File name: Pandora204s1_BoulderCO-NCAR_20230422_L2Fit_fout2c3d20230101p1-8.txt File generation date: 20250127T155159.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: --- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 204 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora204_OF_v2d20210322.txt Instrument calibration file used: Pandora204s1_CF_v3d20230101.txt Level 1 file used: Pandora204s1_BoulderCO-NCAR_20230422_L1_smca1c3d20230101p1-8.txt Full location name: National Center for Atmospheric Research Short location name: BoulderCO-NCAR Country of location: United States Location latitude [deg]: 40.0375 Location longitude [deg]: -105.2420 Location altitude [m]: 1616 Local noon date: 20230422 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: official CF from Session80 First and last pixel inside fitting window: 232 374 Nominal wavelengths inside fitting window [nm]: 305.0197 305.1605 305.3013 305.4422 305.5830 305.7238 305.8646 306.0054 306.1462 306.2869 306.4277 306.5684 306.7091 306.8498 306.9905 307.1312 307.2719 307.4126 307.5532 307.6939 307.8345 307.9752 308.1158 308.2564 308.3970 308.5375 308.6781 308.8186 308.9592 309.0997 309.2402 309.3807 309.5212 309.6617 309.8022 309.9427 310.0831 310.2236 310.3640 310.5044 310.6448 310.7852 310.9256 311.0659 311.2063 311.3466 311.4870 311.6273 311.7676 311.9079 312.0482 312.1885 312.3287 312.4690 312.6092 312.7495 312.8897 313.0299 313.1701 313.3103 313.4504 313.5906 313.7308 313.8709 314.0110 314.1511 314.2912 314.4313 314.5714 314.7115 314.8515 314.9916 315.1316 315.2716 315.4116 315.5516 315.6916 315.8316 315.9716 316.1115 316.2515 316.3914 316.5313 316.6712 316.8111 316.9510 317.0908 317.2307 317.3706 317.5104 317.6502 317.7900 317.9298 318.0696 318.2094 318.3492 318.4889 318.6286 318.7684 318.9081 319.0478 319.1875 319.3272 319.4668 319.6065 319.7462 319.8858 320.0254 320.1650 320.3046 320.4442 320.5838 320.7234 320.8629 321.0024 321.1420 321.2815 321.4210 321.5605 321.7000 321.8395 321.9789 322.1184 322.2578 322.3972 322.5366 322.6760 322.8154 322.9548 323.0942 323.2335 323.3729 323.5122 323.6515 323.7908 323.9301 324.0694 324.2087 324.3479 324.4872 324.6264 324.7656 324.9048 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230422T220006.0Z 8512.916736 32 1 4.92 2 48.32 248.03 18.86 214.82 0.00 1 0.00 1 0 17 1.476e-02 9.737e-03 1.119e-02 5.551e-03 2.524903e-01 2.804764e-03 2.987365e-03 -6.000000e+00 8.370192e-03 228.27 -2.00 3.45 -2.00 316.04 0.00e+00 6.245353e-04 2.886639e-04 6.060794e-05 -6.000000e+00 3.526765e-04 272.81 -2.00 20.00 -2.00 315.54 0.00e+00 1.501 0.000 302.00 328.00 3 5.2109e+00 7.2794e-03 1.7892e-02 -6.0000e+00 2.0902e-02 3.8404e-02 8.1177e-03 1.2623e-02 -6.0000e+00 2.2698e-02 -9.6037e-03 