File name: Pandora155s1_BostonMA_20241126_L2Fit_fout2c9d20240425p1-8.txt File generation date: 20241210T104713.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Jeff Gedes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 155 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora155_OF_v6d20190702.txt Instrument calibration file used: Pandora155s1_CF_v9d20240425.txt Level 1 file used: Pandora155s1_BostonMA_20241126_L1_smca1c9d20240425p1-8.txt Full location name: Boston University Short location name: BostonMA Country of location: USA Location latitude [deg]: 42.3497 Location longitude [deg]: -71.1040 Location altitude [m]: 40 Local noon date: 20241126 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0903 305.2311 305.3720 305.5128 305.6537 305.7945 305.9353 306.0761 306.2169 306.3576 306.4984 306.6391 306.7799 306.9206 307.0613 307.2020 307.3427 307.4834 307.6241 307.7647 307.9054 308.0460 308.1866 308.3273 308.4679 308.6085 308.7490 308.8896 309.0302 309.1707 309.3113 309.4518 309.5923 309.7328 309.8733 310.0138 310.1543 310.2947 310.4352 310.5756 310.7160 310.8565 310.9969 311.1372 311.2776 311.4180 311.5584 311.6987 311.8390 311.9794 312.1197 312.2600 312.4003 312.5406 312.6808 312.8211 312.9613 313.1016 313.2418 313.3820 313.5222 313.6624 313.8026 313.9428 314.0829 314.2231 314.3632 314.5033 314.6434 314.7835 314.9236 315.0637 315.2038 315.3438 315.4839 315.6239 315.7639 315.9039 316.0439 316.1839 316.3239 316.4638 316.6038 316.7437 316.8837 317.0236 317.1635 317.3034 317.4433 317.5831 317.7230 317.8629 318.0027 318.1425 318.2823 318.4221 318.5619 318.7017 318.8415 318.9812 319.1210 319.2607 319.4005 319.5402 319.6799 319.8196 319.9592 320.0989 320.2386 320.3782 320.5178 320.6575 320.7971 320.9367 321.0762 321.2158 321.3554 321.4949 321.6345 321.7740 321.9135 322.0530 322.1925 322.3320 322.4715 322.6109 322.7504 322.8898 323.0292 323.1686 323.3080 323.4474 323.5868 323.7262 323.8655 324.0049 324.1442 324.2835 324.4228 324.5621 324.7014 324.8407 324.9800 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241126T124056.1Z 9096.528427 142 1 51.16 2 82.78 127.31 48.88 171.81 0.00 1 0.00 1 0 25 5.131e-01 2.909e-02 4.505e-01 2.962e-02 7.826826e-01 1.681212e-02 8.661372e-03 -6.000000e+00 2.962594e-01 222.76 -2.00 3.54 -2.00 322.04 0.00e+00 3.475144e-03 8.984448e-03 3.127032e-03 -6.000000e+00 1.505039e-02 277.83 -2.00 20.00 -2.00 321.54 0.00e+00 7.340 0.007 302.00 328.00 3 2.3274e+00 6.1231e-02 8.4407e-02 -6.0000e+00 7.2978e-01 8.3234e-01 8.1608e-02 4.4590e-02 -6.0000e+00 8.0072e-01 -1.0972e+00 7.3220e-02 2.5830e-02 -6.0000e+00 4.7275e-01 4.3723e-01 3.4912e-02 9.5720e-03 -6.0000e+00 2.0629e-01 1.6512e-05 -9.8249e-04 8.7922e-04 1.4851e-04 -6.0000e+00 1.5169e-02 