File name: Pandora155s1_BostonMA_20240904_L2Fit_fout2c9d20240425p1-8.txt File generation date: 20241210T083928.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Jeff Gedes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 155 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora155_OF_v6d20190702.txt Instrument calibration file used: Pandora155s1_CF_v9d20240425.txt Level 1 file used: Pandora155s1_BostonMA_20240904_L1_smca1c9d20240425p1-8.txt Full location name: Boston University Short location name: BostonMA Country of location: USA Location latitude [deg]: 42.3497 Location longitude [deg]: -71.1040 Location altitude [m]: 40 Local noon date: 20240904 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0903 305.2311 305.3720 305.5128 305.6537 305.7945 305.9353 306.0761 306.2169 306.3576 306.4984 306.6391 306.7799 306.9206 307.0613 307.2020 307.3427 307.4834 307.6241 307.7647 307.9054 308.0460 308.1866 308.3273 308.4679 308.6085 308.7490 308.8896 309.0302 309.1707 309.3113 309.4518 309.5923 309.7328 309.8733 310.0138 310.1543 310.2947 310.4352 310.5756 310.7160 310.8565 310.9969 311.1372 311.2776 311.4180 311.5584 311.6987 311.8390 311.9794 312.1197 312.2600 312.4003 312.5406 312.6808 312.8211 312.9613 313.1016 313.2418 313.3820 313.5222 313.6624 313.8026 313.9428 314.0829 314.2231 314.3632 314.5033 314.6434 314.7835 314.9236 315.0637 315.2038 315.3438 315.4839 315.6239 315.7639 315.9039 316.0439 316.1839 316.3239 316.4638 316.6038 316.7437 316.8837 317.0236 317.1635 317.3034 317.4433 317.5831 317.7230 317.8629 318.0027 318.1425 318.2823 318.4221 318.5619 318.7017 318.8415 318.9812 319.1210 319.2607 319.4005 319.5402 319.6799 319.8196 319.9592 320.0989 320.2386 320.3782 320.5178 320.6575 320.7971 320.9367 321.0762 321.2158 321.3554 321.4949 321.6345 321.7740 321.9135 322.0530 322.1925 322.3320 322.4715 322.6109 322.7504 322.8898 323.0292 323.1686 323.3080 323.4474 323.5868 323.7262 323.8655 324.0049 324.1442 324.2835 324.4228 324.5621 324.7014 324.8407 324.9800 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240904T123950.5Z 9013.527667 96 1 50.33 2 64.03 105.30 79.44 98.69 0.00 1 0.00 1 0 25 1.758e-02 6.041e-03 9.815e-04 2.192e-04 3.093103e-01 1.112653e-04 3.677383e-03 -6.000000e+00 1.021658e-02 230.07 -2.00 3.54 -2.00 318.11 0.00e+00 6.981385e-04 2.033884e-05 1.521706e-04 -6.000000e+00 4.595447e-04 287.51 -2.00 20.00 -2.00 317.28 0.00e+00 2.270 0.000 302.00 328.00 3 2.8223e-01 3.0032e-04 2.7897e-02 -6.0000e+00 2.5466e-02 1.3354e-02 3.4176e-04 1.6236e-02 -6.0000e+00 2.7623e-02 -2.7254e-03 2.1502e-04 7.8935e-03 -6.0000e+00 1.6475e-02 -4.9401e-03 1.0875e-04 2.2357e-03 -6.0000e+00 6.9180e-03 2.8488e-02 2.9707e-04 6.5104e-06 2.4523e-05 -6.0000e+00 4.9664e-04 4.2155e-03 