File name: Pandora204s1_BoulderCO-NCAR_20210918_L2Fit_fout2c2d20210826p1-8.txt File generation date: 20250127T104341.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: --- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora204_OF_v2d20210322.txt Instrument calibration file used: Pandora204s1_CF_v2d20210826.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20210918_L1_smca1c2d20210826p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20210918 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0564 305.1973 305.3381 305.4790 305.6198 305.7606 305.9014 306.0422 306.1829 306.3237 306.4645 306.6052 306.7459 306.8866 307.0273 307.1680 307.3087 307.4494 307.5901 307.7307 307.8713 308.0120 308.1526 308.2932 308.4338 308.5743 308.7149 308.8555 308.9960 309.1365 309.2771 309.4176 309.5581 309.6985 309.8390 309.9795 310.1199 310.2604 310.4008 310.5412 310.6816 310.8220 310.9624 311.1028 311.2431 311.3835 311.5238 311.6641 311.8044 311.9447 312.0850 312.2253 312.3656 312.5058 312.6461 312.7863 312.9265 313.0667 313.2069 313.3471 313.4873 313.6274 313.7676 313.9077 314.0478 314.1879 314.3280 314.4681 314.6082 314.7483 314.8883 315.0284 315.1684 315.3084 315.4484 315.5884 315.7284 315.8684 316.0083 316.1483 316.2882 316.4281 316.5681 316.7080 316.8478 316.9877 317.1276 317.2674 317.4073 317.5471 317.6869 317.8267 317.9665 318.1063 318.2461 318.3859 318.5256 318.6654 318.8051 318.9448 319.0845 319.2242 319.3639 319.5035 319.6432 319.7828 319.9225 320.0621 320.2017 320.3413 320.4809 320.6205 320.7600 320.8996 321.0391 321.1786 321.3182 321.4577 321.5971 321.7366 321.8761 322.0156 322.1550 322.2944 322.4339 322.5733 322.7127 322.8520 322.9914 323.1308 323.2701 323.4095 323.5488 323.6881 323.8274 323.9667 324.1060 324.2453 324.3845 324.5238 324.6630 324.8022 324.9414 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210918T131436.1Z 7931.551806 163 1 49.73 2 85.20 91.89 125.57 275.99 0.00 1 0.00 1 0 17 5.292e-01 3.509e-02 5.284e-01 3.316e-02 9.772173e-01 2.020840e-02 9.985557e-03 -6.000000e+00 3.145792e-01 227.95 -2.00 3.45 -2.00 322.43 0.00e+00 -5.509223e-03 8.514009e-03 1.291637e-03 -6.000000e+00 1.380268e-02 279.40 -2.00 20.00 -2.00 322.05 0.00e+00 10.155 0.018 302.00 328.00 3 4.9971e+00 6.7488e-02 9.8846e-02 -6.0000e+00 7.9272e-01 1.3531e+00 8.5480e-02 5.1035e-02 -6.0000e+00 8.7018e-01 -1.7264e+00 7.8049e-02 2.8522e-02 -6.0000e+00 5.0705e-01 6.6939e-01 4.0917e-02 9.9376e-03 -6.0000e+00 2.0808e-01 3.0609e-07 -1.1187e-03 9.8345e-04 1.3784e-04 -6.0000e+00 1.5617e-02 1.4752e-03 2.0064e-05 12 8 8 10 0 0 99.64 18.21 0.83 0.00148 -0.00693 23 5 1 5 0 2161.670 21.17 15.00 18.21 13.11 5.1 810.03 197147 