File name: Pandora204s1_BoulderCO-NCAR_20221214_L2Fit_fwvt1c3d20210826p1-8.txt File generation date: 20250127T145612.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: --- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora204_OF_v2d20210322.txt Instrument calibration file used: Pandora204s1_CF_v3d20210826.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20221214_L1_smca1c3d20210826p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20221214 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: New Fieldcal for early data (starting from 20210826) First and last pixel inside fitting window: 1655 1804 Nominal wavelengths inside fitting window [nm]: 492.0991 492.2198 492.3406 492.4613 492.5820 492.7027 492.8233 492.9440 493.0646 493.1852 493.3058 493.4264 493.5470 493.6675 493.7881 493.9086 494.0291 494.1496 494.2701 494.3905 494.5109 494.6314 494.7518 494.8722 494.9925 495.1129 495.2332 495.3535 495.4738 495.5941 495.7144 495.8346 495.9549 496.0751 496.1953 496.3155 496.4357 496.5558 496.6760 496.7961 496.9162 497.0363 497.1563 497.2764 497.3964 497.5164 497.6364 497.7564 497.8764 497.9963 498.1163 498.2362 498.3561 498.4760 498.5959 498.7157 498.8355 498.9554 499.0752 499.1950 499.3147 499.4345 499.5542 499.6739 499.7936 499.9133 500.0330 500.1526 500.2723 500.3919 500.5115 500.6311 500.7506 500.8702 500.9897 501.1092 501.2287 501.3482 501.4677 501.5871 501.7066 501.8260 501.9454 502.0648 502.1841 502.3035 502.4228 502.5421 502.6614 502.7807 502.9000 503.0192 503.1384 503.2577 503.3769 503.4960 503.6152 503.7344 503.8535 503.9726 504.0917 504.2108 504.3298 504.4489 504.5679 504.6869 504.8059 504.9249 505.0439 505.1628 505.2817 505.4006 505.5195 505.6384 505.7573 505.8761 505.9949 506.1138 506.2325 506.3513 506.4701 506.5888 506.7075 506.8263 506.9449 507.0636 507.1823 507.3009 507.4195 507.5382 507.6567 507.7753 507.8939 508.0124 508.1309 508.2494 508.3679 508.4864 508.6049 508.7233 508.8417 508.9601 509.0785 509.1969 509.3152 509.4336 509.5519 509.6702 509.7885 509.9067 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221214T145956.7Z 8383.624961 293 1 49.51 2 83.73 127.64 47.98 251.37 0.00 1 0.00 1 0 15 3.985e-03 3.948e-03 5.879e-04 5.865e-04 1.976768e+03 3.182919e+01 1.542501e+02 -6.000000e+00 2.019959e+02 268.39 -2.00 20.00 -2.00 505.28 0.00e+00 1.592893e-03 1.535899e-05 8.686586e-05 -6.000000e+00 1.065383e-04 268.39 -2.00 20.00 -2.00 500.52 0.00e+00 9.052157e-01 1.141825e-02 2.079975e-02 -6.000000e+00 7.811650e-02 222.27 -2.00 3.45 -2.00 502.09 0.00e+00 8.284 0.010 489.00 513.00 1 6.1040e+00 8.6954e-04 1.0169e-02 -6.0000e+00 5.9449e-03 7.6173e-03 2.2792e-04 6.8210e-04 -6.0000e+00 1.5741e-03 1.5161e-03 6.1564e-04 5.1544e-05 3.6419e-05 -6.0000e+00 3.5735e-04 -1.4865e-03 -2.5124e-05 11 8 0 10 0 0 99.76 18.24 1.16 -0.00149 0.00278 39 9 1 4 0 1269.400 21.17 14.99 18.24 -1.94 8.8 677.84 -936 -576 -265 -91 425 717 857 934 559 661 357 -10 -298 -265 -563 -222 -86 -26 -131 188 396 294 384 212 340 438 653 -28 -407 -393 -675 -645 30 -16 -158 180 45 -72 -360 -158 -292 -19 74 274 389 376 391 305 -87 -436 -636 -967 -794 -524 -306 -198 11 129 180 309 389 333 391 474 42 201 35 -55 -543 -435 -294 -424 -106 19 -115 -273 -189 -439 -645 -423 -545 -619 -257 -30 -271 -142 -266 -186 -271 -227 59 385 253 368 544 485 42 -252 -445 -758 -813 -669 -228 -300 -291 -18 -257 -404 -138 -106 -107 168 395 378 675 741 758 556 434 432 318 189 416 -30 47 273 184 341 495 66 -217 0 -136 -356 -286 -53 -390 -95 252 193 111 382 238 444 234 94 -306 -374 -283 -589 -878 -552 -263 -94 422 724 879 963 575 669 357 -10 -291 -270 -572 -215 -85 -26 -136 196 412 306 400 222 359 461 683 -29 -411 -383 -652 -628 30 -16 -168 191 48 -75 -371 -162 -300 -19 77 290 415 402 415 319 -89 -439 -620 -924 -751 -501 -302 -202 11 135 188 320 404 348 411 496 44 205 35 -55 -537 -423 -284 -412 -104 19 -115 -272 -185 -422 -615 -402 -521 -598 -249 -29 -269 -142 -265 -185 -270 -227 59 372 249 364 530 489 42 -244 -421 -704 -754 -630 -222 -289 -286 -17 -248 -384 -137 -100 -104 165 394 381 682 752 774 570 441 432 313 184 402 -29 47 269 181 335 484 65 -213 0 -129 -333 -268 -50 -380 -95 253 196 113 390 245 458 242 97 -310 -369 -273 -568 SQ 20221214T155911.4Z 8383.666104 314 1 9.91 2 75.45 138.62 58.93 262.37 0.00 1 0.00 1 0 15 3.739e-03 3.742e-03 1.232e-04 1.230e-04 7.990357e+02 6.335071e+00 6.586453e+01 -6.000000e+00 1.895423e+02 268.39 -2.00 20.00 -2.00 505.26 0.00e+00 6.876777e-04 3.222731e-06 3.879516e-05 -6.000000e+00 9.997634e-05 268.39 -2.00 20.00 -2.00 500.47 0.00e+00 3.626379e-01 2.392248e-03 8.575626e-03 -6.000000e+00 7.331557e-02 222.27 -2.00 3.45 -2.00 502.06 0.00e+00 3.903 0.001 489.00 513.00 1 2.0219e+00 1.8214e-04 4.7329e-03 -6.0000e+00 5.5794e-03 8.5399e-03 4.8152e-05 3.0323e-04 -6.0000e+00 1.4776e-03 1.5856e-01 8.5311e-04 1.0784e-05 1.5862e-05 -6.0000e+00 3.3536e-04 -9.8665e-04 -3.7405e-05 10 0 0 10 0 0 86.07 18.25 1.50 -0.00099 0.00493 577 126 1 4 0 16.440 21.17 15.00 18.25 2.52 9.2 714.91 -904 -590 -299 -54 450 726 845 824 567 571 377 -89 -249 -262 -412 -418 -55 32 -124 208 378 340 384 331 308 440 465 -114 -410 -349 -660 -635 -5 -17 -104 236 104 -171 -290 -208 -230 -142 120 246 371 340 368 318 -120 -405 -527 -876 -781 -455 -245 -202 14 85 229 365 371 318 362 323 137 154 91 -94 -446 -380 -377 -390 -124 -10 -143 -251 -137 -362 -604 -500 -462 -559 -240 -8 -209 -182 -182 -133 -236 -162 126 367 203 276 565 326 49 -237 -454 -618 -794 -531 -206 -317 -333 -52 -172 -353 -153 -140 -125 144 310 433 597 716 672 446 424 430 188 190 362 33 38 300 204 327 525 155 -178 72 -169 -413 -92 -50 -387 -137 195 94 162 356 339 400 308 85 -316 -271 -377 -514 -875 -582 -293 -55 463 761 900 883 606 601 391 -92 -252 -262 -411 -420 -56 33 -127 216 391 352 397 344 321 459 481 -117 -426 -351 -656 -636 -5 -18 -109 247 108 -175 -293 -209 -232 -144 123 254 387 355 381 325 -121 -414 -522 -850 -750 -442 -245 -200 14 87 232 368 374 322 368 329 138 153 89 -95 -446 -374 -368 -383 -123 -10 -139 -253 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-3.7744e-05 11 8 0 10 0 0 87.40 18.25 1.50 -0.00092 0.00502 577 126 1 4 0 16.440 21.17 15.00 18.25 2.52 9.2 715.47 -938 -637 -324 -65 448 728 896 843 593 589 360 -86 -273 -296 -434 -416 -68 23 -92 226 381 366 430 353 318 475 518 -126 -423 -380 -683 -656 -40 -13 -74 234 125 -178 -284 -219 -248 -146 127 269 377 367 379 321 -131 -416 -555 -890 -805 -473 -257 -181 49 111 241 369 383 318 380 363 161 172 125 -107 -450 -387 -362 -392 -126 6 -144 -260 -175 -389 -629 -493 -508 -575 -247 -26 -193 -206 -166 -130 -237 -175 135 378 233 316 563 354 37 -228 -468 -661 -790 -513 -227 -315 -332 -38 -185 -351 -136 -138 -115 145 331 450 618 742 693 471 452 424 171 177 386 25 37 329 204 314 495 163 -210 78 -169 -418 -110 -86 -330 -136 192 79 174 357 341 410 311 70 -316 -318 -414 -526 -909 -630 -318 -66 462 765 919 869 610 621 375 -89 -277 -297 -434 -419 -70 23 -95 235 396 380 446 368 334 497 539 -129 -424 -383 -681 -659 -41 -13 -78 246 130 -184 -289 -221 -251 -149 131 280 395 385 394 329 -133 -410 -552 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