File name: Pandora83s1_BondvilleIL_20260116_L2Fit_fout2c8d20241002p1-8.txt File generation date: 20260117T061323.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Kevin Mishoe Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 83 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora83_OF_v4d20231115.txt Instrument calibration file used: Pandora83s1_CF_v8d20241002.txt Level 1 file used: Pandora83s1_BondvilleIL_20260116_L1_smca1c8d20241002p1-8.txt Full location name: Bondville, Illinois EPA Castnet Site Short location name: BondvilleIL Country of location: United States Location latitude [deg]: 40.0520 Location longitude [deg]: -88.3725 Location altitude [m]: 213 Local noon date: 20260116 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0376 305.1782 305.3189 305.4595 305.6001 305.7407 305.8813 306.0219 306.1625 306.3031 306.4436 306.5841 306.7247 306.8652 307.0057 307.1462 307.2867 307.4271 307.5676 307.7081 307.8485 307.9889 308.1293 308.2697 308.4101 308.5505 308.6909 308.8312 308.9716 309.1119 309.2522 309.3925 309.5328 309.6731 309.8134 309.9537 310.0939 310.2342 310.3744 310.5146 310.6548 310.7950 310.9352 311.0754 311.2155 311.3557 311.4958 311.6359 311.7761 311.9162 312.0563 312.1963 312.3364 312.4765 312.6165 312.7565 312.8966 313.0366 313.1766 313.3166 313.4565 313.5965 313.7365 313.8764 314.0163 314.1563 314.2962 314.4361 314.5760 314.7158 314.8557 314.9955 315.1354 315.2752 315.4150 315.5548 315.6946 315.8344 315.9742 316.1139 316.2537 316.3934 316.5331 316.6728 316.8125 316.9522 317.0919 317.2316 317.3712 317.5109 317.6505 317.7901 317.9297 318.0693 318.2089 318.3485 318.4880 318.6276 318.7671 318.9066 319.0462 319.1857 319.3251 319.4646 319.6041 319.7435 319.8830 320.0224 320.1618 320.3013 320.4407 320.5800 320.7194 320.8588 320.9981 321.1375 321.2768 321.4161 321.5554 321.6947 321.8340 321.9733 322.1125 322.2518 322.3910 322.5302 322.6694 322.8086 322.9478 323.0870 323.2262 323.3653 323.5045 323.6436 323.7827 323.9218 324.0609 324.2000 324.3391 324.4781 324.6172 324.7562 324.8952 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260116T143248.7Z 9512.606119 105 1 20.34 2 78.16 130.65 73.19 156.34 0.00 1 0.00 1 0 33 6.375e-01 6.057e-02 1.943e-01 7.773e-03 7.337714e-01 4.274864e-03 9.583451e-03 -6.000000e+00 3.673926e-01 223.79 -2.00 3.49 -2.00 320.86 0.00e+00 -3.584607e-02 1.743456e-03 1.220926e-02 -6.000000e+00 2.271823e-02 274.77 -2.00 20.00 -2.00 320.36 0.00e+00 4.726 0.002 302.00 328.00 3 3.2444e+00 1.3392e-02 1.0526e-01 -6.0000e+00 9.0740e-01 5.1878e-01 1.7531e-02 1.3515e-01 -6.0000e+00 9.8940e-01 -8.9366e-01 1.6980e-02 2.0546e-02 -6.0000e+00 5.8421e-01 3.8930e-01 8.4703e-03 4.1848e-02 -6.0000e+00 2.5523e-01 9.9364e-05 -1.3867e-03 2.2156e-04 2.2313e-04 -6.0000e+00 