File name: Pandora155s1_BostonMA_20240619_L2Fit_fout2c2d20231025p1-8.txt File generation date: 20240902T142808.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Jeff Gedes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 155 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora155_OF_v4d20190702.txt Instrument calibration file used: Pandora155s1_CF_v2d20231025.txt Level 1 file used: Pandora155s1_BostonMA_20240619_L1_smca1c2d20231025p1-8.txt Full location name: Boston University Short location name: BostonMA Country of location: USA Location latitude [deg]: 42.3497 Location longitude [deg]: -71.1040 Location altitude [m]: 40 Local noon date: 20240619 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.1059 305.2467 305.3875 305.5283 305.6692 305.8100 305.9507 306.0915 306.2323 306.3730 306.5138 306.6545 306.7952 306.9359 307.0766 307.2173 307.3580 307.4987 307.6393 307.7800 307.9206 308.0612 308.2018 308.3424 308.4830 308.6236 308.7641 308.9047 309.0452 309.1857 309.3263 309.4668 309.6073 309.7477 309.8882 310.0287 310.1691 310.3096 310.4500 310.5904 310.7308 310.8712 311.0116 311.1519 311.2923 311.4326 311.5730 311.7133 311.8536 311.9939 312.1342 312.2745 312.4148 312.5550 312.6953 312.8355 312.9757 313.1159 313.2561 313.3963 313.5365 313.6767 313.8168 313.9569 314.0971 314.2372 314.3773 314.5174 314.6575 314.7976 314.9376 315.0777 315.2177 315.3577 315.4978 315.6378 315.7778 315.9177 316.0577 316.1977 316.3376 316.4776 316.6175 316.7574 316.8973 317.0372 317.1771 317.3169 317.4568 317.5966 317.7365 317.8763 318.0161 318.1559 318.2957 318.4355 318.5752 318.7150 318.8547 318.9945 319.1342 319.2739 319.4136 319.5533 319.6930 319.8326 319.9723 320.1119 320.2515 320.3912 320.5308 320.6704 320.8099 320.9495 321.0891 321.2286 321.3682 321.5077 321.6472 321.7867 321.9262 322.0657 322.2051 322.3446 322.4840 322.6235 322.7629 322.9023 323.0417 323.1811 323.3204 323.4598 323.5992 323.7385 323.8778 324.0171 324.1565 324.2957 324.4350 324.5743 324.7136 324.8528 324.9920 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240619T102527.3Z 8936.434344 152 1 50.88 2 78.03 69.10 127.62 271.59 0.00 1 0.00 1 0 17 4.460e-01 3.123e-02 3.334e-01 1.022e-02 6.193854e-01 5.574256e-03 7.833365e-03 -6.000000e+00 2.617804e-01 232.96 -2.00 3.54 -2.00 321.33 0.00e+00 1.581772e-02 2.713921e-03 2.885789e-03 -6.000000e+00 1.159007e-02 286.12 -2.00 20.00 -2.00 320.69 0.00e+00 4.673 0.002 302.00 328.00 3 3.5076e+00 1.9466e-02 5.7542e-02 -6.0000e+00 6.5751e-01 2.4343e-01 2.5939e-02 3.4246e-02 -6.0000e+00 7.1184e-01 -1.7428e-01 2.4087e-02 2.6050e-02 -6.0000e+00 4.2314e-01 2.9653e-02 1.1411e-02 1.8510e-02 -6.0000e+00 1.7636e-01 7.0284e-05 1.2659e-03 3.0256e-04 2.2745e-04 -6.0000e+00 