File name: Pandora83s1_BondvilleIL_20251222_L2Fit_fout2c8d20241002p1-8.txt File generation date: 20251223T062150.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Kevin Mishoe Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 83 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora83_OF_v4d20231115.txt Instrument calibration file used: Pandora83s1_CF_v8d20241002.txt Level 1 file used: Pandora83s1_BondvilleIL_20251222_L1_smca1c8d20241002p1-8.txt Full location name: Bondville, Illinois EPA Castnet Site Short location name: BondvilleIL Country of location: United States Location latitude [deg]: 40.0520 Location longitude [deg]: -88.3725 Location altitude [m]: 213 Local noon date: 20251222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0376 305.1782 305.3189 305.4595 305.6001 305.7407 305.8813 306.0219 306.1625 306.3031 306.4436 306.5841 306.7247 306.8652 307.0057 307.1462 307.2867 307.4271 307.5676 307.7081 307.8485 307.9889 308.1293 308.2697 308.4101 308.5505 308.6909 308.8312 308.9716 309.1119 309.2522 309.3925 309.5328 309.6731 309.8134 309.9537 310.0939 310.2342 310.3744 310.5146 310.6548 310.7950 310.9352 311.0754 311.2155 311.3557 311.4958 311.6359 311.7761 311.9162 312.0563 312.1963 312.3364 312.4765 312.6165 312.7565 312.8966 313.0366 313.1766 313.3166 313.4565 313.5965 313.7365 313.8764 314.0163 314.1563 314.2962 314.4361 314.5760 314.7158 314.8557 314.9955 315.1354 315.2752 315.4150 315.5548 315.6946 315.8344 315.9742 316.1139 316.2537 316.3934 316.5331 316.6728 316.8125 316.9522 317.0919 317.2316 317.3712 317.5109 317.6505 317.7901 317.9297 318.0693 318.2089 318.3485 318.4880 318.6276 318.7671 318.9066 319.0462 319.1857 319.3251 319.4646 319.6041 319.7435 319.8830 320.0224 320.1618 320.3013 320.4407 320.5800 320.7194 320.8588 320.9981 321.1375 321.2768 321.4161 321.5554 321.6947 321.8340 321.9733 322.1125 322.2518 322.3910 322.5302 322.6694 322.8086 322.9478 323.0870 323.2262 323.3653 323.5045 323.6436 323.7827 323.9218 324.0609 324.2000 324.3391 324.4781 324.6172 324.7562 324.8952 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251222T161212.3Z 9487.675143 141 1 16.09 2 67.63 155.19 83.59 129.08 0.00 1 0.00 1 0 17 1.222e-01 2.090e-02 3.479e-02 5.265e-03 3.252286e-01 2.632127e-03 3.904391e-03 -6.000000e+00 6.908845e-02 223.06 -2.00 3.49 -2.00 318.02 0.00e+00 -1.520082e-03 4.605477e-04 3.452786e-04 -6.000000e+00 3.012301e-03 276.24 -2.00 20.00 -2.00 317.42 0.00e+00 2.606 0.000 302.00 328.00 3 4.7038e+00 6.9773e-03 3.0113e-02 -6.0000e+00 1.7025e-01 5.5728e-02 7.8835e-03 1.6653e-02 -6.0000e+00 1.8519e-01 -1.5436e-02 5.1557e-03 8.1918e-03 -6.0000e+00 1.1028e-01 -3.6604e-03 2.7032e-03 2.7806e-03 -6.0000e+00 4.7457e-02 2.5399e-04 -9.9074e-04 1.5186e-04 2.8435e-05 -6.0000e+00 