File name: Pandora204s1_BoulderCO-NCAR_20230127_L2Fit_fout2c3d20230101p1-8.txt File generation date: 20250127T151245.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: --- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora204_OF_v2d20210322.txt Instrument calibration file used: Pandora204s1_CF_v3d20230101.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20230127_L1_smca1c3d20230101p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20230127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: official CF from Session80 First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0197 305.1605 305.3013 305.4422 305.5830 305.7238 305.8646 306.0054 306.1462 306.2869 306.4277 306.5684 306.7091 306.8498 306.9905 307.1312 307.2719 307.4126 307.5532 307.6939 307.8345 307.9752 308.1158 308.2564 308.3970 308.5375 308.6781 308.8186 308.9592 309.0997 309.2402 309.3807 309.5212 309.6617 309.8022 309.9427 310.0831 310.2236 310.3640 310.5044 310.6448 310.7852 310.9256 311.0659 311.2063 311.3466 311.4870 311.6273 311.7676 311.9079 312.0482 312.1885 312.3287 312.4690 312.6092 312.7495 312.8897 313.0299 313.1701 313.3103 313.4504 313.5906 313.7308 313.8709 314.0110 314.1511 314.2912 314.4313 314.5714 314.7115 314.8515 314.9916 315.1316 315.2716 315.4116 315.5516 315.6916 315.8316 315.9716 316.1115 316.2515 316.3914 316.5313 316.6712 316.8111 316.9510 317.0908 317.2307 317.3706 317.5104 317.6502 317.7900 317.9298 318.0696 318.2094 318.3492 318.4889 318.6286 318.7684 318.9081 319.0478 319.1875 319.3272 319.4668 319.6065 319.7462 319.8858 320.0254 320.1650 320.3046 320.4442 320.5838 320.7234 320.8629 321.0024 321.1420 321.2815 321.4210 321.5605 321.7000 321.8395 321.9789 322.1184 322.2578 322.3972 322.5366 322.6760 322.8154 322.9548 323.0942 323.2335 323.3729 323.5122 323.6515 323.7908 323.9301 324.0694 324.2087 324.3479 324.4872 324.6264 324.7656 324.9048 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230127T153758.0Z 8427.651366 79 1 48.96 2 77.03 128.09 112.59 56.64 0.00 1 0.00 1 0 17 2.423e-01 8.243e-03 1.915e-01 3.968e-03 5.719877e-01 2.040060e-03 6.369537e-03 -6.000000e+00 1.348947e-01 223.57 -2.00 3.45 -2.00 320.68 0.00e+00 2.332022e-03 7.412491e-04 7.754348e-04 -6.000000e+00 5.636201e-03 266.27 -2.00 20.00 -2.00 320.30 0.00e+00 4.345 0.001 302.00 328.00 3 3.7184e+00 6.0163e-03 4.5735e-02 -6.0000e+00 3.3397e-01 8.3757e-03 7.7676e-03 2.9132e-02 -6.0000e+00 3.6437e-01 -8.3857e-03 8.2990e-03 1.6465e-02 -6.0000e+00 2.1567e-01 3.5872e-04 4.2385e-03 6.4428e-03 -6.0000e+00 9.1871e-02 1.8657e-04 7.2358e-05 1.1255e-04 6.8038e-05 -6.0000e+00 6.2925e-03 1.0866e-02 0.0000e+00 11 8 0 10 0 