1.2606e-02 -6.7002e-03 0.0000e+00 12 8 8 10 0 0 97.29 19.05 0.45 -0.00670 0.00281 21 4 1 5 0 2422.480 21.98 15.01 19.05 28.84 3.4 1003.18 -84877 -34168 5038 -109541 -110539 -149048 -86305 -187033 -75012 -109571 -115103 -110487 -70522 -112811 -65012 -43475 -3894 49705 -61150 38112 -45395 -4893 -52014 -1714 -70727 269928 -62450 18837 -40167 -24521 5089 2660 -75 -25189 19310 -21299 32030 -15024 10685 1919 9098 -15960 3963 9791 12332 9359 2018 18248 34409 21044 2031 10863 7751 19068 3714 14249 -978 10514 -3450 -1811 5963 5255 15644 11571 9894 5082 9585 3488 10061 4882 5317 4028 3877 1930 128 -1034 -1867 -1140 125 -46570 -2706 3107 -3583 1822 511 499 2007 1730 2812 4171 177 -1546 532 -774 21 1105 3387 3669 1305 -297 770 -2179 -700 1580 -650 -2881 -644 -269 876 1260 512 731 -22 -771 -1783 -141 -981 1222 398 512 -1074 297 111 -709 287 -278 -956 566 1418 372 402 512 371 -491 -11 -620 65 467 -17 -1243 -33 265 510 -846 -340 50 -1170 -1102 -2122 -860 -4260 -747 -1248 -1475 -1651 -954 -3132 -1435 -928 -64 572 -2133 515 -1422 -101 -1740 -35 -2970 2690 -2489 335 -1372 -838 159 102 -3 -1488 701 -1182 1163 -1027 669 150 725 -1749 378 920 1176 959 231 1857 3135 2367 306 1655 1319 3081 722 2536 -203 1916 -712 -375 1231 1234 3775 3204 2845 1490 2668 1078 3258 1758 2049 1603 1496 708 46 -344 -601 -383 48 -31464 -1363 1653 -2190 1116 338 351 1451 1278 2031 2827 116 -964 316 -492 15 912 3159 3851 1482 -335 790 -2071 -618 1412 -636 -3040 -705 -317 1123 1791 796 1169 -35 -1173 -2590 -196 -1413 1817 633 835 -1748 460 166 -1028 396 -371 -1268 793 2226 657 768 1032 788 -1120 -26 -1570 168 1214 -45 -3101 -78 585 1112 SS 20240619T103038.7Z 8936.437948 155 1 17.75 2 77.13 69.90 128.55 272.45 0.00 1 0.00 1 0 17 3.056e-01 1.142e-02 2.340e-01 7.682e-03 5.976827e-01 4.120015e-03 6.696118e-03 -6.000000e+00 1.793900e-01 232.96 -2.00 3.54 -2.00 320.93 0.00e+00 1.638162e-03 1.798402e-03 1.044453e-03 -6.000000e+00 8.011827e-03 286.12 -2.00 20.00 -2.00 320.26 0.00e+00 4.371 0.002 302.00 328.00 3 3.1758e+00 1.3459e-02 5.4309e-02 -6.0000e+00 4.5055e-01 9.8762e-02 1.7440e-02 3.2488e-02 -6.0000e+00 4.8775e-01 -1.6336e-01 1.5872e-02 1.6408e-02 -6.0000e+00 2.9000e-01 5.7171e-02 7.7152e-03 4.9881e-03 -6.0000e+00 1.2099e-01 1.4906e-04 2.1844e-04 2.2569e-04 6.2702e-05 -6.0000e+00 8.6578e-03 -7.6311e-03 0.0000e+00 12 9 9 12 1 1 55.21 19.06 0.67 -0.00763 -0.00599 11 6 1 5 0 1478.420 21.98 15.00 19.06 28.99 3.4 1004.16 -126129 -140597 24168 -131595 -57577 -148041 -62122 -55958 -4452 -107780 -18297 -102775 900000 -42728 17787 -4421 -26175 -12112 -36752 29795 -18164 32758 -35795 43671 -46876 -12446 -30288 -3157 -14480 -13898 -8571 5558 31487 -21538 15333 -15899 -2653 -21421 16283 -8904 19657 -2735 11432 4546 -628 678 