File name: Pandora204s1_BoulderCO-NCAR_20230413_L2Fit_fwvt1c3d20230101p1-8.txt File generation date: 20250127T155619.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: --- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora204_OF_v2d20210322.txt Instrument calibration file used: Pandora204s1_CF_v3d20230101.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20230413_L1_smca1c3d20230101p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20230413 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: official CF from Session80 First and last pixel inside fitting window: 1655 1804 Nominal wavelengths inside fitting window [nm]: 492.0850 492.2057 492.3265 492.4472 492.5679 492.6886 492.8093 492.9300 493.0506 493.1712 493.2918 493.4124 493.5330 493.6536 493.7741 493.8946 494.0151 494.1356 494.2561 494.3766 494.4970 494.6174 494.7379 494.8582 494.9786 495.0990 495.2193 495.3397 495.4600 495.5803 495.7005 495.8208 495.9410 496.0613 496.1815 496.3017 496.4219 496.5420 496.6622 496.7823 496.9024 497.0225 497.1426 497.2626 497.3827 497.5027 497.6227 497.7427 497.8627 497.9826 498.1026 498.2225 498.3424 498.4623 498.5822 498.7020 498.8219 498.9417 499.0615 499.1813 499.3011 499.4208 499.5406 499.6603 499.7800 499.8997 500.0194 500.1390 500.2587 500.3783 500.4979 500.6175 500.7371 500.8566 500.9762 501.0957 501.2152 501.3347 501.4542 501.5736 501.6931 501.8125 501.9319 502.0513 502.1707 502.2900 502.4094 502.5287 502.6480 502.7673 502.8866 503.0058 503.1251 503.2443 503.3635 503.4827 503.6018 503.7210 503.8401 503.9592 504.0784 504.1974 504.3165 504.4356 504.5546 504.6736 504.7926 504.9116 505.0306 505.1495 505.2685 505.3874 505.5063 505.6252 505.7440 505.8629 505.9817 506.1005 506.2193 506.3381 506.4569 506.5756 506.6944 506.8131 506.9318 507.0505 507.1691 507.2878 507.4064 507.5250 507.6436 507.7622 507.8808 507.9993 508.1178 508.2363 508.3548 508.4733 508.5918 508.7102 508.8287 508.9471 509.0655 509.1838 509.3022 509.4205 509.5389 509.6572 509.7755 509.8937 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230413T163429.3Z 8503.690617 246 1 6.28 2 44.96 123.25 78.59 220.04 0.00 1 0.00 1 0 15 3.559e-03 3.560e-03 1.281e-04 1.278e-04 5.611593e+02 6.641526e+00 4.796323e+01 -6.000000e+00 1.829781e+02 271.66 -2.00 20.00 -2.00 505.25 0.00e+00 5.338341e-04 3.359090e-06 3.069053e-05 -6.000000e+00 9.586909e-05 271.66 -2.00 20.00 -2.00 500.41 0.00e+00 3.233409e-03 2.501311e-03 5.718695e-03 -6.000000e+00 7.012583e-02 227.56 -2.00 3.45 -2.00 502.00 0.00e+00 1.411 0.000 489.00 513.00 1 1.8894e+00 1.9026e-04 1.8759e-03 -6.0000e+00 5.3390e-03 1.0658e-02 5.0561e-05 1.4035e-04 -6.0000e+00 1.4144e-03 2.4932e-01 8.2527e-04 1.1271e-05 1.1978e-05 -6.0000e+00 3.1929e-04 1.0086e-02 -3.3613e-05 10 0 0 10 0 0 17.36 18.42 1.64 0.01009 0.01581 559 122 1 4 0 10.570 21.27 15.00 18.42 26.07 10.6 930.59 -831 -554 -268 -78 425 672 842 810 571 579 373 -58 -217 -247 -389 -421 -47 43 -140 219 395 340 377 317 260 432 497 -128 -388 -291 -598 -603 10 -9 -135 210 88 -155 -275 -211 -259 -156 93 228 324 306 334 283 -115 -389 -484 -833 -711 -437 -244 -204 7 68 230 318 369 279 307 322 94 135 92 -88 -424 -351 -348 -382 -87 -15 -146 -243 -133 -333 -585 -467 -427 -508 -214 20 -166 -181 -165 -117 -205 -184 109 340 186 225 521 360 30 -222 -439 -598 -755 -471 -180 -366 -373 -55 -174 -337 -98 -145 -126 163 288 375 588 680 635 408 411 393 185 189 401 16 0 330 186 318 501 138 -216 100 -142 -375 -25 -20 -313 -133 177 87 143 341 322 400 280 85 -312 -279 -379 -460 -826 -536 -268 -80 448 689 877 849 