1.8377e-02 -8.4932e-03 0.0000e+00 12 9 9 12 1 1 99.70 24.45 -0.20 -0.00849 -0.01891 7 2 1 5 0 2542.070 33.50 20.00 24.45 2.92 2.4 998.11 -13416 52981 900000 900000 900000 -12977 13437 900000 60885 900000 900000 900000 900000 65971 900000 227205 63333 21497 148781 54340 25360 900000 97149 67976 64218 900000 900000 170310 142620 348110 139017 164966 144040 98838 109735 18045 66004 51122 84280 115518 155202 87797 67847 -94013 58659 51239 145361 45507 48018 27781 35516 19259 34137 49520 49373 52077 33095 61995 43117 34529 62301 25927 27969 15179 24142 7137 10065 14654 16690 7596 15868 12273 9118 25821 14840 10529 10503 3702 -6609 395 -6818 -5444 1911 -12038 -3612 2445 1451 1440 272 -2132 126 -4348 -1203 10505 -1026 -3236 -1805 -7711 -5976 -7521 -4253 -1773 -2759 -4585 -1072 -3509 -3432 -2266 -775 -850 923 723 701 695 3695 2993 1665 582 -285 1223 1517 2250 318 2043 1255 635 5109 -938 759 329 899 -80 -1861 507 -276 1722 -123 -684 391 529 -1085 -2143 -1170 -387 801 900000 900000 900000 -268 249 900000 1214 900000 900000 900000 900000 1678 900000 1718 1829 946 2025 1890 1170 900000 2351 2725 3400 900000 900000 3220 2912 2633 2523 2495 2941 3364 3236 1269 3045 3286 5035 6465 6925 8300 7799 -46601 6344 5502 5716 4680 4830 3572 4620 3306 5602 7677 8438 9491 7884 11346 9097 7233 9187 5529 6324 4305 6664 2310 3068 4355 5314 3056 6636 5172 4012 10115 5937 3902 3503 1271 -2644 168 -3319 -3028 1115 -8765 -2583 1756 1109 1136 217 -1677 91 -3076 -793 6233 -745 -2736 -1721 -8120 -6861 -9105 -4793 -1936 -2745 -4495 -1076 -3876 -3655 -2528 -924 -1138 1369 1085 1094 1075 5759 4461 2454 887 -460 1882 2344 3618 498 3047 1825 895 6581 -1279 1114 510 1549 -150 -3764 987 -581 3779 -283 -1607 910 1194 -2334 -4313 -2361 SS 20260116T170353.2Z 9512.711033 200 1 53.90 2 62.45 164.31 69.77 190.12 0.00 1 0.00 1 0 17 1.473e-02 5.596e-03 7.687e-04 2.359e-04 3.571937e-01 1.187108e-04 4.310693e-03 -6.000000e+00 8.362413e-03 223.79 -2.00 3.49 -2.00 317.17 0.00e+00 6.319953e-04 1.631514e-05 1.564633e-04 -6.000000e+00 3.613155e-04 274.77 -2.00 20.00 -2.00 316.60 0.00e+00 2.151 0.000 302.00 328.00 3 7.3150e-01 3.0962e-04 2.7570e-02 -6.0000e+00 2.0651e-02 2.0903e-02 3.4762e-04 1.7844e-02 -6.0000e+00 2.2451e-02 -1.3790e-02 2.1175e-04 8.9675e-03 -6.0000e+00 1.3351e-02 2.5960e-04 1.0653e-04 2.6416e-03 -6.0000e+00 5.7339e-03 1.9571e-02 -1.5260e-04 6.5859e-06 2.9304e-05 -6.0000e+00 3.9889e-04 -1.1544e-02 0.0000e+00 10 0 0 10 0 0 99.98 24.61 0.24 -0.01154 -0.01269 1612 181 1 5 0 33.430 33.50 19.99 24.61 6.55 2.3 1027.03 -4471 -3860 -4650 -4791 -5805 -5958 -4618 -3335 -2675 -3259 -3722 -3224 -2106 -1141 -80 61 552 631 1338 1213 1128 881 1371 1139 416 -32 -524 -828 -742 211 668 1582 840 -291 -1788 -2342 -1590 -668 -330 -380 -618 -741 -897 -741 -253 -109 31 -151 -87 421 1005 1283 1406 1322 1316 1106 913 674 529 490 1025 1165 1510 1133 466 -33 -382 117 385 394 127 -48 -10 -144 -99 -290 -435 -519 -568 -596 -794 -1290 -1555 -1547 -1207 -691 -453 -260 -25 279 377 257 314 365 370 53 184 69 -128 -542 -804 -754 -601 -329 -760 -765 -752 -103 253 694 734 664 550 493 393 571 458 497 199 15 -327 -73 -149 245 221 149 416 581 435 198 -72 -9 -137 -1 -115 -102 -22 32 -47 -149 -290 -331 -285 -421 -412 -527 -528 -583 -562 -445 -357 -322 -424 -495 -439 -320 -203 -15 13 129 155 318 301 288 225 353 311 123 -10 -166 -253 -214 59 198 518 285 -106 -642 -808 -573 -257 -144 -196 -339 -410 -516 -434 -147 -64 18 -87 -50 242 605 791 930 884 921 798 676 503 388 352 743 854 1211 949 391 -28 -301 93 317 335 115 -46 -10 -136 -92 -255 -361 -405 -454 -509 -744 -1253 -1586 -1665 -1321 -776 -540 -311 -30 339 430 279 324 374 394 58 218 85 -167 -728 -1066 -945 -716 -386 -923 -964 -993 -137 354 1005 1076 1017 838 735 560 780 629 678 279 22 -494 -110 -217 353 315 203 552 754 597 278 -107 -13 -210 -2 -187 -171 -37 54 -82 -256 -494 -539 -458 SS 20260116T171300.5Z 9512.717367 203 1 1.01 2 62.01 166.67 70.09 192.17 0.00 1 0.00 1 0 17 2.944e-02 8.583e-03 2.318e-02 6.940e-03 3.485328e-01 3.497876e-03 4.197808e-03 -6.000000e+00 1.671107e-02 223.79 -2.00 3.49 -2.00 317.20 0.00e+00 1.255142e-03 4.871342e-04 7.761451e-05 -6.000000e+00 7.220063e-04 274.77 -2.00 20.00 -2.00 316.65 0.00e+00 2.120 0.000 302.00 328.00 3 2.8243e+00 9.1226e-03 2.7070e-02 -6.0000e+00 4.1268e-02 2.8750e-02 1.0229e-02 1.7476e-02 -6.0000e+00 4.4864e-02 -4.6801e-03 6.2458e-03 8.7477e-03 -6.0000e+00 2.6678e-02 -2.7475e-03 3.1570e-03 2.7248e-03 -6.0000e+00 1.1459e-02 2.4914e-03 4.4604e-06 1.9450e-04 2.9121e-05 -6.0000e+00 7.9701e-04 -1.2183e-02 0.0000e+00 12 9 1 12 1 1 999.00 24.60 0.15 -0.01218 -0.01215 1 12 1 5 0 500.820 33.50 20.01 24.60 7.17 2.3 1032.10 -10957 9368 -9275 -2264 -1325 -16237 -16481 892 -4169 -5676 -1895 2443 3782 2757 198 4602 -4830 -2599 -2271 339 3472 4991 1457 2341 -1061 -3945 2549 -1152 1814 1387 2673 593 3189 -2701 -631 -4038 264 464 -61 -1400 -1062 -2792 -398 -1235 -636 1464 862 1539 1626 -743 2750 544 1248 -9 1143 1488 1701 1142 -419 188 1966 598 1613 -92 -645 229 -920 277 1054 -568 -1141 -331 40 -351 1180 254 1428 -931 -1234 -242 169 -1245 -2187 -1490 -1374 -1176 -721 913 -291 -228 836 402 -363 1191 381 274 -281 880 -1198 87 -1167 -374 -47 -592 -162 -1093 -327 -380 -40 830 1492 1249 797 347 -80 511 49 652 -164 871 -416 100 247 -1132 34 -865 454 -32 361 -51 -362 -26 216 396 -109 498 105 -18 -333 -390 -520 -228 275 -1072 853 -1073 -237 -124 -1648 -1734 88 -490 -726 -237 301 519 453 36 914 -1139 -632 -580 88 899 1270 388 651 -301 -1210 742 -335 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