3805 2804 265 8465 2660 8157 -3261 14737 -1244 8625 -3190 6030 4618 3577 5110 6209 2893 1358 4598 -247 4645 -4921 2751 -612 4428 1525 3023 -81 885 -2527 -3907 -3550 -595 -3223 -1150 -674 -1618 -1928 -249 977 -55 417 411 1151 -212 -1147 -654 -1559 -1530 -1815 634 102 558 -1025 -75 -975 787 3 -1886 -1318 -743 -1016 572 1141 -16 523 -677 1180 -348 1116 -644 64 -435 -633 -222 531 718 165 639 -180 885 1382 1182 -255 351 -518 268 100 -166 78 -95 222 -286 -254 -175 45 -479 -1975 -2633 181 -2419 -470 -3024 -592 -572 -33 -2202 -162 -2449 900000 -873 242 -87 -713 -313 -1301 568 -569 625 -1438 862 -2458 -483 -1402 -107 -552 -577 -397 261 1286 -1540 731 -1061 -175 -1885 1308 -989 1816 -336 1270 551 -81 88 487 373 38 1194 442 1420 -694 2824 -294 1922 -816 1393 1055 824 1218 1624 881 460 1539 -84 1490 -1815 1054 -276 2062 753 1438 -37 367 -981 -1458 -1363 -251 -1644 -664 -436 -1054 -1340 -182 752 -45 346 337 892 -155 -859 -472 -1192 -1214 -1663 652 119 684 -1251 -84 -998 748 3 -2050 -1503 -892 -1311 798 1630 -25 846 -1092 1781 -503 1659 -922 96 -696 -1046 -361 827 1079 239 957 -261 1246 2058 1837 -446 661 -1038 559 208 -369 181 -226 530 -679 -578 -376 99 -1037 SS 20240619T103553.0Z 8936.441585 158 1 50.50 2 76.22 70.71 129.48 273.32 0.00 1 0.00 1 0 17 2.272e-01 5.796e-03 1.170e-01 3.279e-03 5.647331e-01 1.762348e-03 6.410873e-03 -6.000000e+00 1.333312e-01 232.96 -2.00 3.54 -2.00 320.88 0.00e+00 2.894494e-03 7.628539e-04 1.127678e-03 -6.000000e+00 5.902814e-03 286.12 -2.00 20.00 -2.00 320.21 0.00e+00 4.101 0.001 302.00 328.00 3 2.6007e+00 5.7888e-03 5.1216e-02 -6.0000e+00 3.3489e-01 1.3745e-02 7.5136e-03 3.0877e-02 -6.0000e+00 3.6255e-01 -4.3760e-02 6.9658e-03 1.6129e-02 -6.0000e+00 2.1551e-01 5.7005e-03 3.3882e-03 5.7033e-03 -6.0000e+00 8.9827e-02 3.5728e-04 2.1578e-04 9.7540e-05 7.1209e-05 -6.0000e+00 6.4202e-03 -7.0708e-03 0.0000e+00 10 0 0 10 0 0 91.24 19.07 0.38 -0.00707 -0.00545 71 13 1 5 0 711.240 21.98 15.00 19.07 29.15 3.3 1005.67 -54375 -36520 -50055 -92298 -121586 -85071 -92963 -92454 -7114 -79227 -50251 -16484 -46305 -52832 -8478 -13835 -2990 -8076 -773 1832 -1039 -11195 -14794 -9570 -1522 -4512 -10375 -7051 -4579 -3239 -12023 -8957 -4804 -11019 -1119 -6568 -6907 869 1276 -1938 -1114 -98 -1254 1944 3096 1672 1344 2014 573 -172 494 1537 3022 2727 3035 3115 1126 -503 617 -268 -621 2849 2460 3031 1915 625 -519 329 1593 1182 623 301 852 40 -394 -931 -1320 -2024 -1493 -1685 -659 -1426 -2108 -1615 -603 58 295 617 1003 1152 583 56 -37 -44 -375 -154 439 775 103 -249 -751 -1049 26 -79 -495 -1542 -897 -512 186 384 287 300 300 23 189 12 33 153 235 -68 -302 271 373 -263 318 -103 -75 1082 323 233 45 -533 -142 -253 -67 -210 8 248 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