4.7012e-03 6.2351e-03 -6.0000e+00 1.3436e-02 2.6238e-03 2.1956e-03 1.8008e-03 -6.0000e+00 5.7004e-03 5.9095e-04 1.1108e-04 1.5196e-04 2.0289e-05 -6.0000e+00 3.8372e-04 7.1664e-03 0.0000e+00 12 9 9 12 1 1 999.00 18.42 0.27 0.00717 0.00800 1 5 1 5 0 2367.500 21.27 15.00 18.42 11.01 10.2 813.46 59 -880 4070 -726 -1826 526 -4697 1533 -31 3388 -2669 -2118 -37 -1716 2772 -1845 284 349 3413 1068 309 1586 -291 1005 -910 219 -269 890 -2994 -3406 1632 1547 378 -787 -4169 -3669 -5367 -3388 -1007 -319 -288 422 981 -1054 517 370 768 921 -787 -569 364 410 632 1882 1735 1352 2101 -300 -29 -415 400 1311 1884 2187 214 -104 -734 -1101 952 233 -322 694 911 1272 709 -1193 -373 -3203 -2376 -2216 -1479 -335 -1949 -1510 -1617 169 24 1482 882 822 519 -1350 -93 -612 -470 -93 -721 1351 542 651 -18 -725 -1335 -600 -370 -256 -786 -240 -881 78 1013 982 594 808 -649 -107 -577 -278 336 -87 -326 672 1361 293 721 -411 -1174 302 1438 237 453 11 -553 160 -131 -546 -434 715 704 -134 -651 -326 -578 11 -183 839 -150 -342 90 -869 296 -7 755 -620 -488 -9 -480 837 -629 99 125 1228 402 119 602 -112 400 -383 94 -117 370 -1207 -1339 638 643 169 -368 -1913 -1610 -2493 -1723 -574 -203 -196 296 699 -768 373 267 547 644 -547 -393 257 303 485 1481 1398 1106 1733 -251 -24 -340 331 1121 1693 2052 205 -96 -642 -937 818 218 -321 711 937 1282 691 -1104 -321 -2679 -1996 -1994 -1428 -343 -2100 -1665 -1850 199 29 1839 1104 1015 616 -1535 -99 -633 -495 -103 -856 1684 709 852 -23 -880 -1561 -703 -454 -325 -1028 -320 -1214 110 1477 1452 867 1134 -874 -137 -735 -360 451 -122 -467 954 1897 403 958 -536 -1486 375 1831 317 625 15 -786 230 -194 -841 -678 1126 1115 -212 -1009 -494 -862 SS 20230422T220552.2Z 8512.920743 35 1 49.11 2 49.35 249.31 19.50 218.24 0.00 1 0.00 1 0 25 1.357e-02 8.505e-03 1.976e-03 6.778e-04 2.521875e-01 3.395638e-04 2.957768e-03 -6.000000e+00 7.694099e-03 228.27 -2.00 3.45 -2.00 317.11 0.00e+00 8.648708e-04 4.455344e-05 1.204877e-04 -6.000000e+00 3.241741e-04 272.81 -2.00 20.00 -2.00 316.56 0.00e+00 1.532 0.000 302.00 328.00 3 3.5836e+00 8.9292e-04 1.8062e-02 -6.0000e+00 1.9214e-02 -9.2910e-05 9.9967e-04 1.2624e-02 -6.0000e+00 2.0864e-02 -2.7121e-03 6.0050e-04 6.2543e-03 -6.0000e+00 1.2351e-02 -2.8587e-03 2.9566e-04 1.8757e-03 -6.0000e+00 5.2404e-03 2.9849e-03 3.5886e-04 1.9050e-05 1.9298e-05 -6.0000e+00 3.5268e-04 6.2654e-03 0.0000e+00 11 8 0 10 0 0 99.44 18.42 0.25 0.00627 0.00896 151 33 1 5 0 325.130 21.27 15.00 18.42 11.00 10.2 814.19 -568 823 440 -1934 -4365 -3745 -3866 128 -646 -1249 -4091 -3684 -2792 -1304 1136 104 825 300 1388 1469 1652 578 1261 941 749 413 -38 -737 -1635 -850 45 895 1727 -347 -3350 -3251 -4461 -2264 -844 -73 -399 -267 -7 -179 539 14 -6 -158 -797 -602 438 585 1097 1298 897 1132 807 541 51 175 517 