File name: Pandora57s1_BoulderCO_20201124_L2Fit_fout2c2d20201015p1-8.txt File generation date: 20251208T234420.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v2d20201015.txt Level 1 file used: Pandora57s1_BoulderCO_20201124_L1_smca1c2d20201015p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20201124 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.0615 305.2022 305.3429 305.4836 305.6243 305.7650 305.9056 306.0463 306.1869 306.3275 306.4681 306.6087 306.7493 306.8899 307.0305 307.1710 307.3116 307.4521 307.5926 307.7331 307.8736 308.0141 308.1546 308.2950 308.4355 308.5759 308.7164 308.8568 308.9972 309.1376 309.2780 309.4183 309.5587 309.6990 309.8394 309.9797 310.1200 310.2603 310.4006 310.5409 310.6811 310.8214 310.9616 311.1019 311.2421 311.3823 311.5225 311.6627 311.8029 311.9430 312.0832 312.2233 312.3635 312.5036 312.6437 312.7838 312.9239 313.0639 313.2040 313.3440 313.4841 313.6241 313.7641 313.9041 314.0441 314.1841 314.3241 314.4640 314.6040 314.7439 314.8838 315.0237 315.1636 315.3035 315.4434 315.5833 315.7231 315.8630 316.0028 316.1426 316.2824 316.4222 316.5620 316.7018 316.8415 316.9813 317.1210 317.2607 317.4004 317.5401 317.6798 317.8195 317.9592 318.0988 318.2385 318.3781 318.5177 318.6573 318.7969 318.9365 319.0761 319.2157 319.3552 319.4948 319.6343 319.7738 319.9133 320.0528 320.1923 320.3318 320.4712 320.6107 320.7501 320.8895 321.0289 321.1683 321.3077 321.4471 321.5865 321.7258 321.8652 322.0045 322.1438 322.2831 322.4224 322.5617 322.7010 322.8402 322.9795 323.1187 323.2579 323.3971 323.5363 323.6755 323.8147 323.9539 324.0930 324.2322 324.3713 324.5104 324.6495 324.7886 324.9277 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201124T195447.6Z 7633.829717 94 1 49.12 2 62.72 197.60 105.96 82.10 0.00 1 0.00 1 0 17 2.070e-02 6.207e-03 1.597e-02 2.722e-03 3.394779e-01 1.361578e-03 4.016834e-03 -6.000000e+00 1.173079e-02 222.50 -2.00 3.45 -2.00 318.38 0.00e+00 2.584351e-04 2.425966e-04 1.017639e-04 -6.000000e+00 4.810222e-04 270.26 -2.00 20.00 -2.00 318.06 0.00e+00 2.171 0.000 302.00 328.00 3 5.2931e+00 3.6203e-03 2.4440e-02 -6.0000e+00 2.9017e-02 4.4422e-02 4.0880e-03 1.6659e-02 -6.0000e+00 3.1712e-02 1.1972e-03 2.8270e-03 8.5314e-03 -6.0000e+00 1.8716e-02 -9.0273e-03 1.5020e-03 2.5582e-03 -6.0000e+00 7.8805e-03 2.8092e-04 -2.5896e-04 8.1353e-05 2.9448e-05 -6.0000e+00 5.7855e-04 -2.3640e-03 -3.4273e-05 11 1 0 11 8 0 30.72 20.27 0.25 -0.00236 -0.00431 19 4 1 5 0 2584.850 25.90 20.00 20.27 18.51 17.7 877.48 -9923 -5695 -4922 -3684 -8294 -5873 -4204 -3609 3009 -6169 -1233 -6789 2139 -1077 -6130 -4528 -846 -1161 -133 -205 -20 103 993 2287 822 -413 -1520 509 -337 -410 915 2295 3517 -1079 -1667 -4293 -2016 -634 1783 55 -1412 -125 -993 -1143 -1032 149 -848 -117 346 -676 643 103 1888 1651 599 1004 -33 822 494 484 1319 1332 2614 1182 899 553 -703 -146 735 905 498 -2551 247 1306 -193 -142 -640 -306 -853 -1117 -313 -819 -1783 -1462 -870 -225 219 589 210 551 444 174 -289 -392 -234 152 387 1096 206 174 -652 -876 -660 -690 -1116 -747 -1064 -582 334 286 318 612 311 76 -441 30 85 212 -172 -220 -66 211 -16 644 965 243 496 527 298 135 201 178 -264 152 44 -198 237 245 12 -248 -11 -411 -687 -538 -329 -292 -205 -435 -290 -217 -208 181 -433 -83 -508 167 -102 -708 -577 -111 -161 -19 -31 -3 16 153 370 143 -76 -284 88 -56 -68 160 437 724 -242 -358 -927 -462 -167 549 20 -584 -54 -445 -520 -468 67 -381 -51 150 -301 300 52 1001 931 355 607 -19 506 298 289 800 800 1695 837 646 376 -454 -100 486 674 410 -2262 213 1069 -149 -98 -439 -200 -586 -801 -252 -738 -1747 -1500 -946 -260 265 733 263 663 497 179 -276 -363 -229 164 466 1355 275 230 -821 -1095 -767 -809 -1414 -999 -1388 -794 477 438 519 1022 510 117 -632 40 112 288 -249 -340 -104 326 -25 927 1314 342 665 705 426 195 307 283 -432 256 78 -374 457 451 23 -483 -20 -737 -1198 SS 20201124T200125.4Z 7633.834322 98 1 50.83 2 63.12 199.28 104.72 83.16 0.00 1 0.00 1 0 17 2.138e-02 6.902e-03 1.322e-02 2.223e-03 3.396759e-01 1.109348e-03 4.014392e-03 -6.000000e+00 1.211418e-02 222.50 -2.00 3.45 -2.00 318.47 0.00e+00 9.587469e-04 2.021000e-04 1.065734e-04 -6.000000e+00 4.967507e-04 270.26 -2.00 20.00 -2.00 318.17 0.00e+00 2.200 0.000 302.00 328.00 3 4.9851e+00 2.9427e-03 2.4638e-02 -6.0000e+00 2.9966e-02 2.5129e-02 3.3290e-03 1.6702e-02 -6.0000e+00 3.2749e-02 -6.0165e-03 2.3186e-03 8.5154e-03 -6.0000e+00 1.9328e-02 -2.7794e-03 1.2343e-03 2.5367e-03 -6.0000e+00 8.1381e-03 3.7685e-04 -4.1147e-04 6.6252e-05 2.9311e-05 -6.0000e+00 5.9748e-04 -2.5882e-03 -4.4481e-05 11 8 0 10 0 0 -44.79 20.27 0.27 -0.00259 -0.00568 28 6 1 5 0 1814.990 25.90 20.00 20.27 19.01 17.9 881.45 -1203 2570 -8858 -4348 -11189 -7945 1275 -112 7760 -7653 -2781 -6405 -1253 3292 -1267 2816 939 302 2048 -657 917 1806 2505 -1077 1843 -43 -1134 203 -255 -78 -1342 1085 2787 -1718 -1329 -4349 -859 -868 1020 -958 -1471 -263 -1696 -765 -482 -530 -1112 -562 -833 -276 967 -331 1293 383 35 1546 -16 -15 -278 248 715 1001 2142 832 301 -88 -868 -542 229 1025 303 5131 780 415 -287 -269 -186 -1288 -102 -787 -1026 -1264 -2154 -1606 -1183 -503 -370 202 639 665 612 382 166 -369 288 90 938 993 166 30 -159 -994 -618 -306 -865 -1210 -916 -757 -82 419 404 338 47 174 -377 -261 -289 39 161 -169 -215 284 58 380 