0 99.58 18.26 0.18 0.01087 0.01141 46 10 1 5 0 1064.090 21.17 15.00 18.26 7.97 9.6 779.96 -96786 19327 -28539 -51172 -16548 -80586 39117 -72551 -47156 -95834 -663 -24547 179745 -33595 18144 -40988 6775 4096 -14856 10660 -19818 22422 -21988 32087 -26656 15800 -21908 4303 -3411 7033 -8928 -4679 -4038 -9127 -5999 -21403 549 -12780 9435 -4269 6661 -1958 2646 -4679 -543 4979 -65 107 -2998 6555 399 3834 -1121 3163 1558 3269 1469 -624 2239 -1703 3012 -550 4563 3715 3620 1896 1394 -209 1356 1287 1953 -179 336 970 -1883 -171 -2736 -2601 -4115 -1944 -2315 -1407 -2566 -2191 -1226 -1058 843 675 2575 383 1339 -86 -121 -1927 -64 -873 -78 1718 374 613 -571 -655 -1501 -151 -1231 -251 -872 -892 449 807 1021 480 1043 -173 -114 -755 -355 -395 340 -52 -456 333 729 495 -26 81 -730 442 -497 201 -277 -206 -522 -110 -165 -52 423 323 528 3 50 -481 -330 -1030 86 -213 -466 -102 -847 151 -853 -502 -1704 -5 -262 695 -584 246 -1110 134 91 -422 255 -646 502 -753 735 -1118 481 -963 146 -121 236 -396 -235 -232 -599 -372 -1484 33 -1026 749 -462 737 -253 345 -675 -76 678 -9 16 -475 998 70 730 -245 718 381 819 387 -169 574 -444 767 -157 1398 1289 1336 696 496 -76 524 571 958 -94 177 485 -896 -72 -1088 -1016 -1762 -950 -1318 -901 -1819 -1634 -960 -882 727 602 2268 335 1090 -66 -88 -1425 -50 -789 -79 1946 468 776 -694 -726 -1532 -151 -1329 -284 -1036 -1120 597 1172 1615 804 1743 -282 -176 -1117 -518 -597 539 -87 -765 541 1142 755 -39 116 -1006 610 -756 337 -503 -394 -1035 -228 -361 -119 984 765 1252 6 110 -1020 -675 SS 20230127T154321.2Z 8427.655106 82 1 31.70 2 76.22 129.11 111.74 57.68 0.00 1 0.00 1 0 17 1.375e-01 7.315e-03 4.433e-02 1.700e-03 5.438493e-01 8.600415e-04 6.155293e-03 -6.000000e+00 7.654407e-02 223.57 -2.00 3.45 -2.00 320.21 0.00e+00 2.060689e-03 2.761461e-04 8.000732e-04 -6.000000e+00 3.198179e-03 266.27 -2.00 20.00 -2.00 319.82 0.00e+00 4.107 0.001 302.00 328.00 3 2.4243e+00 2.4425e-03 4.3228e-02 -6.0000e+00 1.8951e-01 3.0259e-03 3.0224e-03 2.7365e-02 -6.0000e+00 2.0675e-01 -4.8941e-03 3.0281e-03 1.5116e-02 -6.0000e+00 1.2238e-01 -2.4789e-03 1.5835e-03 5.6820e-03 -6.0000e+00 5.2132e-02 8.4874e-04 9.1009e-05 4.7098e-05 5.8424e-05 -6.0000e+00 3.5705e-03 1.0753e-02 0.0000e+00 12 9 1 12 1 1 99.47 18.26 0.23 0.01075 0.01144 80 27 1 5 0 389.040 21.17 15.00 18.26 8.55 9.6 783.53 -45825 -42843 -45533 -58803 -54732 -50366 -51588 -36893 -40240 -23434 -36484 -14238 -33121 -8559 -23598 -6938 -12065 -7972 1513 -5548 81 -13672 -5735 -3326 -5742 -11360 -7320 -9848 -9581 -7608 -5622 1461 190 1588 -5845 -3680 -7196 -1451 -3906 -1357 643 -193 1874 1311 1095 555 1215 -174 158 -194 1524 1144 1662 1045 1273 1939 627 603 -208 