1184 1897 2500 1155 1 -851 -1957 -383 389 759 867 889 934 347 -590 -1500 -2910 -2247 -2008 -1541 -1296 -2122 -1688 -1222 -372 492 889 1122 1156 698 158 -885 -985 -686 -559 430 1299 1017 335 -32 -1215 -1386 -656 -896 -841 -605 -578 -9 842 1076 1076 736 261 -560 -721 -838 -438 108 479 203 625 607 386 540 -62 -603 -54 -37 -59 -23 -336 -510 -230 -44 222 208 741 422 265 -161 -698 -933 -67 107 59 -256 -520 -410 -438 16 -89 -185 -615 -549 -456 -242 236 24 201 76 361 395 456 159 346 272 229 132 -12 -228 -471 -234 13 274 570 -123 -1153 -1056 -1558 -894 -362 -37 -223 -156 -4 -109 326 9 -3 -92 -456 -341 256 367 725 902 647 829 605 407 37 128 382 929 1485 2090 996 0 -688 -1528 -305 322 695 836 863 879 308 -518 -1187 -2172 -1693 -1687 -1345 -1251 -2222 -1838 -1408 -424 590 1103 1401 1406 794 178 -909 -957 -689 -616 522 1611 1364 453 -41 -1443 -1651 -785 -1083 -1084 -811 -810 -13 1209 1634 1674 1116 399 -788 -943 -1074 -579 152 720 297 967 914 562 744 -82 -755 -71 -48 -82 -34 -511 -788 -366 -68 366 355 1284 744 460 -271 -1132 -1470 SS 20230422T222802.5Z 8512.936140 43 1 49.35 2 53.37 253.95 22.35 229.62 0.00 1 0.00 1 0 25 1.421e-02 8.519e-03 2.191e-03 6.383e-04 2.729990e-01 3.195287e-04 3.187139e-03 -6.000000e+00 8.056790e-03 228.28 -2.00 3.45 -2.00 317.45 0.00e+00 9.195913e-04 4.582417e-05 1.755723e-04 -6.000000e+00 3.394600e-04 272.81 -2.00 20.00 -2.00 316.89 0.00e+00 1.672 0.000 302.00 328.00 3 3.3401e+00 8.4489e-04 1.9618e-02 -6.0000e+00 2.0119e-02 -5.1713e-03 9.4769e-04 1.3645e-02 -6.0000e+00 2.1848e-02 -1.1479e-03 5.8170e-04 6.7824e-03 -6.0000e+00 1.2933e-02 -3.6431e-03 2.9164e-04 2.0458e-03 -6.0000e+00 5.4873e-03 3.2853e-03 3.1108e-04 1.7995e-05 2.0356e-05 -6.0000e+00 3.6931e-04 6.4596e-03 0.0000e+00 11 8 0 10 0 0 90.56 18.43 0.26 0.00646 0.00880 168 37 1 5 0 293.680 21.27 15.00 18.43 11.58 10.5 820.88 659 151 754 -3060 -3326 -5736 -2643 -1772 -849 -2123 -3860 -4330 -2967 -1260 99 755 -320 1219 796 1715 1077 967 828 708 344 467 322 -1185 -1400 -1281 211 540 2122 -696 -3428 -3969 -4070 -2428 -1001 70 -553 -186 -97 100 454 457 114 21 -975 -473 328 578 1100 1400 1031 1019 871 257 124 -112 392 1019 2122 2517 1255 90 -912 -1871 -517 681 686 1061 831 1040 296 -536 -1444 -2833 -2231 -1921 -1519 -1334 -2100 -1854 -1044 -502 598 789 1342 1078 759 91 -905 -1017 -807 -431 296 1296 959 452 -180 -1260 -1525 -709 -840 -1055 -588 -557 15 744 1149 1045 790 242 -482 -752 -737 -349 73 524 158 715 630 544 456 49 -682 -88 -113 -15 -1 -328 -519 -291 -15 191 267 708 408 140 -104 -686 -910 62 16 83 -334 -321 -526 -243 -181 -97 -262 -481 -543 -408 -198 18 150 -68 264 181 400 260 231 199 180 93 131 92 -325 -357 -315 54 150 632 -225 -1074 -1184 -1292 -877 -429 32 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