646 805 283 674 462 461 89 109 37 6 19 -252 111 241 -193 20 -164 -377 -546 -60 138 -552 -246 -610 -403 62 -6 443 -541 -189 -473 -101 297 -140 335 121 41 290 -99 139 270 381 -180 316 -8 -210 35 -42 -13 -242 210 582 -391 -286 -946 -196 -230 318 -357 -562 -105 -709 -322 -202 -223 -466 -231 -370 -124 420 -157 644 204 19 867 -9 -9 -158 138 408 611 1416 601 221 -62 -571 -350 155 776 254 4293 682 350 -226 -191 -120 -801 -66 -576 -853 -1172 -2171 -1692 -1228 -554 -430 240 760 765 654 404 162 -353 288 101 1076 1269 229 42 -206 -1197 -690 -344 -1052 -1566 -1237 -1074 -122 622 639 549 74 261 -562 -364 -398 56 243 -273 -329 458 91 573 923 1096 369 874 641 693 143 182 59 10 34 -466 211 466 -377 38 -299 -663 -933 SS 20201124T200735.3Z 7633.838603 101 1 40.65 2 63.52 200.83 103.57 84.14 0.00 1 0.00 1 0 17 1.462e-02 5.143e-03 1.118e-02 1.831e-03 3.460769e-01 9.119464e-04 4.091259e-03 -6.000000e+00 8.286347e-03 222.50 -2.00 3.45 -2.00 318.35 0.00e+00 4.373886e-04 1.630305e-04 1.063646e-04 -6.000000e+00 3.397474e-04 270.26 -2.00 20.00 -2.00 318.04 0.00e+00 2.231 0.000 302.00 328.00 3 4.5216e+00 2.4217e-03 2.5031e-02 -6.0000e+00 2.0497e-02 1.6740e-02 2.7390e-03 1.7005e-02 -6.0000e+00 2.2400e-02 8.2329e-04 1.9065e-03 8.6983e-03 -6.0000e+00 1.3220e-02 -7.0738e-03 1.0156e-03 2.5971e-03 -6.0000e+00 5.5668e-03 5.8150e-04 -2.2986e-04 5.4257e-05 3.0036e-05 -6.0000e+00 4.0861e-04 -2.5559e-03 -1.8817e-05 12 1 1 12 1 1 76.66 20.28 0.20 -0.00256 -0.00428 31 8 1 5 0 1264.830 25.90 20.00 20.28 19.00 17.8 879.91 -4860 1457 -699 -3133 -5806 -7465 -755 -4482 1056 -4809 -1875 -2909 -4570 -2168 -1652 -575 -1677 -45 787 -128 1792 -2242 352 -144 -27 235 -2 599 -2325 1583 573 2933 1629 -705 9 -1504 -1998 -1618 137 -354 -582 -722 -874 -505 -272 -533 -910 -1012 -388 83 139 604 902 599 226 766 590 451 322 458 731 1479 1869 1411 826 95 -16 -91 574 593 296 461 335 510 165 -345 -452 -695 -276 -853 -907 -1153 -1991 -1255 -1347 -386 151 127 431 100 640 -9 -65 211 471 646 434 989 446 -182 -356 -764 -368 69 -831 -1118 -859 -747 -286 354 464 106 193 -21 8 -231 116 12 76 -21 -127 181 -47 423 680 603 319 633 383 389 250 -79 -151 54 -83 -3 -11 -6 -186 -40 -91 -248 -350 -241 75 -38 -167 -287 -362 -36 -252 63 -322 -124 -203 -372 -203 -179 -69 -219 -6 111 -19 265 -344 54 -24 -5 43 0 104 -391 256 101 558 345 -159 2 -320 -464 -435 44 -133 -242 -318 -399 -233 -125 -247 -418 -460 -174 38 67 288 458 324 127 441 347 265 185 260 425 916 1263 1033 617 68 -11 -60 397 463 254 415 302 440 133 -251 -299 -442 -183 -643 -775 -1100 -1907 -1255 -1437 -436 178 155 527 119 700 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