8.5025e-03 0.0000e+00 12 8 8 10 0 0 92.83 22.17 0.64 0.00850 0.00112 22 4 1 5 0 2325.160 25.39 20.41 22.17 12.36 4.8 877.59 900000 900000 900000 900000 900000 141268 900000 -155904 900000 15146 -108035 -153060 -114120 900000 120943 -20053 72465 900000 64492 50193 14167 29896 900000 6549 -19526 63194 -59722 -1126 84965 -94219 -4421 219285 -22622 -21731 29343 152825 -22302 -18424 222051 23777 174701 58531 -11386 26140 5810 6119 96074 7638 -44761 53524 30145 45836 18423 31707 53084 -17767 29732 18460 21356 32011 6673 24343 -6921 24333 7503 32688 10366 1478 1334 5248 6444 12621 4398 2243 -5223 6142 14589 5509 2699 -776 -5732 -2296 8020 -4068 6628 -1620 4240 -2335 5810 -3061 8923 1167 5462 -4595 5437 -4556 -5567 -5422 3472 -5945 -4236 -1010 -3275 4563 -4447 -2051 -1756 289 -1313 651 -450 505 -3546 -540 -1974 1418 3788 -1348 2353 348 1636 2251 586 2510 133 -2293 3082 -833 780 1167 174 760 -883 -317 161 -98 1129 667 -670 625 -202 -825 -2057 900000 900000 900000 900000 900000 4073 900000 -7262 900000 437 -3355 -8487 -5316 900000 3487 -623 2090 900000 1860 1447 408 862 900000 189 -751 1822 -3047 -32 2450 -6896 -170 6323 -1359 -1305 987 4407 -1340 -1240 6403 1428 5037 2813 -1035 1759 475 500 3232 642 -6156 3215 2535 3635 2081 3352 4720 -3034 3429 2307 2463 3231 898 3042 -1243 3562 1348 4870 1793 295 299 1280 1672 3135 1141 547 -1228 1158 2629 1063 623 -222 -2021 -891 3060 -1859 2896 -812 2088 -1248 2822 -1548 3741 502 2241 -2252 2786 -3042 -4396 -4894 3080 -5723 -3711 -766 -2353 3097 -3541 -1688 -1539 270 -1407 781 -610 720 -5302 -762 -2706 1837 4907 -1938 3440 530 2395 3131 801 3262 172 -2934 3712 -1136 1209 2055 343 1594 -2001 -766 415 -263 3049 1827 -1828 1595 -485 -1863 -4623 SS 20241126T132339.3Z 9096.558094 159 1 18.76 2 76.86 135.46 48.88 185.71 0.00 1 0.00 1 0 25 2.693e-01 1.140e-02 1.974e-01 9.884e-03 5.038763e-01 5.039892e-03 5.839142e-03 -6.000000e+00 1.521293e-01 222.76 -2.00 3.54 -2.00 320.42 0.00e+00 1.146934e-03 1.828270e-03 6.374647e-04 -6.000000e+00 6.758805e-03 277.82 -2.00 20.00 -2.00 319.83 0.00e+00 4.289 0.001 302.00 328.00 3 3.9795e+00 1.5041e-02 4.9651e-02 -6.0000e+00 3.7407e-01 7.2334e-02 1.8661e-02 2.6116e-02 -6.0000e+00 4.0867e-01 -5.7889e-02 1.6862e-02 1.3341e-02 -6.0000e+00 2.4372e-01 1.6645e-02 8.5532e-03 4.0807e-03 -6.0000e+00 1.0290e-01 8.1080e-05 9.6054e-05 2.9517e-04 5.1512e-05 -6.0000e+00 7.5888e-03 7.7569e-03 0.0000e+00 12 9 9 12 1 1 99.94 22.26 0.22 0.00776 0.00848 7 4 1 5 0 2344.540 25.39 20.03 22.26 14.45 4.8 894.51 -78773 -76418 -100853 -62727 160048 -114901 -59971 -33496 -85945 -47932 -68820 -17242 10175 -53680 42145 10593 47530 68 -10683 56428 -31751 19198 -7262 -18374 -1401 -16127 -8139 -21275 1271 7439 7407 -1239 -11516 -277 956 -4704 9628 