597 596 379 -61 -224 -252 -396 -431 -49 44 -146 231 416 358 396 335 276 457 523 -133 -393 -297 -603 -614 10 -9 -144 223 93 -161 -281 -214 -264 -160 97 238 342 323 349 292 -117 -386 -486 -818 -690 -429 -236 -203 7 69 234 323 375 286 315 330 95 135 91 -86 -409 -349 -343 -378 -83 -15 -143 -236 -127 -326 -570 -454 -417 -480 -203 19 -161 -177 -161 -114 -201 -181 108 341 190 231 527 359 29 -213 -411 -574 -723 -438 -173 -366 -380 -55 -173 -331 -95 -142 -126 164 282 371 583 677 635 409 407 383 185 187 393 16 0 328 185 315 494 137 -213 97 -135 -351 -24 -19 -304 -132 170 84 139 332 315 393 276 83 -300 -272 -362 -437 SQ 20230413T163436.8Z 8503.690704 246 2 6.25 2 44.94 123.28 78.61 220.06 0.00 1 0.00 1 0 15 3.550e-03 3.545e-03 1.270e-04 1.267e-04 5.560055e+02 6.590685e+00 4.725452e+01 -6.000000e+00 1.825245e+02 271.66 -2.00 20.00 -2.00 505.25 0.00e+00 5.318879e-04 3.326917e-06 3.061027e-05 -6.000000e+00 9.563160e-05 271.66 -2.00 20.00 -2.00 500.40 0.00e+00 2.820722e-03 2.478078e-03 5.726197e-03 -6.000000e+00 6.995230e-02 227.56 -2.00 3.45 -2.00 501.99 0.00e+00 1.411 0.000 489.00 513.00 1 1.8713e+00 1.8844e-04 1.8748e-03 -6.0000e+00 5.3258e-03 1.0552e-02 5.0087e-05 1.4013e-04 -6.0000e+00 1.4109e-03 2.5391e-01 8.3919e-04 1.1166e-05 1.1990e-05 -6.0000e+00 3.1850e-04 9.6130e-03 -3.1412e-05 10 0 0 10 0 0 -3.15 18.42 1.64 0.00961 0.01543 559 122 1 4 0 10.570 21.27 15.00 18.42 26.07 10.6 931.08 -844 -550 -271 -81 423 674 853 821 560 548 381 -71 -222 -261 -394 -397 -49 39 -138 209 382 327 398 292 255 422 484 -131 -418 -278 -615 -589 -15 -18 -102 225 102 -174 -282 -236 -248 -160 103 187 322 306 321 292 -132 -400 -491 -827 -714 -433 -247 -189 -9 87 220 306 364 301 324 316 74 122 93 -79 -442 -374 -346 -369 -105 -9 -178 -267 -129 -326 -590 -451 -418 -521 -204 14 -184 -191 -175 -107 -210 -181 100 345 188 248 510 339 35 -243 -445 -600 -731 -489 -218 -348 -374 -60 -140 -332 -117 -135 -135 131 315 393 552 649 641 395 408 403 181 192 394 11 20 291 174 303 511 148 -187 81 -141 -370 -63 -13 -322 -112 191 59 149 351 331 399 284 84 -322 -270 -374 -443 -806 -536 -274 -85 430 697 896 868 590 569 389 -71 -222 -269 -404 -410 -49 40 -146 222 405 346 421 311 273 450 513 -138 -427 -273 -627 -578 -15 -19 -110 240 107 -182 -292 -242 -255 -166 107 197 342 325 339 303 -135 -399 -475 -818 -699 -428 -241 -191 -9 90 226 313 373 311 335 326 76 123 93 -77 -430 -358 -329 -353 -101 -9 -176 -262 -124 -308 -554 -442 -393 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18.42 1.64 0.00972 0.01555 559 122 1 4 0 10.570 21.27 15.00 18.42 26.07 10.6 931.08 -835 -542 -258 -54 427 696 857 785 570 586 379 -69 -223 -244 -405 -393 -36 37 -138 206 374 346 383 310 256 424 470 -134 -387 -272 -604 -574 -10 -17 -131 200 109 -177 -292 -203 -231 -173 120 198 342 327 345 294 -122 -410 -496 -810 -723 -413 -255 -205 11 76 203 322 349 297 328 293 86 133 86 -97 -426 -381 -357 -353 -71 9 -188 -258 -131 -337 -554 -452 -417 -524 -217 16 -166 -202 -142 -92 -209 -173 112 352 191 243 523 340 48 -229 -422 -585 -731 -500 -204 -346 -370 -64 -159 -344 -102 -139 -142 148 287 399 553 658 638 387 429 382 164 173 392 26 31 332 188 300 522 140 -205 103 -129 -375 -67 -11 -339 -138 199 73 168 356 317 386 275 83 -303 -293 -350 -462 -828 -523 -258 -55 449 713 891 822 595 601 383 -73 -230 -248 -411 -402 -37 38 -144 217 392 363 402 327 272 448 494 -139 -392 -277 -609 -583 -10 -17 -139 212 114 -184 -299 -206 -235 -178 124 207 360 344 360 302 -124 -406 -497 -793 -701 -404 -258 -204 11 77 207 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