0.0000e+00 10 0 0 10 0 0 21.24 23.17 0.34 0.00422 0.00645 2019 390 1 5 0 24.900 26.21 20.01 23.17 26.12 4.4 980.79 -3491 -3319 -3134 -6720 -6582 -7140 -4702 -4013 -3503 -5371 -5940 -4857 -2892 -1969 -461 -987 -572 533 411 1033 -439 216 809 536 -148 152 -972 -1461 -1250 214 723 1244 1265 -2209 -3443 -2819 -2578 -1215 -416 -620 -784 -325 -164 -196 751 275 130 155 -231 833 1285 1022 1250 1371 1005 1458 868 577 367 719 1228 1678 1825 1579 -13 -211 -142 -264 1141 240 116 221 108 298 -329 -496 -631 -970 -414 -1340 -1324 -1566 -2358 -1371 -963 -539 -222 58 290 258 395 227 110 601 138 62 468 576 -223 -515 -430 -748 88 184 -872 -989 -470 -561 320 429 491 145 375 199 270 485 377 235 188 -376 -537 13 191 134 551 210 590 1371 541 151 100 -301 -21 116 10 -340 111 139 -254 -268 -125 -479 -225 -252 -259 -247 -509 -453 -489 -340 -324 -310 -504 -564 -488 -327 -234 -62 -146 -89 86 69 179 -78 38 148 105 -31 32 -206 -294 -239 41 150 281 309 -561 -840 -691 -703 -387 -157 -270 -340 -147 -76 -92 349 128 60 77 -114 417 627 538 697 804 610 903 548 362 227 444 788 1163 1374 1258 -10 -156 -99 -185 864 190 99 196 95 248 -275 -373 -437 -661 -303 -1123 -1151 -1500 -2422 -1472 -1025 -610 -263 70 347 294 447 236 106 578 144 67 562 760 -309 -697 -541 -869 97 214 -1106 -1324 -656 -769 462 661 794 236 585 288 388 664 523 320 276 -582 -840 20 283 190 791 289 777 1844 791 222 155 -481 -34 198 16 -607 202 259 -473 -482 -216 -799 -370 SS 20240904T124156.7Z 9013.529129 98 1 50.27 2 63.66 105.70 79.07 99.06 0.00 1 0.00 1 0 17 1.703e-02 5.993e-03 9.308e-04 2.143e-04 3.055531e-01 1.087668e-04 3.633725e-03 -6.000000e+00 9.894637e-03 230.07 -2.00 3.54 -2.00 318.06 0.00e+00 6.794583e-04 1.957835e-05 1.470230e-04 -6.000000e+00 4.450505e-04 287.51 -2.00 20.00 -2.00 317.23 0.00e+00 2.240 0.000 302.00 328.00 3 2.7300e-01 2.9318e-04 2.7540e-02 -6.0000e+00 2.4664e-02 1.3032e-02 3.3338e-04 1.6032e-02 -6.0000e+00 2.6753e-02 -2.4395e-03 2.0882e-04 7.7909e-03 -6.0000e+00 1.5956e-02 -4.9184e-03 1.0535e-04 2.2031e-03 -6.0000e+00 6.7002e-03 2.9754e-02 3.0637e-04 6.3693e-06 2.4326e-05 -6.0000e+00 4.8098e-04 4.0389e-03 0.0000e+00 10 0 0 10 0 0 11.14 23.19 0.33 0.00404 0.00634 2090 404 1 5 0 24.050 26.21 20.01 23.19 26.45 4.4 983.67 -2869 -2928 -3598 -6334 -6868 -6661 -4798 -3373 -3345 -5057 -6002 -4332 -3115 -1835 -605 -930 -459 481 400 977 -222 270 974 385 -21 13 -737 -1455 -1060 227 863 1045 1296 -2391 -3304 -2707 -2527 -1169 -440 -639 -719 -272 -228 -116 706 291 87 138 -241 901 1330 992 1243 1279 1015 1410 934 526 375 704 1226 1714 1804 1491 -43 -161 -157 -274 1106 241 89 209 31 289 -342 -441 -684 -946 -374 -1248 -1353 -1549 -2326 -1386 -931 -586 -222 26 306 214 367 225 129 570 188 72 455 602 -200 -504 -442 -719 69 206 -862 -958 -497 -555 293 411 457 132 367 211 281 484 415 204 227 -364 -506 6 206 123 570 196 622 1362 550 162 79 -314 -34 119 -5 -305 98 102 -260 -254 -125 -481 -215 -214 -237 -295 -496 -492 -471 -360 -281 -306 -490 -590 -447 -364 -224 -84 -141 -73 80 69 175 -41 49 183 77 -4 3 -160 -300 -207 45 182 241 322 -620 -820 -675 -701 -379 -170 -284 -317 -125 -108 -55 333 138 40 69 -121 457 657 529 702 760 623 883 596 334 234 440 796 1199 1372 1200 -34 -120 -111 -194 843 193 77 187 28 243 -266 -334 -477 -649 -275 -1050 -1182 -1490 -2398 -1493 -994 -665 -263 32 368 245 417 234 125 549 196 78 547 795 -278 -683 -557 -836 76 240 -1095 -1284 -694 -760 423 633 739 215 572 306 403 661 574 277 331 -562 -791 9 304 173 818 268 817 1827 803 238 122 -498 -55 202 -8 -543 179 189 -482 -455 -216 -800 -353 SS 20240904T124402.2Z 9013.530581 100 1 50.44 2 63.29 106.11 78.70 99.42 0.00 1 0.00 1 0 17 1.667e-02 6.032e-03 8.801e-04 2.094e-04 3.013627e-01 1.062489e-04 3.587075e-03 -6.000000e+00 9.686138e-03 230.07 -2.00 3.54 -2.00 318.01 0.00e+00 6.678502e-04 1.882200e-05 1.353174e-04 -6.000000e+00 4.356698e-04 287.51 -2.00 20.00 -2.00 317.17 0.00e+00 2.212 0.000 302.00 328.00 3 2.6743e-01 2.8579e-04 2.7179e-02 -6.0000e+00 2.4144e-02 1.2330e-02 3.2480e-04 1.5809e-02 -6.0000e+00 2.6189e-02 -1.8042e-03 2.0253e-04 7.6810e-03 -6.0000e+00 1.5619e-02 -5.1347e-03 1.0190e-04 2.1716e-03 -6.0000e+00 6.5590e-03 3.0959e-02 2.9611e-04 6.2239e-06 2.4205e-05 -6.0000e+00 4.7084e-04 4.0033e-03 0.0000e+00 10 0 0 10 0 0 17.03 23.20 0.33 0.00400 0.00623 2128 411 1 5 0 23.620 26.21 20.01 23.20 26.76 4.4 986.15 -2946 -2606 -3047 -6326 -6760 -6221 -4605 -2942 -3429 -4800 -6524 -3973 -3025 -1549 -538 -627 -545 600 388 1132 -130 517 987 431 178 85 -477 -1535 -972 1 869 1161 1401 -2337 -3327 -2740 -2415 -1164 -473 -648 -837 -297 -287 -63 581 309 58 221 -204 866 1233 1055 1288 1299 1026 1421 941 482 401 670 1262 1641 1832 1500 -64 -206 -194 -343 1101 251 46 260 89 303 -399 -414 -717 -935 -360 -1223 -1330 -1491 -2365 -1367 -909 -601 -225 43 336 231 421 217 126 586 205 62 483 591 -231 -505 -450 -717 63 211 -854 -966 -526 -526 342 418 465 145 375 216 277 488 404 221 226 -417 -519 -35 204 136 604 202 615 1338 545 147 110 -322 -35 107 8 -317 85 122 -240 -261 -124 -480 -223 -229 -219 -259 -515 -504 -455 -358 -253 -326 -481 -669 -423 -366 -195 -77 -98 -90 102 69 208 -24 97 190 89 39 19 -106 -325 -195 0 188 273 356 -619 -843 -697 -682 -384 -186 -293 -377 -139 -138 -30 279 149 28 112 -103 445 618 569 736 781 638 901 608 310 253 424 828 1162 1409 1126 -52 -155 -138 -245 846 202 40 233 79 257 -313 -316 -504 -645 -267 -1033 -1167 -1440 -2449 -1479 -975 -686 -268 52 405 266 446 226 122 567 214 67 581 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