3.3073e-03 -6.1692e-03 0.0000e+00 12 9 9 12 9 1 99.86 24.57 -0.54 -0.00617 -0.01361 4 2 1 5 0 3217.600 33.50 20.03 24.57 7.35 2.3 1053.25 -30745 -16283 25544 23804 115875 -3078 -1347 19125 6334 38458 4018 13639 17418 -7090 -3546 1937 -4915 -2322 4243 -786 991 6745 -2405 -2398 -4893 9666 5913 5710 5982 11977 11025 4801 1276 -5542 320 -6064 -1134 615 3701 4336 6278 2173 1235 -30882 -1616 -961 5315 -1105 -680 991 1864 -1564 1325 1518 3051 3225 -911 1881 526 1423 7445 2299 4383 296 1910 -946 -897 1869 2850 254 1362 489 101 2954 698 597 -501 -439 -2774 538 -2067 -2899 -51 -3982 -1664 255 -575 1004 136 427 849 167 -262 2260 -896 -343 -433 -888 20 -214 -953 830 -1049 -1624 -933 -1172 -1059 -449 409 1237 870 993 -812 -421 429 529 515 324 -259 220 809 282 -559 343 -523 -774 1905 -684 -88 429 527 270 -25 38 127 418 -236 -12 627 212 -981 -742 -200 -2541 -1313 1416 1295 2261 -185 -83 1090 468 2231 334 1050 1431 -863 -482 281 -815 -392 704 -143 182 1167 -463 -491 -1110 2005 1290 1193 1161 2115 2055 1048 317 -1562 82 -1585 -297 183 1176 1631 2605 1001 594 -19053 -809 -477 2453 -534 -323 465 908 -853 754 914 1893 2058 -570 1152 349 918 4570 1443 2944 224 1475 -718 -629 1226 1924 198 1172 451 95 2615 594 461 -351 -313 -2060 395 -1772 -2805 -48 -4125 -1784 288 -695 1245 160 527 980 178 -257 2220 -940 -363 -512 -1093 27 -291 -1245 1050 -1248 -1926 -1176 -1476 -1397 -615 585 1881 1328 1577 -1300 -638 638 729 688 445 -379 344 1216 425 -885 521 -765 -1082 2650 -952 -120 628 826 414 -39 62 217 755 -417 -22 1138 383 -1727 -1329 -343 SS 20251222T163736.3Z 9487.692782 154 1 3.06 2 65.83 161.22 80.00 133.49 0.00 1 0.00 1 0 17 1.568e-02 6.697e-03 1.165e-02 4.110e-03 3.001231e-01 2.065713e-03 3.654995e-03 -6.000000e+00 8.876812e-03 223.06 -2.00 3.49 -2.00 316.92 0.00e+00 7.886918e-04 2.686937e-04 7.377313e-05 -6.000000e+00 3.869254e-04 276.24 -2.00 20.00 -2.00 316.33 0.00e+00 2.425 0.000 302.00 328.00 3 3.0580e+00 5.3587e-03 2.7925e-02 -6.0000e+00 2.1875e-02 3.3275e-02 6.0047e-03 1.5110e-02 -6.0000e+00 2.3789e-02 -4.8320e-03 3.6009e-03 7.5426e-03 -6.0000e+00 1.4166e-02 -3.2157e-03 1.7841e-03 2.2553e-03 -6.0000e+00 6.1004e-03 1.6205e-03 -3.3085e-04 1.1634e-04 2.6071e-05 -6.0000e+00 4.2461e-04 -1.0322e-02 0.0000e+00 12 9 1 12 9 1 92.43 24.60 0.17 -0.01032 -0.01281 3 8 1 5 0 764.250 33.50 20.01 24.60 8.20 2.3 1060.14 1367 -6264 -463 -2481 8194 -2527 -763 -432 -6545 461 -3947 -923 4300 -4137 3177 188 734 -803 2169 -181 -46 -240 1005 -795 -1877 639 -73 603 1025 2272 -567 1932 -434 -1896 -866 -4578 -1302 -918 -1347 -194 840 -428 -795 832 -1792 -961 578 -63 -453 680 759 617 1708 1997 1701 1295 313 388 -727 -183 787 521 2154 851 850 -494 -21 -379 693 934 521 33 -329 257 -290 -89 -225 -1205 -1777 277 -1044 -1296 -1347 -1282 -1667 -287 -405 