254 381 1712 2782 3533 2253 1062 -160 -1201 -120 623 1034 789 874 954 72 -1066 -1650 -3011 -2229 -2491 -1553 -971 -2099 -1786 -1279 -347 454 1002 1338 1580 671 307 -880 -997 -914 -724 490 1289 836 296 -191 -1386 -1334 -553 -1159 -1301 -536 -434 132 783 1111 972 826 229 -688 -610 -535 -427 83 53 -127 511 640 368 574 -217 -627 -83 -108 -89 -75 -289 -459 -136 -33 84 50 649 247 213 -50 -346 -470 -442 -478 -570 -833 -677 -569 -630 -445 -576 -311 -572 -193 -609 -156 -626 -187 -385 -268 50 -209 3 -580 -231 -143 -275 -612 -389 -523 -489 -393 -327 94 14 129 -494 -293 -639 -132 -449 -184 97 -32 318 230 195 101 223 -33 31 -40 335 282 445 305 393 618 209 202 -68 82 124 598 1085 1535 1052 487 -71 -542 -58 318 587 474 525 546 38 -555 -788 -1424 -1127 -1372 -988 -700 -1681 -1507 -1143 -329 421 957 1278 1461 626 265 -723 -814 -811 -733 524 1559 1116 401 -246 -1631 -1422 -580 -1317 -1575 -675 -579 176 1149 1788 1657 1409 377 -1069 -893 -774 -642 131 88 -214 832 1004 559 832 -324 -898 -119 -161 -148 -136 -523 -864 -268 -69 176 107 1411 541 453 -106 -700 -914 SS 20230127T162542.8Z 8427.684523 99 1 48.98 2 70.32 137.60 104.75 65.34 0.00 1 0.00 1 0 17 3.426e-02 6.946e-03 9.229e-03 9.110e-04 3.976569e-01 4.514642e-04 4.602044e-03 -6.000000e+00 1.907120e-02 223.57 -2.00 3.45 -2.00 319.15 0.00e+00 1.045914e-03 1.044200e-04 3.785796e-04 -6.000000e+00 7.968308e-04 266.27 -2.00 20.00 -2.00 318.73 0.00e+00 2.938 0.000 302.00 328.00 3 2.6485e+00 1.2305e-03 3.1107e-02 -6.0000e+00 4.7217e-02 6.4372e-03 1.4186e-03 1.9699e-02 -6.0000e+00 5.1513e-02 9.1828e-03 1.1230e-03 1.0210e-02 -6.0000e+00 3.0490e-02 -7.9803e-03 6.0443e-04 3.3303e-03 -6.0000e+00 1.2989e-02 2.0184e-03 1.2180e-04 2.5889e-05 3.2954e-05 -6.0000e+00 8.8955e-04 1.0428e-02 0.0000e+00 11 8 0 10 0 0 99.88 18.26 0.21 0.01043 0.01134 217 47 1 5 0 225.670 21.17 14.99 18.26 14.35 9.7 827.67 -5417 -6545 -2242 -10311 -8753 -16530 -9259 -14580 -2959 -13305 -9669 -14354 -8452 -4134 -1001 -668 -1507 1434 -1257 2012 -1776 1203 -1007 340 -1538 -549 -711 -1367 -2916 -3532 96 -1074 1480 -2165 -2456 -4878 -3993 -3175 -704 -414 -700 -298 -288 342 325 995 -183 379 -1525 45 540 865 1157 1541 1268 1004 1213 101 259 -450 686 1093 2370 2588 1387 581 -572 -1069 -81 755 605 1036 506 1141 -101 -387 -1516 -2600 -2142 -1760 -1211 -1174 -1946 -1872 -903 -695 561 533 1250 830 825 -17 -595 -601 -525 -489 396 1314 735 339 -241 -1014 -1308 -450 -999 -1011 -662 -548 248 675 1062 756 726 80 -369 -629 -574 -330 13 99 -60 575 475 446 449 -65 -623 148 -21 -27 -101 -235 -363 -217 -24 -21 269 547 391 50 -26 -611 -493 -142 -201 -70 -340 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