312 -195 -211 -261 -330 -404 -336 -271 -474 -515 -262 -413 -214 -149 -209 -356 -215 -360 -156 -114 -226 -103 156 48 264 355 409 529 304 186 488 517 418 242 -87 -18 201 132 -66 11 -49 -19 0 25 214 -226 115 -6 18 -42 -94 -174 -93 26 -200 -77 -45 134 -188 -140 -129 154 149 257 318 210 189 200 58 -70 81 109 -30 -185
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SQ 20250922T141408.4Z 9396.593153 118 1 5.43 2 62.52 115.83 72.06 114.04 0.00 1 0.00 1 0 15 2.348e-03 2.356e-03 5.124e-04 5.117e-04 4.459699e+03 3.286241e+01 2.761242e+02 -6.000000e+00 1.337320e+02 286.59 -2.00 20.00 -2.00 505.28 0.00e+00 5.921583e-04 1.427099e-05 4.638688e-05 -6.000000e+00 6.665130e-05 286.59 -2.00 20.00 -2.00 500.49 0.00e+00 1.111362e-01 1.010003e-02 3.733179e-02 -6.000000e+00 4.640343e-02 228.41 -2.00 3.49 -2.00 502.08 0.00e+00 2.156 0.000 489.00 513.00 1 3.8171e+00 7.7649e-04 4.4352e-03 -6.0000e+00 3.5689e-03 -2.3516e-03 1.9735e-04 8.2680e-04 -6.0000e+00 9.1471e-04 3.1189e-02 -5.5547e-04 5.1509e-05 2.9299e-05 -6.0000e+00 2.4597e-04 1.5330e-02 -1.1684e-04 12 1 1 12 1 1 97.78 25.21 0.83 0.01533 0.01148 31 36 1 4 0 169.530 34.00 20.00 25.21 25.91 1.9 1100.00 -422 -228 -319 60 263 503 517 551 609 529 364 396 182 30 -46 -115 -32 -251 -87 -111 -240 -89 -76 -25 123 77 -219 -213 -24 -219 -286 -54 -137 -279 -153 -153 -256 -182 -73 -161 -13 -20 156 100 140 201 218 127 -59 -91 -162 -246 -127 -341 -232 -218 -84 42 87 270 231 366 361 316 251 311 198 20 96 95 9 -13 34 -198 -167 -157 -232 -269 -145 -258 -380 -231 -208 -392 -235 -300 -401 -348 -278 -157 -186 -307 -332 -267 -272 -263 -85 -321 3 132 127 321 335 360 513 316 311 571 508 352 183 -44 -87 -88 138 51 -41 -132 -83 -164 38 94 -51 -129 -56 -85 -73 95 30 76 -61 -79 -121 -6 72 -38 -22 -7 32 151 152 317 158 248 244 -58 -28 6 -4 24 -159 -409 -224 -319 61 269 517 540 572 640 550 373 406 185 30 -46 -117 -33 -258 -90 -117 -253 -94 -80 -26 129 80 -229 -222 -24 -223 -286 -54 -138 -287 -158 -160 -267 -188 -76 -165 -13 -20 162 104 147 210 227 130 -61 -92 -162 -241 -125 -332 -231 -221 -86 43 89 274 234 372 369 322 254 315 198 20 95 93 9 -13 33 -197 -165 -155 -228 -261 -140 -250 -369 -225 -202 -384 -229 -296 -398 -345 -275 -156 -183 -306 -335 -266 -273 -258 -82 -308 3 125 120 302 319 351 507 312 304 559 493 343 181 -43 -87 -88 139 51 -42 -133 -84 -164 38 92 -50 -126 -55 -84 -72 93 30 74 -60 -76 -115 -5 69 -36 -22 -7 32 150 152 317 157 247 243 -58 -28 6 -4 23 -154
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