7130 8454 4557 -1738 1757 -657 20752 561 3873 -1985 -1935 2729 1333 962 6266 -2553 -825 3202 -2952 1735 -448 -1936 2736 352 1481 4874 516 4074 2167 1513 544 3661 -598 -855 1719 1915 1789 -1270 -2697 -2195 -1227 177 2621 -3966 489 -3489 17 -885 1257 -139 -432 -28 1135 1972 675 1561 4 -969 -1141 -205 -613 529 -2098 14 -29 -1680 186 -2039 -2560 -295 -792 76 1124 1301 516 1044 82 -416 -676 242 -393 -416 -388 -367 -187 1106 -134 602 899 390 1464 638 -241 237 173 296 391 300 -459 -175 238 159 -472 -467 228 -811 -1484 -1505 -2621 -1099 1543 -3034 -1051 -514 -2377 -1008 -1788 -317 174 -2047 776 306 1041 2 -461 1360 -1796 690 -344 -1055 -73 -1014 -471 -1346 63 374 428 -90 -1033 -23 75 -396 791 720 1024 642 -288 298 -119 3067 103 694 -380 -377 523 275 219 1487 -717 -244 952 -966 552 -144 -618 832 115 528 1877 216 1663 900 619 232 1618 -313 -485 979 1066 939 -627 -1271 -968 -546 87 1404 -2601 343 -2737 14 -738 1093 -128 -408 -26 994 1654 534 1174 3 -861 -1115 -226 -757 681 -2703 16 -30 -1724 195 -2346 -3121 -372 -1068 106 1713 2128 871 1713 128 -615 -965 348 -597 -673 -649 -609 -300 1700 -200 857 1268 541 2117 995 -417 421 322 574 800 631 -1015 -395 542 359 -1028 -999 462 -1645 SS 20241126T132436.1Z 9096.558751 161 1 50.39 2 76.74 135.65 48.90 186.01 0.00 1 0.00 1 0 25 1.527e-01 5.814e-03 5.797e-02 2.371e-03 5.062595e-01 1.215863e-03 5.836084e-03 -6.000000e+00 8.628215e-02 222.76 -2.00 3.54 -2.00 320.56 0.00e+00 2.947401e-03 4.626176e-04 4.241462e-04 -6.000000e+00 3.833395e-03 277.82 -2.00 20.00 -2.00 319.99 0.00e+00 4.252 0.001 302.00 328.00 3 1.9977e+00 3.6996e-03 4.9473e-02 -6.0000e+00 2.1216e-01 3.7186e-02 4.6417e-03 2.6469e-02 -6.0000e+00 2.3178e-01 -2.1620e-02 4.3553e-03 1.3825e-02 -6.0000e+00 1.3823e-01 -1.6791e-03 2.1976e-03 5.3612e-03 -6.0000e+00 5.8363e-02 6.1103e-04 -1.5282e-04 7.1246e-05 6.1469e-05 -6.0000e+00 4.3042e-03 7.8510e-03 0.0000e+00 10 0 0 10 0 0 99.98 22.27 0.31 0.00785 0.00670 240 46 1 5 0 209.910 25.47 20.17 22.27 14.52 4.8 895.69 -50872 -76489 -49390 -68864 -36331 -54136 -48916 -41581 -34260 -12199 -52779 -24920 -25085 -4043 -25396 -6291 -19961 -1062 -15944 -9559 -3132 -1529 -3207 -12861 -7165 -10373 -3628 -10532 293 -14633 2083 -2570 -275 -5259 -1587 -4809 -4944 -1985 -2892 2332 -1442 1852 -1730 1729 23 1594 -255 2526 -3975 2432 3487 1765 3373 1496 1608 1564 947 -14 1321 -665 1259 696 2918 1832 1104 735 805 526 1507 680 417 1509 -94 919 -1325 245 -1419 -917 -1284 -304 -1295 -1089 -1798 -1489 -1089 -737 -113 -62 885 542 1187 124 555 -298 -17 -519 393 575 -89 -282 -647 -496 -124 2 -1466 -1000 -980 -301 291 526 404 142 280 250 254 453 327 77 35 -733 -509 -258 568 15 743 -198 461 1091 490 51 12 -84 -73 96 -226 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