63589 -50339 900000 55378 -25105 85848 900000 -87923 900000 -36865 -130972 -306 4383 900000 -92697 900000 89421 900000 52869 900000 73131 -14428 1396 900000 87357 -130696 900000 15616 157319 -14285 900000 161264 900000 10112 99097 -6629 900000 135912 -33546 128440 13578 900000 34648 79092 -20823 900000 33733 102116 3452 56631 25300 89191 18213 84666 68554 42665 58677 47290 200762 -6547 26697 -17284 10020 21670 21798 22610 -4410 81087 6708 18748 32762 60133 45072 39260 -14883 -8903 -15865 -18045 5218 16865 -7015 -6142 10879 4218 14075 -2632 14822 -6178 4993 10950 1220 811 -5789 -10208 -8688 5406 -1798 -1408 -8044 1755 -8499 -2033 -3621 -2046 -7147 -5240 4460 1075 -2431 -1855 1568 212 -203 108 1613 -1294 2436 -1537 -139 622 -195 5081 609 4207 646 2862 -3240 3276 1520 -720 -1687 -1143 882 -416 -439 151 2835 788 -776 -1088 -1210 -991 6358 2051 -1623 900000 1786 -810 2769 900000 -2836 900000 -1189 -7148 -10 141 900000 -6439 900000 2884 900000 1705 900000 2359 -465 45 900000 2817 -13618 900000 504 5074 -499 900000 5201 900000 353 3196 -267 900000 4383 -2885 4142 839 900000 1676 2551 -1623 900000 1541 3293 241 2587 1768 3596 1615 4096 4053 3325 3785 3177 6475 -686 2153 -2462 1239 2563 2578 2674 -723 6320 1262 3426 5371 7272 5814 4748 -2720 -1436 -2857 -3831 1066 3671 -2262 -2195 3509 1542 4918 -1045 5458 -2560 1919 3708 433 288 -2365 -4685 -4699 3017 -1262 -1097 -6824 1271 -6072 -1215 -2156 -1279 -5000 -3822 3220 910 -2490 -2186 1973 281 -271 140 2001 -1673 3185 -2208 -202 874 -261 6164 752 4874 755 3203 -4115 4576 2545 -1402 -3646 -2648 2166 -1118 -1245 434 8016 2254 -2141 -2776 -2836 -2208 SS 20210918T132635.5Z 7931.560133 166 1 49.36 2 82.91 93.83 127.73 278.09 0.00 1 0.00 1 0 17 6.631e-01 9.382e-03 2.876e-01 4.778e-03 7.991718e-01 2.643647e-03 8.291412e-03 -6.000000e+00 3.800738e-01 227.95 -2.00 3.45 -2.00 321.92 0.00e+00 6.469734e-03 1.170538e-03 1.056123e-03 -6.000000e+00 1.582040e-02 279.40 -2.00 20.00 -2.00 321.58 0.00e+00 7.463 0.007 302.00 328.00 3 4.6284e+00 8.6576e-03 7.4874e-02 -6.0000e+00 9.5129e-01 1.5128e-01 1.4270e-02 4.3837e-02 -6.0000e+00 1.0370e+00 -2.6118e-01 1.7893e-02 2.5871e-02 -6.0000e+00 6.0952e-01 1.1151e-01 8.4313e-03 9.0732e-03 -6.0000e+00 2.5512e-01 5.1604e-06 -1.0089e-03 1.3963e-04 1.1345e-04 -6.0000e+00 1.8328e-02 1.0360e-03 -3.2454e-05 12 8 8 10 0 0 52.58 18.20 0.29 0.00104 -0.00655 137 30 1 5 0 360.190 21.06 15.00 18.20 14.11 5.1 818.15 -270847 -200083 900000 -121467 900000 -256630 -235070 -248146 -245414 -186489 -191897 -196397 -93069 -140309 -124850 11579 -82137 54015 -67282 -29643 -65556 -21336 -92183 8752 -81789 -29401 -60648 -72073 -92643 -34761 36589 -31101 53907 -8569 22990 -25020 -8640 -3779 1340 8814 -16489 -9583 -4079 -3468 21575 27553 1963 8046 11559 10088 2300 8423 5274 13393 8457 6589 9622 3259 2844 -999 4670 3031 6399 3629 3871 3777 3225 786 2685 4180 3596 6797 -148 2522 -669 1076 -2281 -3435 -795 -620 -1436 -1374 -1897 -1955 -46 -342 1889 2263 2007 1571 580 -1377 -1752 -2051 -1894 -848 -575 1306 -171 84 -783 -753 -1259 -370 -1498 -1709 -1829 -921 399 440 1040 403 373 -743 -680 -316 -137 -224 -152 -336 298 1252 1155 827 199 -382 -40 556 62 -221 82 -14 -110 42 -440 -142 383 602 371 30 -120 -699 -627 -2294 -1017 900000 -566 900000 -2282 -1792 -2417 -2598 -1185 -1381 -1746 -434 -1307 -1322 54 -835 252 -741 -262 -777 -179 -1483 61 -1385 -342 -899 -1190 -1922 -456 324 -619 603 -178 341 -593 -190 -94 39 287 -789 -467 -200 -176 877 1097 106 433 646 576 161 631 454 1170 831 690 1008 363 309 -111 508 373 884 594 685 673 581 152 528 939 902 1729 -40 622 -155 238 -491 -776 -201 -175 -488 -540 -833 -918 -23 -180 1023 1259 1119 850 297 -678 -844 -1042 -1098 -576 -459 1188 -175 87 -767 -660 -1001 -289 -1263 -1533 -1738 -935 445 560 1486 625 592 -1168 -1021 -455 -199 -341 -245 -562 486 1933 1710 1191 278 -521 -53 768 99 -407 155 -29 -241 98 -1109 -376 1032 1643 1011 79 -293 -1602 -1380 SS 20210918T133728.7Z 7931.567694 169 1 49.09 2 80.83 95.61 129.68 280.06 0.00 1 0.00 1 0 25 3.959e-01 6.787e-03 8.098e-02 1.739e-03 6.632876e-01 9.290960e-04 7.079976e-03 -6.000000e+00 2.266810e-01 227.95 -2.00 3.45 -2.00 321.34 0.00e+00 4.917183e-03 3.652315e-04 6.806406e-04 -6.000000e+00 9.132410e-03 279.40 -2.00 20.00 -2.00 321.01 0.00e+00 5.967 0.004 302.00 328.00 3 4.3453e+00 2.8363e-03 6.0210e-02 -6.0000e+00 5.6768e-01 3.5321e-02 4.0390e-03 3.5183e-02 -6.0000e+00 6.1868e-01 -7.7571e-02 4.8545e-03 1.9685e-02 -6.0000e+00 3.6370e-01 3.0795e-02 2.4015e-03 6.5975e-03 -6.0000e+00 1.5125e-01 2.5087e-05 -6.4125e-04 5.1119e-05 8.0487e-05 -6.0000e+00 1.0802e-02 5.1004e-04 -1.3682e-05 11 8 0 10 0 0 22.34 18.20 0.24 0.00051 -0.00431 350 76 1 5 0 140.240 21.17 15.00 18.20 15.50 5.1 828.73 -169929 -110004 -112245 -107463 -144074 -119540 -132636 -147664 -124697 -110662 -98226 -107443 -65120 -82201 -39862 -54445 -22430 -44710 -20445 -26169 -13754 -28526 -22657 -13702 -28719 -12220 -26964 -21095 -24835 -10737 -16354 -5907 -2789 -9464 -6935 -10706 -7843 -4627 -1089 -424 1432 -2380 1872 -372 4327 -143 1645 3024 1814 3657 3258 4744 2779 5800 2097 4112 614 898 -571 355 164 3201 3544 2870 2795 1564 1389 390 2789 1885 1171 1507 592 656 -934 -681 -3184 -2460 -2490 -1294 -1384 -882 -2304 -1199 -829 -385 378 718 1287 1067 1168 -547 -901 -855 -988 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