547 693 321 510 -174 -87 797 378 -21 734 -497 -11 -957 -87 -400 -350 -359 -885 -873 -701 -23 282 478 426 733 454 71 242 508 96 873 193 -443 -376 -119 91 168 -231 146 880 497 601 439 -186 -368 -17 514 -367 34 -3 91 113 -104 -370 -654 -79 155 -867 -63 -333 890 -284 -87 -55 -997 70 -631 -146 716 -801 665 46 189 -220 604 -54 -13 -67 304 -238 -604 210 -24 192 305 703 -174 637 -161 -753 -328 -1716 -496 -373 -661 -104 467 -257 -495 519 -1149 -613 360 -39 -275 409 477 394 1152 1421 1194 936 233 291 -541 -133 576 406 1712 742 765 -429 -18 -306 574 821 487 31 -317 251 -269 -79 -189 -952 -1432 231 -951 -1258 -1419 -1358 -1877 -327 -492 657 840 382 596 -196 -93 804 394 -23 854 -625 -14 -1288 -110 -487 -411 -419 -1112 -1128 -910 -31 383 693 636 1092 694 103 336 679 130 1158 274 -650 -553 -174 135 241 -329 198 1166 645 817 623 -273 -541 -25 790 -579 55 -6 155 195 -178 -614 -1079 -126 SS 20251222T165624.1Z 9487.705834 165 1 5.38 2 64.81 165.83 77.51 136.92 0.00 1 0.00 1 0 17 9.869e-03 5.619e-03 1.431e-03 6.691e-04 2.917088e-01 3.369261e-04 3.551280e-03 -6.000000e+00 5.586211e-03 223.06 -2.00 3.49 -2.00 316.35 0.00e+00 5.368877e-04 3.801256e-05 9.518612e-05 -6.000000e+00 2.434775e-04 276.24 -2.00 20.00 -2.00 315.78 0.00e+00 2.335 0.000 302.00 328.00 3 4.7188e-01 8.6680e-04 2.6912e-02 -6.0000e+00 1.3766e-02 2.4094e-02 9.6948e-04 1.4573e-02 -6.0000e+00 1.4970e-02 -1.5321e-02 5.6679e-04 7.2751e-03 -6.0000e+00 8.9143e-03 1.6582e-03 2.7063e-04 2.1285e-03 -6.0000e+00 3.8395e-03 2.3968e-02 -2.2144e-04 1.8842e-05 2.5137e-05 -6.0000e+00 2.6715e-04 -1.1404e-02 0.0000e+00 12 1 1 12 1 1 99.26 24.57 0.27 -0.01140 -0.01307 111 126 1 5 0 47.980 33.50 20.02 24.57 8.56 2.3 1065.27 -1125 -1916 -2584 -3035 -3637 -4282 -1323 -732 -1385 -1205 -2171 -2209 -1220 -480 414 94 370 279 1090 1181 1248 874 1658 1584 731 11 -744 -251 -511 397 885 1600 664 -125 -1590 -2066 -1338 -510 9 -265 -581 -694 -1027 -623 -397 -188 -262 -394 -237 84 1080 1188 1470 1222 1332 967 1025 746 494 587 952 1102 1357 897 420 -197 -526 -114 274 450 181 -40 -20 -2 -24 -239 -603 -730 -610 -641 -864 -1407 -1553 -1481 -1103 -701 -544 -140 89 248 382 67 141 200 134 118 132 67 -18 -538 -673 -755 -626 -324 -700 -552 -665 -105 283 699 684 658 601 486 408 466 408 530 215 105 -207 59 -130 301 296 162 434 537 403 194 -113 -43 -184 -72 -129 -98 -10 28 -55 -211 -283 -309 -327 -196 -377 -493 -560 -656 -723 -223 -137 -272 -253 -462 -477 -289 -122 120 29 120 94 383 403 437 306 581 583 289 4 -297 -101 -194 144 334 657 284 -57 -705 -877 -592 -243 5 -154 -361 -459 -674 -414 -263 -124 -172 -266 -157 56 735 831 1051 925 1007 752 815 597 389 455 746 880 1137 787 381 -172 -438 -94 233 398 173 -39 -20 -2 -22 -212 -520 -610 -495 -557 -824 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